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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 14 Issue 2
Apr.  2023
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ZOU Chengjun, HONG Jiabin, WU Yonglin, WANG Chunxiang, LI Zhifeng. Electrodeposition synthesis of Ni/Ni(OH)2/PANI composites film and electrochemical properties[J]. Nonferrous Metals Science and Engineering, 2023, 14(2): 202-209. DOI: 10.13264/j.cnki.ysjskx.2023.02.006
Citation: ZOU Chengjun, HONG Jiabin, WU Yonglin, WANG Chunxiang, LI Zhifeng. Electrodeposition synthesis of Ni/Ni(OH)2/PANI composites film and electrochemical properties[J]. Nonferrous Metals Science and Engineering, 2023, 14(2): 202-209. DOI: 10.13264/j.cnki.ysjskx.2023.02.006
shu

Electrodeposition synthesis of Ni/Ni(OH)2/PANI composites film and electrochemical properties

  • a.

    Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

  • b.

    Jiangxi Key Laboratory of Power Battery and Materials, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

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  • Received Date: January 09, 2022
  • Available Online: May 05, 2023
    Graphical Abstract
    • Abstract
  • In this paper, Ni/Ni(OH)2/PANI electrode materials were synthesized on Cu foil substrates by the electrodeposition method. The Ni/Ni(OH)2 nanolayer was firstly prepared on the Cu foil surface by the electrodeposition method, then the PANI layer was deposited on the Ni/Ni(OH)2 surface via the electrochemical polymerization method. The morphology, structure and electrochemical properties of Ni/Ni(OH)2/PANI were investigated by SEM, TEM, FT-IR, XPS, CV, GCD and EIS. The results showed that the Ni/Ni(OH)2/PANI electrode materials had a high specific capacitance and excellent cycle performance. The Ni/Ni(OH)2/PANI electrode materials had an outstanding specific capacitance of 1 400 F/g at 1 A/g, excellent rate capability with a capacitance retention rate of 62.7% from 1 to 10 A/g and good cycling stability with a capacitance retention rate of 76% after 2 000 cycles. PANI layer deposited on Ni/Ni(OH)2 surface could reduce the charge transfer impedance of the electrode surface and protect the electrode, thus improving the electrochemical cycle performance of the electrode.
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    • References (28)
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