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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
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Volume 6 Issue 1
Feb.  2015
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YANG Ming, WU Di, YE Xinyu, JIAO Yunfen, WU Long, HUANG Xin, LI Qin. Preparation of large particle neodymium oxide by oxalic acid precipitation with stripping solution[J]. Nonferrous Metals Science and Engineering, 2015, 6(1): 106-110. DOI: 10.13264/j.cnki.ysjskx.2015.01.020
Citation: YANG Ming, WU Di, YE Xinyu, JIAO Yunfen, WU Long, HUANG Xin, LI Qin. Preparation of large particle neodymium oxide by oxalic acid precipitation with stripping solution[J]. Nonferrous Metals Science and Engineering, 2015, 6(1): 106-110. DOI: 10.13264/j.cnki.ysjskx.2015.01.020
shu

Preparation of large particle neodymium oxide by oxalic acid precipitation with stripping solution

  • School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

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  • Received Date: September 01, 2014
  • Published Date: February 27, 2015
    Graphical Abstract
    • Abstract
  • The large particle neodymium oxide is prepared with oxalic acid as precipitator, and stripping solution by P507-N235-kerosene-cyclohexane system as mother solution. The particle size, morphology, phase composition and thermal stability of samples are characterized by laser particle size analyzers, including SEM, XRD and TG-DTG. The main parameters affecting the particle size of precursor in precipitation are reaction temperature, stirring velocity, feeding speed and aging time. The optimum parameters are as follows: reaction temperature, 50 ℃; stirring velocity, 300 r/min; feeding speed, 9 mL/min; aging time, 24 h. A comparative experiment indicates that the residual organic phase in stripping solution can effectively increase the particle size of precursor. Comparative experiments show that the residual organic phase stripping solution of neodymium oxide effectively increases the particle size of precursor. The precursor decomposes completely to neodymium oxide calcined at 800 ℃ for 2 h. The median particle size of final neodymium oxide is larger than 50 μm.
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    • References (16)
  • [1]
    Platova R A, Kondrukevich A A, Platov Y T. Application of neodymium oxide to increase the whiteness of porcelain[J]. Glass and Ceramics, 2012, 68(11): 393-398. https://www.researchgate.net/publication/257565796_Application_of_neodymium_oxide_to_increase_the_whiteness_of_porcelain
    [2]
    Bernhard M E Russbueldt, Wolfgang F Hoelderich. New rare earth oxide catalysts for the transesterification of triglycerides with methanol resulting in biodiesel and pure glycerol[J]. Journal of Catalysis, 2010, 271(2): 290-304. doi: 10.1016/j.jcat.2010.02.005
    [3]
    Ye X Y, Gao W G, Xia L B, et al. A modified solution combustion method to superfine Gd2O3:Eu3+ phosphor: preparation, phase transformation and optical properties[J].Journal of Rare Earths, 2010, 28(3): 345-350. doi: 10.1016/S1002-0721(09)60109-5
    [4]
    吴龙, 吴迪, 叶信宇, 等.稀土氧化物复合ZrO2陶瓷的制备及应用研究进展[J].有色金属科学与工程, 2012, 3(4): 37-42. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201204006
    [5]
    Ma Y, Wang B R, Li L N, et al. Study on the preparation process of large particle cerium oxide[J]. Journal of Rare Earths, 2010, 28: 136-138. doi: 10.1016/S1002-0721(10)60299-2
    [6]
    高玮, 古宏晨.稀土草酸盐沉淀过程中颗粒大小的控制[J].稀土, 2000, 21(1): 11-13. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ200001004.htm
    [7]
    Jayaramaiah J R, Lakshminarasappa B N, Nagabhushana B M. Luminescence studies of europium doped yttrium oxide nano phosphor[J]. Sensors & Actuators:B.Chemical, 2012, 173: 234-238. https://www.researchgate.net/publication/257354353_Luminescence_studies_of_europium_doped_yttrium_oxide_nano_phosphor
    [8]
    Hee Jo Song, Jun Hong Noh, Hee-Suk Roh, et al. Preparation and characterization of nano-sized Y3 Al5O12: Ce3+ phosphor by high-energy milling process[J]. Current Applied Physics, 2013(13): 69-74.
    [9]
    Park Woo-Jung, Jung Mong-Kwon, Moon Ji-Wook, et al. Enhanced luminescent of Y (P, V) O4: Eu3+ nano phosphors in porous cellulose fibers by facile liquid phase precursor synthesis[J]. Journal of Nanoscience and Nanotechnology, 2009, 9(7): 4371-4375. doi: 10.1166/jnn.2009.M62
    [10]
    王嵩龄, 刘钧云, 贾江涛, 等.大粒度、高表观比重氧化铈的合成[J].中国稀土学报, 2008, 26(1): 117-120. http://www.cnki.com.cn/Article/CJFDTOTAL-XTXB200801025.htm
    [11]
    Liu Z G, Li M, Hu Y H, et al. Preparation of large particle rare earth oxides by precipitation with oxalic acid[J]. Journal of Rare Earths, 2008, 26(2): 158-162. doi: 10.1016/S1002-0721(08)60057-5
    [12]
    马莹, 李莉娜, 王宝荣, 等.草酸沉淀法制备大颗粒氧化钇工艺研究[J].稀有金属, 2010, 34(6): 950-954. http://www.cnki.com.cn/Article/CJFDTOTAL-ZXJS201006029.htm
    [13]
    杨幼明, 蓝桥发, 邓声华, 等. P507与N235混合溶剂的稳定性及对NdCl3的协萃效应[J].中国稀土学报, 2013, 31(4): 385-392. http://www.cnki.com.cn/Article/CJFDTOTAL-XTXB201304002.htm
    [14]
    叶信宇, 吴龙, 杨明, 等. P507-N235双溶剂萃取体系反萃工艺研究[J].中国稀土学报, 2013, 31(6): 695-702. http://www.cnki.com.cn/Article/CJFDTOTAL-XTXB201306009.htm
    [15]
    胡皆汗, 郑学仿.实用光谱学[M].北京:科学出版社, 2010.
    [16]
    胡晓丽, 陈东丹, 胡晓洪, 等.表面活性剂对TiO2粉体粒度和形貌的影响[J].中国陶瓷工业, 2003, 4(10): 25-28. http://www.cnki.com.cn/Article/CJFDTOTAL-ZTCG200304006.htm
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