| Citation: |
Lu Jianhong, Yan Jianhui, Tu Jianguo, Wang Mingyong. Rreparation and characterization of Alkyl phosphoric self-assembled monolayers on electroless copper film surface[J]. Nonferrous Metals Science and Engineering, 2020, 11(4): 49-55. DOI: 10.13264/j.cnki.ysjskx.2020.04.008
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Self-assembled monolayers of alkyl phosphonic acids were prepared on the surfaces of freshly made-up electroless copper plated samples by pulsed constant-voltage/potentiostatic pulse enhancement in order to analyse the electrochemical, spectral properties and wettability of self-assembled monolayers. Results showed that the corrosion currents of those self-assembled monolayers decreased 98.4% in 1% alkyl phosphonic acid solution, and their electrochemical impedance increased correspondingly, compared with those of blank samples. In that case, self-assembled monolayers inhibited the anodic process of the corrosion reaction, which lead to interfacial charge transfer instead of oxygen diffusion. FT-IR spectroscopy confirmed that the alkyl phosphonic acid monomolecular film was successfully assembled on the surfaces of electroless copper plated samples, and their corresponding absorption peak of became relatively larger after enhanced by the pulsed constant-voltage. Contact angle test indirectly also affirmed that the alkyl phosphonic acid solution was assembled into films, samples' hydrophilic surface converted into hydrophobic, and the contact angle θ of the self-assembled monomolecular films increased by 39° after the pulsed potentiostatic enhancement treatment, indicating that the pulsed potentiostatic enhancement made the assembled film denser.
| [1] |
QIANG Y, FU S, ZHANG S, et al. Designing and fabricating of single and double alkyl-chain indazole derivatives self-assembled monolayer for corrosion inhibition of copper[J]. Corros Sci, 2018, 140(8): 111-121. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=22e70d2ca74fd2dd387ed50d060145e0
|
| [2] |
尹焕才, 陆一泓, 陈名利.巯基-金自组装单层膜在生物分析检测领域的技术应用及缺陷与改进方法[J].材料导报, 2016, 30(23): 127-133. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cldb201623019
|
| [3] |
杨生荣, 任嗣利, 张俊彦, 等.自组装单分子膜的结构及其自组装机理[J].高等学校化学学报, 2001, 22(3): 470-476. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gdxxhxxb200103027
|
| [4] |
卢建红, 甄崇礼, 沈玉, 等.自组装单分子膜的研究现状及展望[J].材料保护, 2018, 151(8): 114-119. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=clbh201808024
|
| [5] |
KAREL L E, MEHRING P, CACIUC V, et al. Self-assembled monolayers of methylselenolate on the Au 111 surface: a combined STM and DFT study[J]. Surf Sci, 2014, 619: 67-70. doi: 10.1016/j.susc.2013.09.018
|
| [6] |
马玉聪, 樊保民, 郝华, 等.十八胺基分子组装体在碳钢表面的作用机理与模拟[J].高等学校化学学报, 2019, 40(1): 96-107. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gdxxhxxb201901014
|
| [7] |
陆冰沪, 李大双, 李琳穗, 等.铜箔表面硅烷化处理及其耐腐蚀性能[J].有色金属科学与工程, 2019, 10(1): 54-59. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jxysjs201901009
|
| [8] |
程时杰.先进电工材料进展[J].中国电机工程学报, 2017, 37(15): 4273-4285. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgdjgcxb201715001
|
| [9] |
LIU C C, CHENG J, LI X, et al, Laser-induced silver seeding on filter paper for selective electroless copper plating[J]. Materials, 2018, 11(8): 1348-1355.
|
| [10] |
PAWAR P, ANASANE S, BALLAV R, et al. Experimental study of electro-less copper coated on ABS material used for tooling in EDM machining process[J]. J Produ Eng, 2016, 19(2): 27-32.
|
| [11] |
WANG Y, NIi L J, YANG F, et al. Facile preparation of a high-quality copper layer on epoxy resin via electroless plating for applications in electromagnetic interference shielding[J]. J Mater Chem C, 2017, 48: 12769-12776. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=468f251c7d444b149ae768ef9490bad1
|
| [12] |
QIANG Y J, ZHANG S T, YAN S, et al. Three indazole derivatives as corrosion inhibitors of copper in a neutral chloride solution[J]. Corros Sci, 2017, 126(9): 295-304. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=41b0135650e79d34c7b6768e4b3883b4
|
| [13] |
WU J J, CAI C, ZHOU Z, et al. Low-cost mussel inspired poly(catechol /polyamine) coating with superior anti-corrosion capability on copper[J]. J Colloid Interface Sci, 2016, 463(2): 214-221. https://www.sciencedirect.com/science/article/abs/pii/S0021979715303015
|
| [14] |
ZHANG J A, PAN M, YANG R, et al. Structure, biological and electrochemical studies Structure, biological and electrochemical studies of transition metal complexes from N, S, N'donor ligand 8-(2-pyridinylmethylthio) quino-lone[J]. Polyhedron, 2010, 29(1): 581-591. doi: 10.1016/j.poly.2009.07.024
|
| [15] |
王海人, 屈钧娥, 张强, 等.膦酸自组装膜在铝合金表面的吸附及缓蚀行为[J].表面技术, 2011, 40(1): 40-43. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bmjs201101013
|
| [16] |
刁鹏, 梅岗, 侯群超, 等.恒电位组装的硫醇单层膜的电化学性质[J].物理化学学报, 2005, 21(3): 291-295. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb200503013
|
| [17] |
LU J H, WANG M Y, DENG X M, et al. Evaluation of K3Fe(CN)6 on deposition behavior and structure of electroless copper plating[J]. Electrochemictry, 2019, 87(2): 214-219. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=https://www.jstage.jst.go.jp/article/electrochemistry/87/4/87_19-00010/_article/-char/en
|
| [18] |
陈振宇, 黄礼平, 黄玲, 等.硫醇分子自组装膜在铜表面的作用行为研究[J].表面技术, 2012, 41(2): 1-4. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=bmjs201202001
|
| [19] |
徐群杰, 万宗跃, 印仁和, 等. 3-氨基-1, 2, 4-三氮唑自组装膜对黄铜的缓蚀作用[J].物理化学学报, 2008, 24(1), 115-120. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb200801020
|
| [20] |
ILONA F, JUDIT T, GABOR P, et al. Kinetics of self-assembled layer formation on iron[J]. Electrochim Acta, 2002, 47: 2335-2340. doi: 10.1016/S0013-4686(02)00084-1
|
| [21] |
周坤, 蒋中英.混合自组装膜的电化学行为研究[J].苏州大学学报(自然科学版), 2011, 27(4): 47-52.
|
| [22] |
TAKESHI I, NOBUYOSHI A, SATORU K, et al. Fabrication of 3D interdigitated array electrode consisting of Au nanoparticles and its application for biosensing[J]. Electrochemictry, 2012, 80(5): 305-307. doi: 10.5796/electrochemistry.80.305
|
| [23] |
SERGIO K, LAURO T, KUBOTA. Electrochemical behavior of self-assembled DNA-gold nanoparticle lattice films[J]. Electrochem Comm, 2018, 90(5): 51-55. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=c0c8ed288d35971d4cbb3d8debf7e610
|
| [24] |
白英奇, 王春涛, 李波, 等. L-半胱氨酸自组装膜对铜的缓蚀功能研究[J].山西大学学报(自然科学版), 2011, 34(4): 621-626. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sxdxxb201104021
|
| [25] |
徐群杰, 周国定, 陆柱.缓蚀剂对铜作用的激光扫描微区光电化学研究[J].化学学报, 2000, 58(9), 1079-1085. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hxxb200009003
|
| [26] |
杜伟, 李佳佳, 万俐, 等.十八硫醇自组装膜对青铜的缓蚀作用[J].中国有色金属学报, 2012, 22(11): 3249-3254. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgysjsxb201211039
|
| [27] |
CHEN S, XIANG B, CHEN S, et al. Synthesis and surface characterization of self-assembled monolayers of thiazoles incorporating hydrocarbon and fluorocarbon chains on copper substrates[J]. Applied Surface Science, 2018, 456(10): 25-36.
|
| [28] |
QIAO L G, SHI W F. Synthesis and characterization of hyperbranched polyurethane-benzyltetrazole[J]. Chin J Polym Sci, 2011, 29(6): 670-683. doi: 10.1007/s10118-011-1080-4
|
| [29] |
AAMI A A, EBRALIDZE I, DICKSON S E, et al. Characterization of hydroxyphenol-terminated alkane thiol self-assembled monolayers: Interactions with phosphates by chemical force spectrometry[J]. J Colloid Interface Sci, 2013, 393: 352-360. doi: 10.1016/j.jcis.2012.10.026
|
| [30] |
姚凤凤, 侯春风, 杨志永, 等.烷基硫醇/金自组装单分子膜表面上金属沉积特性研究进展[J].物理学进展, 2004, 24(4): 469-490. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlxjz200404006
|
| [31] |
CAMILLONE N, CHIDSEY C E D, LIU G Y, et al. Substrate dependence on the surface structure and chain packing of docosyl mercaptan self-assembled on the (111), (110), and (100) faces of single-crystal golds[J]. J Chem Phys, 1993, 98(5): 4234-4245. doi: 10.1063/1.465030
|
| [32] |
ABRAHAM U. Formation and structure of self-assembled monolayers[J]. Chem Rev, 1996, 96: 1533-1554. doi: 10.1021/cr9502357
|
| [33] |
李华, 任浩, 张维维, 等.新型二维有机膦酸镍化合物的合成、晶体结构与气体吸附性能[J].高等学校化学学报, 2011, 32(1): 28-31. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gdxxhxxb201101007
|
| [34] |
LAONGNUAN S, ANDREW C, JAMISON T, et al. Stability: a key issue for self-assembled monolayers on gold as thin film coatings and nanoparticle protectants[J]. Colloids Surf A Physicochem Eng Asp, 2011, 390: 1-19. doi: 10.1016/j.colsurfa.2011.09.020
|
| [35] |
NEAL D S, THOMAS M M, TERRY A M. Structure dependent viscoelastic properties of C9-alkanethiol monolayers[J]. Tribol Lett, 1999(7): 67-71. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d401a16544d92b283f946970f12e7ac6
|
| [36] |
BRUNO G N, AARON P, KENDRA L W, et al. Controlling Interfacial properties of lithium-ion battery cathodes with alkylphosphonate self-assembled monolayers[J]. Adv Mater Interfaces, 2018, 5(10): 1-12. doi: 10.1002/admi.201701292
|
| [37] |
LESSEL M, BAUMCHEN O, KLOS M, et al. Self-assembled silane monolayers: an efficient step-by-step recipe for high-quality, low energy surfaces[J]. Surf Interface Anal, 2015, 47(5): 557-564. doi: 10.1002/sia.5729
|
| [38] |
TIAN Z T, MARCONNET A, CHEN G. Enhancing solid-liquid interface thermal transport using self-assembled monolayers[J]. Appl Phys Lett, 2015, 106: 1-4. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=e02503fd5140bbb937da78950adf442a
|
| [39] |
王芳, 王茜, 王亚斌, 等.铝合金表面三嗪二硫醇和硅烷纳米复合薄膜的制备及表征[J].功能材料, 2011, 42(3): 432-435. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gncl201103014
|
| [40] |
李杰, 刘玉德, 高东明, 等.激光加工结合自组装制备铝合金超疏水表面[J].中国材料进展, 2015, 34(6): 462-466. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgcljz201506007
|
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