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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 10 Issue 4
Aug.  2019
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XU Yangming, CUI Qiang, WANG Yaqin, SHI Kexin, TONG jinlin, WANG Bin. Composition optimization and electrochemical properties of Mg-Al-Pb-Ga-Y alloys as anodes for seawater activated battery[J]. Nonferrous Metals Science and Engineering, 2019, 10(4): 51-58. DOI: 10.13264/j.cnki.ysjskx.2019.04.009
Citation: XU Yangming, CUI Qiang, WANG Yaqin, SHI Kexin, TONG jinlin, WANG Bin. Composition optimization and electrochemical properties of Mg-Al-Pb-Ga-Y alloys as anodes for seawater activated battery[J]. Nonferrous Metals Science and Engineering, 2019, 10(4): 51-58. DOI: 10.13264/j.cnki.ysjskx.2019.04.009
shu

Composition optimization and electrochemical properties of Mg-Al-Pb-Ga-Y alloys as anodes for seawater activated battery

  • 1.

    Wuhan Zhongyuan ChangJiang Technology Development Co., Ltd., Wuhan 430090, China

  • 2.

    School of Materials Science and Engineering, Central South University, Changsha 410083, China

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  • Received Date: April 11, 2019
  • Published Date: August 30, 2019
    Graphical Abstract
    • Abstract
  • Magnesium alloy anode materials for Mg-Al-Pb-Ga-0.9Y seawater battery were prepared by metallurgy method. The effects of Pb、Ga additions on the microstructures and electrochemical properties of this alloy were investigated by optical microscopy(OM), scanning electronic microscopy(SEM), X-ray diffraction(XRD) and Electrochemical test. The results show that the discharge voltage and corrosion resistance of the alloy increase with the growth of Pb content. Moreover, the optimum effect of discharge voltage is achieved with 5 wt% Pb and 1 wt% Ga additions. The alloy has a high discharge voltage at 20 mA/cm2 and 100 mA/cm2 current densities. The Mg-3Al-5Pb-1Ga-0.9Y alloy has more excellent comprehensive performance than the other alloys, which also has the most negative discharge potential. The working potentials at current densities of 20 mA/cm2 and 100 mA/cm2 are -1.723 V and -1.680 V respectively. In addition, the Mg-3Al-5Pb-1Ga-0.9Y alloy has a low self-corrosion rate, and its corrosion current density is 5.1164×10-5 A/cm2.
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    • References (23)
  • [1]
    CAO D X, WU L, WANG G, et al. Electrochemical oxidation behaviour of Mg–Li–Al–Ce–Zn and Mg–Li–Al–Ce–Zn–Mn in sodium chloride solution[J]. Power Sources, 2008, 183(2): 799-804. doi: 10.1016/j.jpowsour.2008.06.005
    [2]
    张俊昌, 冯艳, 王乃光, 等.挤压比对海水激活电池用AP65镁合金阳极材料放电性能的影响[J].有色金属科学与工程, 2017, 8(3):54-63. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=2017030009
    [3]
    马洪斌.阀控铅酸蓄电池发展现状[J].蓄电池, 2004, 41(3):137-140. doi: 10.3969/j.issn.1006-0847.2004.03.012
    [4]
    马永刚. 2005年我国铅酸蓄电池市场需求量预测[J].中国有色金属, 2005(3):56-57. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjsgy200503020
    [5]
    FENG Y, WANG R C, PENG C Q, et al. Aging behaviour and electrochemical properties in Mg-4.8Hg-8Ga (wt.%) alloy[J]. Corrosion Science, 2010, 52(10):3474-3480. doi: 10.1016/j.corsci.2010.06.024
    [6]
    ANDREI M, GABRIELE F D, BONORA P L, et al. Corrosion behaviour of magnesium sacrificial anodes in tap water[J]. Materials & Corrosion, 2015, 54(1):5-11. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=10.1002/maco.200390010
    [7]
    BALASUBRAMANIAN R, VELUCHAMY A, VENKATAKRISHNAN N, et al. Electrochemical characterization of magnesium/silver chloride battery[J]. Journal of Power Sources, 1995, 56(2):197-199. doi: 10.1016/0378-7753(95)80034-E
    [8]
    王乃光, 王日初, 彭超群, 等.镁阳极在海水激活电池中的应用[J].中国有色金属学报, 2016, 26(5):1034-1044. http://d.old.wanfangdata.com.cn/Periodical/zgysjsxb201605012
    [9]
    THIRUNAKARAN R, VASUDEVAN S, SIVASHANMUGAM A, et al. 1-Nitronaphthalene as a cathode material for magnesium reserve batteries[J]. Power Sources, 1996, 58(2): 213-215. doi: 10.1016/S0378-7753(96)02376-2
    [10]
    张嘉佩.合金元素及热加工工艺对镁阳极组织和性能的影响[D].长沙: 中南大学, 2011. http://cdmd.cnki.com.cn/Article/CDMD-10533-1011183132.htm
    [11]
    BELDJOUDI T, FIAUD C, ROBBIOLA L. Influence of homogenization and artificial aging heat treatments on corrosion behavior of Mg-Al Alloys[J]. Corrosion -Houston Tx-, 1993, 49(9):738-745. doi: 10.5006/1.3316126
    [12]
    腾昭阳.合金元素对镁阳极腐蚀和电化学性能的影响[D].长沙: 中南大学, 2014. http://cdmd.cnki.com.cn/Article/CDMD-10533-1014407910.htm
    [13]
    LIU X G, PENG X D, XIE W D, et al. Preparation technologies and applications of strontium-magnesium master alloys[J]. Materials Science Forum, 2005, 488/489:31-34. doi: 10.4028-www.scientific.net-MSF.488-489.31/
    [14]
    李高林.稀土(Y、Nd)对AZ80镁合金耐腐蚀性能影响的研究[D].洛阳: 河南科技大学, 2012. http://cdmd.cnki.com.cn/Article/CDMD-10464-1012042798.htm
    [15]
    钟丽应.稀土元素对AZ91镁合金组织结构和腐蚀行为的影响[D].杭州: 浙江大学, 2008. http://cdmd.cnki.com.cn/Article/CDMD-10335-2008148684.htm
    [16]
    王乃光. AP65镁合金在氯化钠溶液中电化学行为研究[D].长沙: 中南大学, 2013. http://cdmd.cnki.com.cn/Article/CDMD-10533-1013358689.htm
    [17]
    ZHANG J P, WANG R C, FENG Y, et al. Effects of Hg and Ga on microstructures and electrochemical corrosion behaviors of Mg anode alloys[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(12):3039-3045. doi: 10.1016/S1003-6326(11)61568-9
    [18]
    YUAN S, LU H, SUN Z, et al. Electrochemical Performance of Mg-3Al Modified with Ga, In and Sn as Anodes for Mg-Air Battery[J]. Journal of the Electrochemical Society, 2016, 163(7):1181-1187. doi: 10.1149/2.0371607jes
    [19]
    HAMEDMOGHANN B O, JALAL A, MOSTAFA H. Effects of gallium and lead on the electrochemical behavior of Al-Mg-Sn-Ga-Pb as anode of high rate discharge battery[J]. Journal of Alloys and Compounds, 2017, 695: 2637-2644. doi: 10.1016/j.jallcom.2016.11.176
    [20]
    WANG N, WANG R, FENG Y, et al. Discharge and corrosion behaviour of Mg-Li-Al-Ce-Y-Zn alloy as the anode for Mg-air battery[J]. Corrosion Science, 2016, 112:13-24. doi: 10.1016/j.corsci.2016.07.002
    [21]
    邓姝皓, 易丹青, 赵丽红, 等.一种新型海水电池用镁负极材料的研究[J].电源技术, 2007, 31(5):402-405. doi: 10.3969/j.issn.1002-087X.2007.05.016
    [22]
    MASSALSKI T B, OKAMOTO H, SUBRAMANIAN P, et al. Binary alloy phasediagrams[M]. Geauga: ASM Int, 1990.
    [23]
    MERINO M C, PARDO A, ARRABAL R, et al. Influence of chloride ion concentration and temperature on the corrosion of Mg-Al alloys in salt fog[J]. Corrosion Science, 2010, 52(5):1696-1704. doi: 10.1016/j.corsci.2010.01.020
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