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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 11 Issue 2
Apr.  2020
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LIU Zhijun, PENG Wanwan, LI Zhifeng, WANG Chunxiang, ZHANG Qian, ZHONG Shengwen. Effect of niobium doping on the electrochemical performance of nickel-based cathode materials[J]. Nonferrous Metals Science and Engineering, 2020, 11(2): 89-96. DOI: 10.13264/j.cnki.ysjskx.2020.02.013
Citation: LIU Zhijun, PENG Wanwan, LI Zhifeng, WANG Chunxiang, ZHANG Qian, ZHONG Shengwen. Effect of niobium doping on the electrochemical performance of nickel-based cathode materials[J]. Nonferrous Metals Science and Engineering, 2020, 11(2): 89-96. DOI: 10.13264/j.cnki.ysjskx.2020.02.013
shu

Effect of niobium doping on the electrochemical performance of nickel-based cathode materials

  • a.

    Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology, Ganzhou 341000, China

  • b.

    Jiangxi Key Laboratory of Power Battery and Materials, Jiangxi University of Science and Technology, Ganzhou 341000, China

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  • Received Date: January 09, 2020
  • Published Date: April 29, 2020
    Graphical Abstract
    • Abstract
  • To find out the way to maintain the electrochemical cycle stability and the high-temperature performance of nickel-based cathode materials LiNi0.8Co0.1Mn0.1O2 is the key to its wide application to industry. This paper focuses on the improvement of the electrochemical properties of nickel-based cathode materials by doping niobium. The cathode materials of Li(Ni0.8Co0.1Mn0.1)1-xNbxO2（x = 0, 0.01, 0.02, 0.03) were synthesized by calcining the mixtures of LiOH·H2O, Nb2O5 and the ternary material sphericalNi0.8Co0.1Mn0.1(OH) 2 precursor which was made from sulphate by co-precipitation method in N2 atmosphere. The XRD results showed that small amount of the Nb5+ ions could dope into the cathode materials’ lattice and formed Li3NbO4with stable chemical properties on the surface of the cathode materials. When x was 0.02, the special capacity of the first discharge was 172.9 mAh/g and the capacity retention rate was 97.47% after 100 cycles at 25℃, within the voltage range of 2.75~4.2 V and with the ratio of 0.2 C. At 50℃and with the ratio of 0.5 C, the capacity retention rate changed little after 100 cycles and the average discharge specific capacity was 183.7 mAh/g. Moreover, the sample had good rate performance.
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    • References (34)
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