Current Issue Cover
Advanced Search
Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 11 Issue 2
Apr.  2020
Turn off MathJax
Article Contents
Abstract
References
Related Articles
LIU Zhijun, PENG Wanwan, LI Zhifeng, WANG Chunxiang, ZHANG Qian, ZHONG Shengwen. Effect of niobium doping on the electrochemical performance of nickel-based cathode materials[J]. Nonferrous Metals Science and Engineering, 2020, 11(2): 89-96. DOI: 10.13264/j.cnki.ysjskx.2020.02.013
Citation: LIU Zhijun, PENG Wanwan, LI Zhifeng, WANG Chunxiang, ZHANG Qian, ZHONG Shengwen. Effect of niobium doping on the electrochemical performance of nickel-based cathode materials[J]. Nonferrous Metals Science and Engineering, 2020, 11(2): 89-96. DOI: 10.13264/j.cnki.ysjskx.2020.02.013
shu

Effect of niobium doping on the electrochemical performance of nickel-based cathode materials

  • a.

    Faculty of Materials Metallurgy and Chemistry,Jiangxi University of Science and Technology, Ganzhou 341000, China

  • b.

    Jiangxi Key Laboratory of Power Battery and Materials, Jiangxi University of Science and Technology, Ganzhou 341000, China

More Information
  • Received Date: January 09, 2020
  • Published Date: April 29, 2020
    Graphical Abstract
    • Abstract
  • To find out the way to maintain the electrochemical cycle stability and the high-temperature performance of nickel-based cathode materials LiNi0.8Co0.1Mn0.1O2 is the key to its wide application to industry. This paper focuses on the improvement of the electrochemical properties of nickel-based cathode materials by doping niobium. The cathode materials of Li(Ni0.8Co0.1Mn0.1)1-xNbxO2（x = 0, 0.01, 0.02, 0.03) were synthesized by calcining the mixtures of LiOH·H2O, Nb2O5 and the ternary material sphericalNi0.8Co0.1Mn0.1(OH) 2 precursor which was made from sulphate by co-precipitation method in N2 atmosphere. The XRD results showed that small amount of the Nb5+ ions could dope into the cathode materials’ lattice and formed Li3NbO4with stable chemical properties on the surface of the cathode materials. When x was 0.02, the special capacity of the first discharge was 172.9 mAh/g and the capacity retention rate was 97.47% after 100 cycles at 25℃, within the voltage range of 2.75~4.2 V and with the ratio of 0.2 C. At 50℃and with the ratio of 0.5 C, the capacity retention rate changed little after 100 cycles and the average discharge specific capacity was 183.7 mAh/g. Moreover, the sample had good rate performance.
    • FullText(HTML)
    • References (34)
  • [1]
    CHEN J J. Recent progress in advanced materials for lithium ion batteries[J]. Materials, 2013, 6(1): 156-183. http://d.old.wanfangdata.com.cn/Periodical/wnkb-e201804012
    [2]
    胡伟,钟盛文,李晓艳,等. LiNi0.55Co0.15Mn0.3O2三元正极材料的合成及电化学性能研究[J]. 有色金属科学与工程, 2019, 10(3): 54-57. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201903009
    [3]
    ZHANG J, ZHANG J, OU X, et al. Enhancing high-Voltage performance of Ni-Rich cathode by surface modification of self-assembled NASICON fast Ionic Conductor LiZr2(PO4)3[J]. ACS Appl Mater Interfaces, 2019, 11(17): 15507-15516. doi: 10.1021/acsami.9b00389
    [4]
    ZHANG M L, ZHAO H, TAN M, et al. Yttrium modified Ni-rich LiNi0.8Co0.1Mn0.1O2 with enhanced electrochemical performance as high energy density cathode material at 4.5 V high voltage[J]. Journal of Alloys and Compounds, 2019, 774(5): 82-92. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=5107c78839fbe68168c9d86df20a09c8
    [5]
    AURBACH D, SRUR-LAVI O, GHANTY C, et al. Studies of aluminum-doped LiNi0.5Co0.2Mn0.3O2: Electrochemical behavior, aging, structural transformations, and thermal characteristics[J]. Journal of The Electrochemical Society, 2015, 162(6): A1014-A1027. doi: 10.1149/2.0681506jes
    [6]
    YANG Z R, BAO L, LI W K, et al. Synthesizing LiNi0.8Co0.1Mn0.1O2 with novel shell-pore structure for enhanced rate performance[J]. Journal of Alloys and Compounds, 2019, 789: 736-743. doi: 10.1016/j.jallcom.2019.03.125
    [7]
    LU M, HAN E, ZHU L, et al. The effects of Ti4+-Fe3+ co-doping on Li[Ni1/3Co1/3Mn1/3]O2[J]. Solid State Ionics, 2016, 298: 9-14. doi: 10.1016/j.ssi.2016.10.014
    [8]
    HUANG Y, WANG Z X, LI X H, et al. Synthesis of Ni0.8Co0.1Mn0.1(OH)2 precursor and electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode material for lithium batteries[J]. Transactions of Nonferrous Metals Society of China, 2015, 25(7): 2253-2259. doi: 10.1016/S1003-6326(15)63838-9
    [9]
    LI X, ZHANG K, WANG M, et al. Dual functions of zirconium modification on improving the electrochemical performance of Ni-rich LiNi0.8Co0.1Mn0.1O2[J]. Sustain. Energy Fuels, 2018, 2(2): 413-421. doi: 10.1039/C7SE00513J
    [10]
    MANTHIRAM A, SONG B H, Li W D. A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries[J]. Energy Storage Materials, 2017, 6: 125–139. doi: 10.1016/j.ensm.2016.10.007
    [11]
    FAN G X, LIU Z P, WEN Y, et al. Surface treatment on structure and property of LiNi0.8Co0.15Al0.05O2 by silane coupling agent[J]. Journal of Inorganic Materials, 2018, 33(7): 749-755. doi: 10.15541/jim20170461
    [12]
    LI X, GE W J, WANG H, et al. Research progress on the capacity fading mechanisms of high-nickel ternary layered oxide cathode materials[J]. Journal of Inorganic Materials, 2017, 32(2): 114-121. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wjclxb201702001
    [13]
    LEE S H, YOON C S, AMINE K, et al. Improvement of long-term cycling performance of Li[Ni0.8Co0.15Al0.05]O2 by AlF3 coating[J]. Journal of Power Sources, 2013, 234(15): 201-207. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=967a08f471a80904156c07f708283e48
    [14]
    YANG K, LI Z F, GUO J, et al. Significant improvement of electrochemical properties of AlF3-coated LiNi0.5Co0.2Mn0.3O2 cathode materials[J]. Electrochimica Acta, 2012, 63(29): 363-368. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=96caa15fb119d44a2a627247c47cc88d
    [15]
    LIU W, LI X F, XIONG D B, et al. Significantly improving cycling performance of cathodes in lithium ion batteries: the effect of Al2O3 and LiAlO2 coatings on LiNi0.6Co0.2Mn0.2O2[J]. Nano Energy, 2018, 44: 111-120. doi: 10.1016/j.nanoen.2017.11.010
    [16]
    WANG J P, DU C Y, YAN C Q, et al. Al2O3 coated concentration-cradient Li[Ni0.73Co0.12Mn0.15]O2 cathode material by freeze drying for long-life lithium ion batteries[J]. Electrochimica Acta, 2015, 174(20): 1185-1191. https://www.researchgate.net/publication/281751500_Al2O3_Coated_Concentration-Gradient_LiNi073Co012Mn015O2_Cathode_Material_by_Freeze_Drying_for_Long-Life_Lithium_Ion_Batteries
    [17]
    DAI G L, DU H J, WANG S S, et al. Improved electrochemical performance of LiNi0.8Co0.15Al0.05O2 with ultrathin and thickness controlled TiO2 shell via atomic layer deposition technology[J]. RSC Adv, 2016, 6(103): 100841-100848. doi: 10.1039/C6RA21903A
    [18]
    LAI Y Q, XU M, ZHANG Z A, et al. Optimized structure stability and electrochemical performance of LiNi0.8Co0.15Al0.05O2 by sputtering nanoscale ZnO film[J]. Journal of Power Sources, 2016, 309(31): 20-26. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=18bb8f713e665184f7283b3c5347f0bf
    [19]
    XUE L L, LI Y J, XU B, et al. Effect of Mo doping on the structure and electrochemical performances of LiNi0.6Co0.2Mn0.2O2 cathode material at high cut-off voltage[J]. Journal of Alloys and Compounds, 2018, 748(5): 561-568. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=8bddae625d1e1a6ff8b9c71378c884b2
    [20]
    SCHIPPER F, DIXIT M, KOVACHEVA D, et al. Stabilizing nickel-rich layered cathode materials by a high charge cation doping strategy: zirconium-doped LiNi0.6Co0.2Mn0.2O2[J]. Royal Society of Chemistry, 2016, 41(4): 16073-16084. https://www.researchgate.net/publication/308072757_Stabilizing_Nickel-Rich_Layered_Cathode_Materials_by_a_High-Charge_Cation_Doping_Strategy_Zirconium-Doped_LiNi06Co02Mn02O2
    [21]
    YANG Z G, HUA W B, ZHANG J, et al. Enhanced electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode materials at elevated temperature by Zr Doping[J]. Acta Physico-Chimica Sinica, 2016, 32 (5): 1056－1061. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201605008
    [22]
    CHEN Y X, LI Y J, LI W, et al. High-voltage electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode material via the synergetic modification of the Zr/Ti elements[J]. Electrochimica Acta, 2018, 281(10): 48-59. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7bb3fdbdaf1a36c639c37944f6a46659
    [23]
    林桂仙, 韩博, 黄群,等.TiO2改性提高LiNi0.8Co0.1Mn0.1O2正极材料的电化学及储存性能[J].中国材料进展, 2019, 38(5): 489-496. http://d.old.wanfangdata.com.cn/Periodical/zgcljz201905010
    [24]
    WU J F, LIU H G, YE X H, et al. Effect of Nb doping on electrochemical properties of LiNi1/3Co1/3Mn1/3O2 at high cutoff voltage for lithium-ion battery[J]. Journal of Alloys & Compounds, 2015, 644(25): 223-227. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4bf1b900576c70a802fb9699141d3457
    [25]
    YANG Z G, XIANG W X, WU Z G, et al. Effect of niobium doping on the structure and electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium ion batteries[J]. Ceramics International, 2017, 43(4): 3866-3872. doi: 10.1016/j.ceramint.2016.12.048
    [26]
    KANEDA H, KOSHIKA Y, NAKAMURA T, et al. Improving the cycling performance and thermal stability of LiNi0.6Co0.2Mn0.2O2 cathode materials by Nb-doping and surface modification[J]. International Journal of Electrochemical Science, 2017, 12(6): 4640-4653. https://www.researchgate.net/publication/317288793_Improving_the_Cycling_Performance_and_Thermal_Stability_of_LiNi06Co02Mn02O2_Cathode_Materials_by_Nb-doping_and_Surface_Modification
    [27]
    LI Z F, LUO C Y, WANG C X, et al. Effects of Nb substitution on structure and electrochemical properties of LiNi0.7Mn0.3O2 cathode materials[J]. Journal of Solid State Electrochemistry, 2018, 22(9): 2811-2820. doi: 10.1007/s10008-018-3975-2
    [28]
    LI J B. XU Y L, DU X F, et al. Improved electrochemical stability of Zn-doped LiNi1/3Co1/3Mn1/3O2 cathode materials[J]. Acta Phys. -Chim. Sin. 2012, 28(8): 1899-1905. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201208015
    [29]
    张继斌, 滑纬博, 郑卓, 等. 高倍率性能锂离子电池Li[Ni1/3Co1/3Mn1/3]O2正极材料的制备及其电化学性能[J]. 物理化学学报, 2015, 31(5): 905-912. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201505013
    [30]
    ZHANG X Y, JIANG W J, MAUGER A,et al. Aging of LiNi1/3Mn1/3Co1/3O2 cathode material upon exposure to H2O[J]. Journal of Power Sources, 2011, 196(11): 5102-5108. doi: 10.1016/j.jpowsour.2011.02.009
    [31]
    刘熙林,钟盛文,梅文捷,等. (Li1.07Ni0.4Mn0.53)1-xAlxO2正极材料的合成与性能[J]. 有色金属科学与工程, 2015, 6(5): 63-68. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201505012
    [32]
    彭弯弯. 高容量镍基正极材料LiNi0.8Co0.1Mn0.1O2的制备与改性研究[D]. 赣州：江西理工大学, 2018.
    [33]
    LI Z, HONG J H, HE G, et al. Effect of FePO4 coating on performance of Li1.2Mn0.54Ni0.13Co0.13O2 as cathode material for Li-ion battery[J]. Journal of Inorganic Materials, 2015, 30(2): 129-134. doi: 10.15541/jim20140268
    [34]
    REN X Z, LIU T, SUN L N, et al. Preparation and electrochemical performances of Li1.2Mn0.54-xNi0.13Co0.13ZrxO2 cathode materials for lithium-ion batteries[J]. Acta Phys. Chim. Sin, 2014, 30(9): 1641-1649. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201409007
    • Related Articles

  • Related Articles

    [1]YAO Mingcan, LI Tianyu, HU Jin, FU Fangzhong, LIN Jiahao, FAN Helin, WANG Ruixiang, XU Zhifeng. Structure and transport properties of FeO-SiO2 melt[J]. Nonferrous Metals Science and Engineering, 2025, 16(1): 17-24. DOI: 10.13264/j.cnki.ysjskx.2025.01.003
    [2]DU Mingxing, LENG Jinfeng, LI Zhanzhi, YIN Yuhu. Effect of trace Er and Zr addition on mechanical properties of 6082 Al alloy during solid solution-aging treatment[J]. Nonferrous Metals Science and Engineering, 2024, 15(1): 139-146. DOI: 10.13264/j.cnki.ysjskx.2024.01.017
    [3]JIN Jiefang, YU Xiong, ZHONG Yilu. Energy dissipation characteristics of red sandstone with different water content during impact loading[J]. Nonferrous Metals Science and Engineering, 2021, 12(5): 69-80. DOI: 10.13264/j.cnki.ysjskx.2021.05.009
    [4]FAN Jie, XIE Gang, TIAN Lin, YU Xiaohua, WANG Bingbing, WANG Pinjie. Calculation of first principles of electron structure of Fe2+ doped sphalerite and its influence on mineral leaching[J]. Nonferrous Metals Science and Engineering, 2021, 12(2): 1-7. DOI: 10.13264/j.cnki.ysjskx.2021.02.001
    [5]GAN Minglong, LI Yameng, FU Junxiang. Phase transition and upconversion luminescent properties of NaYF4: Yb, Er@SiO2 at high temperature[J]. Nonferrous Metals Science and Engineering, 2021, 12(1): 75-80. DOI: 10.13264/j.cnki.ysjskx.2021.01.010
    [6]TONG Zhifang, LiN Xin, ZENG Qingpo. Dissipative particle dynamics of the sadsorption propertiesof compound additives on the surface of dicalcium silicate[J]. Nonferrous Metals Science and Engineering, 2020, 11(4): 1-8. DOI: 10.13264/j.cnki.ysjskx.2020.04.001
    [7]QU Miao, LIU Yu, XIAO Zhengbing. A first principle study on the basic properties of inclusions in aluminum alloy[J]. Nonferrous Metals Science and Engineering, 2018, 9(6): 1-10. DOI: 10.13264/j.cnki.ysjskx.2018.06.001
    [8]YUAN Wei, JIN Jie-fang, LIANG Chen, WANG Jie, He Cong, CHENG Yun. Numerical Analysis of Dynamic Damage and Energy Dissipation Characteristics of Concrete under Confining Pressure[J]. Nonferrous Metals Science and Engineering, 2017, 8(4): 98-104. DOI: 10.13264/j.cnki.ysjskx.2017.04.017
    [9]ZHAO Kui, YU Bin, LI Qiseng, ZHU Zhicheng, KUANG Zeliang. Experimental study on in-situ stress measurement from marble using acoustic emission method[J]. Nonferrous Metals Science and Engineering, 2017, 8(3): 88-93. DOI: 10.13264/j.cnki.ysjskx.2017.03.015
    [10]LI Qin, LUO Yang, YE Xinyu, HUANG Xin. Application progress of first-principles calculations in CALPHAD technology[J]. Nonferrous Metals Science and Engineering, 2015, 6(6): 37-46. DOI: 10.13264/j.cnki.ysjskx.2015.06.008

  • Cited by

    Periodical cited type(1)

    1. 赵越，刘宇奇，金楠皓，王新颖，刘小铭，陈寒，李玮，李杨华. 基于含氮衍生物和羧酸的Co（Ⅱ）配合物的合成、结构及磁学、荧光性质. 云南大学学报(自然科学版). 2024(02): 309-318 .

    Other cited types(0)

Catalog

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (125) PDF downloads (10) Cited by(1)
    Related

    Copyright © 2010 Editorial Department of Nonferrous Metals Science and Engineering All rights reserved

    Address：11th floor, bishop building, University of science and technology, No. 86, Hongqi Avenue, Ganzhou City, Jiangxi Province  Tel：0797-8312555

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return