Determination of hydrogen content of hafnium by inert gas fusion infrared method

ZHAO Fei; LI Juan

doi:10.13264/j.cnki.ysjskx.2017.06.019

Volume 8 Issue 6

Dec. 2017

Turn off MathJax

Article Contents

Abstract

References

Nonferrous Metals Science and Engineering > 2017 > 8(6): 117-120. > DOI: 10.13264/j.cnki.ysjskx.2017.06.019

ZHAO Fei, LI Juan. Determination of hydrogen content of hafnium by inert gas fusion infrared method[J]. Nonferrous Metals Science and Engineering, 2017, 8(6): 117-120. DOI: 10.13264/j.cnki.ysjskx.2017.06.019

Citation:

PDF (475 KB)

Determination of hydrogen content of hafnium by inert gas fusion infrared method

ZHAO Fei^,,
LI Juan

Western Metal Materials Co. Ltd., Xi'an 710016, China

More Information

Received Date: July 26, 2017
Published Date: December 30, 2017

Graphical Abstract

Abstract

Abstract

Using LECO-NH836 nitrogen-hydrogen analyzer, the sample was melted in an inert atmosphere, and the content of hydrogen in hafnium was detected by the infrared method. By choosing 1.00 g nickel basket as the flux of hydrogen release in hafnium, the influence of different analytical powers on the hydrogen content analysis was studied. The analysis power of 5 000 W, the shortest analysis time of 60 s, and the sample mass of 0.10 g were selected to verify the applicability of titanium reference materials.The RSDs of 11 replicates of the two samples were 5.64 % and 1.52 %, respectively, with good precision.The spiked recoveries ranged from 95.18 % to 105.26 %. The result of the study is instructive for the accurate determination of hydrogen in hafnium.
- inert gas fusion,
- hafnium,
- infrared method,
- hydrogen

FullText(HTML)

References (24)

References

[1]	罗新文, 罗方承.锆铪材料的性能、应用、生产技术与发展前景[J].江西冶金, 2009, 29(4):39-41. http://www.docin.com/p-786511528.html
[2]	熊炳昆.金属铪的制备及应用[J].稀有金属快报, 2005, 24(5):46-47. http://www.doc88.com/p-6387758314582.html
[3]	熊炳昆, 贾弘, 逯福生, 等.我国金属锆铪及其制品的生产、应用及供求分析[J].稀有金属快报, 2004, 23(5):30-33. http://www.cqvip.com/qk/98187X/200406/10232573.html
[4]	熊炳昆.稀有金属王国中的姊妹花——锆和铪[J].稀有金属快报, 2005, 24(1):41-42. http://www.cqvip.com/QK/98187X/200501/12142281.html
[5]	KOTSAR M L, MORENKO O G, SHTUTSA M G, et al. Obtaining of high-purity titanium, zirconium, and hafnium by the method of iodide refining in industrial conditions[J].Inorganic Materials, 2010, 46(3):282-290. doi: 10.1134/S0020168510030131
[6]	DZIDZIGURI E L, SIDOROVA E N, SALANGINA E A. Development of a process for producing nanostructured hafnium powder[J].Metallurgist, 2010, 54(7/8):455-458. doi: 10.1007/s11015-010-9322-1.pdf
[7]	RAGHAVAN V. Al-Hf-Ir(Aluminum-Hafnium-Iridium)[J].Journal of Phase Equilibria & Diffusion, 2008, 29(4):368-368. https://www.researchgate.net/publication/243188115_Al-Hf-Ir_Aluminum-Hafnium-Iridium
[8]	LEHN J S, JAVED S, HOFFMAN D M. Synthesis of zirconium, hafnium, and tantalum complexes with sterically demanding hydrazide ligands[J]. Inorganic Chemistry, 2007, 46(3):993-1000. doi: 10.1021/ic061483w
[9]	马天军, 陈振海, 俞世吉, 等.折叠波导行波管铪栅极退火温度及其性能[J].材料热处理学报, 2015, 36(增刊1):213-217. http://www.cnki.com.cn/Article/CJFDTotal-JSCL2015S1042.htm
[10]	罗琳, 李波, 孙宝莲, 等.高纯铪中微量硅的钼蓝分光光度法研究[J].河南化工, 2015(5):60-62. http://www.cqvip.com/QK/92519X/199904/3722197.html
[11]	王可可, 李亮莎, 黄宏亮, 等.铪金属-有机骨架材料的孔尺寸调控及其吸附性能[J].化工学报, 2014, 65(5):1696-1705. http://www.docin.com/p-929091828.html
[12]	车德华, 徐刚, 徐盛明.溶剂萃取法分离锆铪技术进展[J].有色金属工程, 2014(1):75-80. https://www.wenkuxiazai.com/doc/df1b408880eb6294dd886c61.html
[13]	田丽森, 尹延西, 胡志方, 等.高纯金属铪制备技术研究进展[J].矿冶, 2014, 23(2):49-54. http://d.wanfangdata.com.cn/Periodical_ky201402012.aspx
[14]	蒋亚芳, 张杰, 苏兴智.脉冲加热-红外法测定钽、铌中氢量[J].硬质合金, 2010, 27(6):376-379. http://industry.wanfangdata.com.cn/dl/Detail/Periodical?id=Periodical_yzhj201006011
[15]	翟可新, 王勇, 刘元清, 等.惰性气体熔融-热导/红外法同时测定钛合金中氧氮氢[J].冶金分析, 2015, 35(2):27-30. http://industry.wanfangdata.com.cn/dl/Detail/Periodical?id=Periodical_yjfx201502006
[16]	李婷, 徐开群.红外-热导联合法测定煤中碳氢氮含量的原理解析[J].煤质技术, 2012(1):25-28. http://www.cqvip.com/QK/98010A/201201/41021462.html
[17]	刘忠杰, 肖桐, 覃庆泽.焊缝金属中可扩散氢含量的试验研究[J].兵器材料科学与工程, 2003, 2(5):44-45. http://www.doc88.com/p-982460284041.html
[18]	曹红福, 朱建龙.影响钢中氢含量的因素[J].江苏冶金, 2000, 28(4):28-29. http://www.doc88.com/p-80029909270.html
[19]	张小英, 陈鹏.铜合金中氢含量的测定[J].冶金分析, 1995, 15(6):57-58. http://www.cnki.com.cn/Article/CJFDTOTAL-YJFX506.025.htm
[20]	何雄杰.钛及钛合金中氧和氢的联合测定[J].钛工业进展, 2006, 23(1):32-34. http://www.cqvip.com/QK/90541X/200601/21224549.html
[21]	GB/T4698. 15-2011, 海绵钛、钛及钛合金化学分析方法氢量的测定[S].
[22]	商雪松, 仇慧群, 郭恺.脉冲加热-热导法测定金属中氢含量的研究[J].黑龙江科学, 2015(2):28-29. doi: 10.3969/j.issn.1674-8646.2015.02.012
[23]	李素娟, 朱跃进.脉冲热导法测定铝及铝合金中氢[J].冶金分析, 2002, 22(5):58-59. http://bianke.cnki.net/Web/Article/HXFJ201104019.html
[24]	王虹.惰性气体中熔样-热导法测定锆中氢的含量[J].理化检验(化学分册), 2014(6):781-783. http://bianke.cnki.net/OnlineView/Index/7863

[1]	DOU Zhongkun, ZHANG Jialiang, CHEN Yongqiang, WANG Chengyan. Separation of molybdenum and nickel from acidic leaching solution of melted alloy of waste hydrogenation catalyst by solvent extraction[J]. Nonferrous Metals Science and Engineering, 2024, 15(1): 1-7. DOI: 10.13264/j.cnki.ysjskx.2024.01.001
[2]	LIU Li, YANG Tianhui, ZHOU Xi, MENG Ranhao. Effect of hydride on the hydrogen storage performance of Mg₂Ni based alloys[J]. Nonferrous Metals Science and Engineering, 2023, 14(6): 825-832. DOI: 10.13264/j.cnki.ysjskx.2023.06.010
[3]	WANG Buxiang, SHU Qing. Research progress in single-atomic electrocatalytic hydrogen evelution reaction catalyst[J]. Nonferrous Metals Science and Engineering, 2022, 13(5): 92-100. DOI: 10.13264/j.cnki.ysjskx.2022.05.011
[4]	YU Xiangbiao, XIAO Jie, GUO Shaoyu, XIAO Yiyu, LIAO Chunfa, JIANG Pingguo. Study on the preparation of tungsten powder by hydrogen reduction of blue tungsten[J]. Nonferrous Metals Science and Engineering, 2021, 12(3): 35-41. DOI: 10.13264/j.cnki.ysjskx.2021.03.005
[5]	YU Boyuan, ZHANG Jialiang, YANG Cheng, WANG Lihua, CHEN Yongqiang, WANG Chengyan. Research advances on valuable metals recovery from spent hydrogenation catalyst[J]. Nonferrous Metals Science and Engineering, 2020, 11(5): 16-24, 51. DOI: 10.13264/j.cnki.ysjskx.2020.05.003
[6]	YE Shewen, PENG Wenkun, PENG Ziyang, OU Ziran, GUO Ziting, ZENG Qinqin, YANG Hui. Nitrogen-doped carbon-supported ultrafine molybdenum carbide hydrogen evolution reaction catalyst[J]. Nonferrous Metals Science and Engineering, 2020, 11(3): 33-38. DOI: 10.13264/j.cnki.ysjskx.2020.03.004
[7]	SONG Hanlin, JIANG Pingguo, LIU Wenjie, WANG Zhengbing. Research progress on hydrogen reduction kinetics of tungsten oxide[J]. Nonferrous Metals Science and Engineering, 2017, 8(5): 64-69. DOI: 10.13264/j.cnki.ysjskx.2017.05.009
[8]	ZHAO Fei, YANG Junhong, LI Juan. Sample preparation method for determination of oxygen in titanium capillary with inert gas fusion infrared method[J]. Nonferrous Metals Science and Engineering, 2017, 8(2): 128-130. DOI: 10.13264/j.cnki.ysjskx.2017.02.022
[9]	LUO Linshan, ZHOU Jian, WEN Xiaoqiang, LIU Wenwen, ZHOU Jian. Effect of Ti/Cr on hydrogen absorption/desorption properties of(VFe)₅₀Ti_26-xCr_24+x(0≤x≤2.0)hydrogen storage alloys[J]. Nonferrous Metals Science and Engineering, 2016, 7(1): 20-23. DOI: 10.13264/j.cnki.ysjskx.2016.01.005
[10]	DING Ying. The utilization of rare earth from waste hydrogen-nickel battery cathode materials[J]. Nonferrous Metals Science and Engineering, 2013, 4(3): 96-100. DOI: 10.13264/j.cnki.ysjskx.2013.03.020

Cited By

Get Citation

PDF

XML

Article Metrics

Article views (88) PDF downloads (3)

Determination of hydrogen content of hafnium by inert gas fusion infrared method

Abstract

References

Related Articles

Catalog

Article Metrics

Related

Determination of hydrogen content of hafnium by inert gas fusion infrared method

Abstract

References

Related Articles

Catalog

Article Metrics

Related

Export File

Citation

Format

Content