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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 5 Issue 3
Jun.  2014
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YIN Yanhonga, WU Zipinga, ZHAO Mana, XUE Fei-honga, GUO Xianga. Preparation and photocatalytic performance of ultrafine tungsten oxide[J]. Nonferrous Metals Science and Engineering, 2014, 5(3): 50-55. DOI: 10.13264/j.cnki.ysjskx.2014.03.009
Citation: YIN Yanhonga, WU Zipinga, ZHAO Mana, XUE Fei-honga, GUO Xianga. Preparation and photocatalytic performance of ultrafine tungsten oxide[J]. Nonferrous Metals Science and Engineering, 2014, 5(3): 50-55. DOI: 10.13264/j.cnki.ysjskx.2014.03.009
shu

Preparation and photocatalytic performance of ultrafine tungsten oxide

  • a.

    School of Materials Science and Engineering

  • b.

    Engineering Research Center of High-efficiency Development and Application Technology of Tungsten Resources (Ministry of Education), Jiangxi University of Science and Technology, Ganzhou 341000, China

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  • Received Date: January 18, 2014
  • Published Date: June 29, 2014
    Graphical Abstract
    • Abstract
  • Sodium tungstate and hydrochloric acid are used as raw materials, carbon nanotubes as template, tungsten acid and carbon nanotube composite are prepared respectively by using one-step and two-step method, and then roasted at 600 ℃ for 2 h under oxygen atmosphere. The average particle size of tungsten acid and carbon nanotubes composite prepared one and two step methods are 10 nm and 100 nm respectively. The average particle size of tungsten oxide powders are 250 nm and 2 μm respectively. The specific surface area of tungsten oxide powders is 36.53 m2/g and 13.99 m2/g respectively. The photocatalytic performance of tungsten oxide is studied by the UV-Vis spectrophotometer using 11W fluorescent light as the light source. The degradation rate of tungsten oxide powders can reach 93.8 % and 79.1 %. The physical absorption and photocatalytic activity of tungsten oxide prepared by one-step method is better than that of two-step method because of its smaller particle diameter and higher specific surface area.
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    • References (23)
  • [1]
    Yan A H, Xie C S, Zeng D W, et al. Synthesis, formation mechanism and sensing properties of WO3 hydrate nanowire netted-spheres[J].Materials Research Bulletin, 2010, 45: 1541-1547. doi: 10.1016/j.materresbull.2010.05.026
    [2]
    宋旭春, 王芸, 林深, 等.氧化钨纳米颗粒和纳米线的选择合成及光致发光研究[J].稀有金属材料与工程, 2007, 36(3): 10-11. http://www.cnki.com.cn/Article/CJFDTOTAL-COSE2007S3004.htm
    [3]
    Bi Y F, Li D D, Nie H. Preparation and catalytic properties of tungsten oxides with different morphologies[J]. Materials Chemistry and Physics, 2010, 123: 225-230. doi: 10.1016/j.matchemphys.2010.03.086
    [4]
    Hidayt D, Purwanto A, Wang W N, et al. Preparation of size-controlled tungsten oxide nanoparticles and evaluation of their adsorption performance[J]. Materials Research Bulletin, 2010, 45: 165-173. doi: 10.1016/j.materresbull.2009.09.025
    [5]
    王醒东, 郑华均, 钟金环, 等.纳米WO3的结构、制备及应用前景[J].化工新型材料, 2009, 37(2): 15-17. http://mall.cnki.net/magazine/Article/HGXC200902006.htm
    [6]
    Yu B, Tang H L, Kong Z P, et al. Preparation and characterization of three-dimensional mesoporous crystals of tungsten oxide[J]. Chemical Physics Letters, 2005, 407: 83-86. doi: 10.1016/j.cplett.2005.03.066
    [7]
    Che G, Lakshmi B B, Martin C R, et al. Chemical vapor deposition based synthesis of carbon nanotubes and nanofibers using a template method[J]. Chem. Mater., 1998, 10: 260-267. doi: 10.1021/cm970412f
    [8]
    Yue Y F, Qiao Z A, Fulvio, et al. Template-free synthesis of hierarchical porous metal-organic frameworks[J]. J Am Chem. Soc., 2013, 135: 9572-9575. doi: 10.1021/ja402694f
    [9]
    Balamurugan J, Pandurangan A, Thangamuthu R, et al. Effective synthesis of well-graphitized carbon nanotubes on bimetallic SBA-15 template for use as counter electrode in dye-sensitized solar cells[J]. Ind. Eng. Chem. Res., 2013, 52: 384-393. doi: 10.1021/ie3021973
    [10]
    李静, 李利军, 高艳芳, 等.模板法制备纳米材料[J].材料导报, 2011, 25: 5-9. http://mall.cnki.net/magazine/Article/CLDB2011S2001.htm
    [11]
    Ajayan P M, Stephan O, Redlich P H, et al. Carbon nanotubes as removable templates for metal oxide nanocomposites and nanostructures [J]. Nature, 1995, 375: 564-567. doi: 10.1038/375564a0
    [12]
    Lijima S. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354: 56-58. doi: 10.1038/354056a0
    [13]
    Li J, Zhao Q L, Zhang G Y, et al. Synthesis of monoclinic WO3 nanosphere hydrogen gasochromic film via a sol-gel approach using PS-b-PAA diblock copolymer as template[J]. Solid State Sciences, 2010, 12: 1393-1398. doi: 10.1016/j.solidstatesciences.2010.05.016
    [14]
    Li J H, Lee K I, Lu X K, et al. In-situ growth of pine-needle-like tungsten oxide nanowire arrays on carbon nanofibers[J].Materials Letters, 2013, 99: 131-133. doi: 10.1016/j.matlet.2013.02.077
    [15]
    桂阳海, 崔瑞立, 牛连杰, 等.碳纳米管掺杂纳米WO3气敏材料的制备及其应用[J].化工新型材料, 2011, 9: 62-64. http://mall.cnki.net/magazine/Article/HGXC201109017.htm
    [16]
    尹艳红, 吴子平, 羊建高.超声场辅助制备碳纳米管/氧化钨纳米棒高效光催化剂的研究[J].有色金属科学与工程, 2012, 3(5): 39-44. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201205008
    [17]
    尹艳红, 吴子平, 羊建高, 等.一种以模板法制备超细氧化钨的方法:中国, ZL201110192047.9[P].2013-10-02.
    [18]
    Tao L, Xue S S, Jinne A, et al. Steering on-surface polymerization with metal-directed template[J]. J Am Chem. Soc, 2013, 135: 3576-3582 doi: 10.1021/ja311890n
    [19]
    宋继梅, 张小霞, 焦剑, 等.三氧化钨纳米片的制备及其光催化性质研究[J].安徽大学学报(自然科学版), 2009, 33(3): 73-77. http://www.cnki.com.cn/Article/CJFDTOTAL-AHDX200903020.htm
    [20]
    Salmaoui S, Sediri F, Neji G, et al. Hexagonal hydrated tungsten oxide nanomaterials: Hydrothermal synthesis and electrochemical properties [J]. Electrochimica Acta, 2013, 108: 634-643. doi: 10.1016/j.electacta.2013.07.086
    [21]
    Wu Z P, Xia B Y, Wang X X, et al. Preparation of dispersible double-walled carbon nanotubes and application as catalyst support in fuel cells[J]. J Power Sources, 2010, 195: 2143-2148. doi: 10.1016/j.jpowsour.2009.10.013
    [22]
    Wu Z P, Wang J N, Ma J. Methanol-mediated growth of carbon nanotubes [J]. Carbon, 2008, 47 (1): 324-327. https://www.researchgate.net/profile/Jie_Ma11/publication/222167328_Methanol-mediated_growth_of_carbon_nanotubes/links/00b7d51e0c129a0cfb000000.pdf?origin=publication_list
    [23]
    刘守新, 刘鸿.光催化及光电催化基础与应用[M].北京:化学工业出版社, 2006: 136-174.
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