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Volume 24 Issue 3-4
Oct.  2010
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XIANG Ping, FENG Qi-ming, NIU Yin-jian, XIAO Gong-ming, LIU Wei-qi. Sulphuric Acid Leaching of (from Zinc Electrolysis Anode Slime Using PbS as a Reductant[J]. Nonferrous Metals Science and Engineering, 2010, 24(3-4): 92-96.
Citation: XIANG Ping, FENG Qi-ming, NIU Yin-jian, XIAO Gong-ming, LIU Wei-qi. Sulphuric Acid Leaching of (from Zinc Electrolysis Anode Slime Using PbS as a Reductant[J]. Nonferrous Metals Science and Engineering, 2010, 24(3-4): 92-96.
shu

Sulphuric Acid Leaching of (from Zinc Electrolysis Anode Slime Using PbS as a Reductant

  • 1.

    School of Mineral Processing and Bioengineering, Central South University, Changsha 410083, China

  • 2.

    Xiangqi Research Institute for Comprehensive Utilization of Mineral Resources, Zhuzhou 412005, China

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  • Received Date: July 22, 2010
  • Published Date: October 30, 2010
    Graphical Abstract
    • Abstract
  • An investigation into leaching of MnO2 from zinc electrolysis anode slime in Zhuzhou Zinc smelter in sulphuric acid solution using PbS as a reductant was carried out. The effects of the fineness of PbS particle, the molar ratio of PbS to MnO2, the molar ratio of H2SO4 to MnO2, the reaction time and temperature etc. on the leaching rate of Mn were discussed in the batch test that used pure PbS as the reductante. The results revealed that the finer the PbS particles were, the more contact area of PbS particles to MnO2 was, and so the faster the leaching speed of Mn was obtained. The results also showed that the molar ratio of PbS to MnO2, the molar ratio of H2SO4 to MnO2, the reaction time and temperature etc. had significant influence on the leaching speed of Mn. The optimal leaching conditions were obtained using 0.5 molar ratio of PbS to MnO2 and 3 molar ratio of H2SO4 to MnO2 for 120min at 90℃. At the optimal leaching conditions using 0.037 ~0.074mm pure PbS as the reductant, more than 85% of Mn leaching rate could be obtained. At the same conditions using PbS flotation concentrates as the reductant, more than 93% of Mn leaching rate could be obtained. The leaching test using PbS flotation concentrate as the reductant showed that the synergistic reductive extraction of ZnS and FeS caused the content of impurities in filtrate be upgraded, as well as the content of Pb in leaching slag be reduced. So that, in order to produce high-purity manganese products using Mn2+-containing leaching solution, as well as to facilitate leaching slag into the furnace smelting, it is better to adopt a higher grade flotation concentrate of PbS as the reductant.
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    • References (24)
  • [1]
    赵永, 蒋开喜, 王德全, 等.添加锌电解阳极泥对ZnS浸出过程的影响[J].东北大学学报:自然科学版, 2006, 27(1):61-64. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2006&filename=DBDX200601015&v=MjQyNTZZWVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUkwyZVplUnRGaURoV3J2T0lTL1Bkckc0SHRmTXJvOUU=
    [2]
    关亚君.锌阳极泥过量对电锌酸浸影响的理论探讨与改进实践[J].湖南有色金属, 2006, 22(3):25-27. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2006&filename=HNYJ200603007&v=MjA3MjNMdXhZUzdEaDFUM3FUcldNMUZyQ1VSTDJlWmVSdEZpRGhXNzdCTFNQU1pMRzRIdGZNckk5Rlk0UjhlWDE=
    [3]
    彭小苏.锌电解阳极电积MnO2的研究[J].有色金属(冶炼部分), 2001, 3:2-4. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2001&filename=METE200103000&v=MDU5OTh6SktDamZhN0c0SHRETXJJOUZaSVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUkwyZVplUnRGaURoVzc=
    [4]
    黄开国, 王秋风.从锌浸出渣中浮选回收银[J].中南工业大学学报:自然科学版, 1997, 6:530-532. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD9697&filename=ZNGD706.005&v=MDU2ODJPVFJMaWRaZVptRXlEblVBPT1QeVBNYXJTNEdNL01yNG9xRjU0T2ZnZzV6aEFVNGpoNE9YNlRySDAzZWI=
    [5]
    张万生.锌浸出渣浮选银生产实践[J].湖南有色金属, 2000, (S1): 86-90. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2000&filename=HNYJ2000S1029&v=MDg4MDVMMmVaZVJ0RmlEaFc3ckxMU1BTWkxHNEh0R3ZybzlIYllSOGVYMUx1eFlTN0RoMVQzcVRyV00xRnJDVVI=
    [6]
    倪恒发, 张小虎, 张全胜.从锌浸出渣中浮选回收银的实践[J].资源再生, 2008, (2):28-29. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2008&filename=JSZS200802013&v=MTAzMzZaNFI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUkwyZVplUnRGaURoVzd2T0x6N1JmYkc0SHRuTXJZOUU=
    [7]
    王淼生, 郑团, 周继刚.锌阳极泥制取碳酸锰的研究[J].广东有色金属学报, 1997, 7(2):125-130. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD9697&filename=GDYS199702008&v=Mjg2MzQ5RmJJUjhlWDFMdXhZUzdEaDFUM3FUcldNMUZyQ1VSTDJlWmVSdEZ5bmtVcjdBSWluU2ZiS3hGOWJNclk=
    [8]
    廖云军, 梅光贵, 刘荣义.锌电解过程中减少锰离子贫化及对阳极泥返回利用的研究[J].中国锰业, 1999, 19(1): 33-36. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD9899&filename=ZGMM901.006&v=Mjk5MTBoNE9YNlRySDAzZWJPVFJMaWRaZWR2RmlubVVBPT1QeXJHWTdxNEg4L01yNGtxRjU0T2ZnZzV6aEFVNGo=
    [9]
    沈慧庭, 覃华, 黄晓毅, 等.某含锰冶金渣中锰和铅的综合回收研究[J].金属矿山, 2009, (6):171-175. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2009&filename=JSKS200906055&v=MzE2OTZZWVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUkwyZVplUnRGeW5rVXIzTkx6N0FmYkc0SHRqTXFZOUE=
    [10]
    Bafghi M S, Zakeri A, Ghasemi Z, Adeli M. Reductive Dissolution of Manganese Ore in Sulfuric Acid in the Presence of Iron Metal[J]. Hydrometallurgy, 2008, 90(2-4) : 207-212. doi: 10.1016/j.hydromet.2007.07.003
    [11]
    袁明亮, 邱冠周.软锰矿直接还原浸出的研究[J].矿产综合利用, 2000, 5:4-7. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2000&filename=KCZL200005002&v=MDA0NTkxRnJDVVJMMmVaZVJ0Rnlua1Vyck1MaTdSWXJHNEh0SE1xbzlGWm9SOGVYMUx1eFlTN0RoMVQzcVRyV00=
    [12]
    黄佩芳, 马集成, 滕英才.硫铁矿和锰矿浓硫酸熟化法生产硫酸锰[J].广西大学学报:自然科学版, 2002, 27(1):39-41. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2002&filename=GXKZ200201009&v=MTgyMTkxRnJDVVJMMmVaZVJ0Rnlua1Vydk9JalhBZExHNEh0UE1ybzlGYllSOGVYMUx1eFlTN0RoMVQzcVRyV00=
    [13]
    Pande A M, Gupta K N, Altekar V A. Single Cell Extraction of Zinc and Manganese Dioxide from Zinc Sulphide Concentrate and Manganese ores[J]. Hydrometallurgy, 1982, 9(1):57-68. doi: 10.1016/0304-386X(82)90053-6
    [14]
    李军旗.硫化锌精矿和软锰矿同时浸出机理[J].有色金属, 1996, 48(2):90-93. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD9697&filename=YOUS602.017&v=MDM1MjFiT1RSTGlkWmVkdkZpamtXdz09UENMZWZiVzRITS9Ncm9ncUY1NE9mZ2c1emhBVTRqaDRPWDZUckgwM2U=
    [15]
    Kanungo S B, DAS R P. Extraction of Metals from Manganese Nodules of the Indian Ocean by Leaching in Aqueous Solution of Sulphur Dioxide[J]. Hydrometallurgy, 1988, 20(2):135-146. doi: 10.1016/0304-386X(88)90047-3
    [16]
    Abbruzzese C. Percolation Leaching of Manganese Ore by Aqueous Sulfur Dioxide[J]. Hydrometallurgy, 1990, 25(1):85-97. doi: 10.1016/0304-386X(90)90066-B
    [17]
    Veglio F, Toro L. Fractional Factorial Experiments in the Development of Manganese Dioxide Leaching by Sucrose in Sulphuric Acid Solutions[J]. Hydrometallurgy, 1994, 36(2): 215-230. doi: 10.1016/0304-386X(94)90007-8
    [18]
    Momade F W Y, Momade Zs G. Reductive Leaching of Manganese Oxide Ore in Aqueous Methanol Sulphuric Acid Medium[J]. Hy -drometallurgy, 1999, 51(1): 103-113.
    [19]
    Sahoo R N, Naik P K, Das S C. Leaching of Manganese from Lowgrade Manganese Ore using Oxalic Acid as Reductant in Sulphuric Acid Solution[J]. Hydrometallurgy, 2001, 62(3): 157-163. doi: 10.1016/S0304-386X(01)00196-7
    [20]
    Ismail A A, Ali E A, Abrahim I A, Ahmed M S. A Comparative Study on Acid Leaching of Low Grade Manganese Ore Using Some Industrial Wastes as Reductants[J]. The Canadian Journal of Chemical Engineering, 2008, 82(6):1296-1300. doi: 10.1002/cjce.5450820618
    [21]
    徐本军, 覃文庆, 邱冠周.方铅矿和软锰矿两矿法浸出工艺的研究[J].矿产保护与利用, 2005, (3) :29-33. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2005&filename=KCBH200503008&v=MDU4MTh6QkxpN0packc0SHRUTXJJOUZiSVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUkwyZVplUnRGeW5rVTc=
    [22]
    唐尚文.用闪锌矿(方铅矿)精矿催化还原软锰矿(大洋锰结核矿)制取硫酸锰[J].无机盐工业, 2005, 37(6):46-49. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFD2005&filename=WJYG200506023&v=MDc4NTlOTWlmU2FiRzRIdFRNcVk5SFo0UjhlWDFMdXhZUzdEaDFUM3FUcldNMUZyQ1VSTDJlWmVSdEZ5bmtVN3I=
    [23]
    胡全红, 刘坚, 屈芸.方铅矿的两矿法浸出动力学研究[J].矿冶工程, 2007, 27(4):61-63. http://d.wanfangdata.com.cn/Periodical/kygc200704015
    [24]
    王少芬. 硫化矿发电浸出过程工艺及其基础理论研究[D]. 长沙: 中南大学, 2003. http://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CDFD&dbname=CDFD9908&filename=2004116114.nh&v=MDgwMTMzcVRyV00xRnJDVVJMMmVaZVJ0Rnlua1VMN0tWMTI3R3JLNUdORE5xNUViUElSOGVYMUx1eFlTN0RoMVQ=
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