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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 11 Issue 6
Dec.  2020
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CHAI Xiaojun, WANG Minghua, LI Jinqiong, HAN Zhuo, PENG Guanghuai, LIAO Jinsheng, WEN Herui. Preparation and near-infrared luminescence properties of Y2MgTiO6: Mn4+/ Nd3+[J]. Nonferrous Metals Science and Engineering, 2020, 11(6): 48-56. DOI: 10.13264/j.cnki.ysjskx.2020.06.007
Citation: CHAI Xiaojun, WANG Minghua, LI Jinqiong, HAN Zhuo, PENG Guanghuai, LIAO Jinsheng, WEN Herui. Preparation and near-infrared luminescence properties of Y2MgTiO6: Mn4+/ Nd3+[J]. Nonferrous Metals Science and Engineering, 2020, 11(6): 48-56. DOI: 10.13264/j.cnki.ysjskx.2020.06.007
shu

Preparation and near-infrared luminescence properties of Y2MgTiO6: Mn4+/ Nd3+

  • School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

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  • Received Date: June 13, 2020
  • Published Date: December 30, 2020
    Graphical Abstract
    • Abstract
  • A series of Y2MgTiO6:Mn4+/Nd3+ down-conversion materials were prepared by traditional high-temperature solid-phase reaction. The steady-state excitation emission spectra and transient fluorescence lifetime were analyzed. During the energy transfer process of Mn4+→Nd3+, the infrared emission of 885 nm and 1 085 nm generated by Nd3+ under the excitation of 331 nm corresponds to 4F3/2→4I11/2 and 4F3/2→4I9/2 energy level transition. The results confirmed that the luminescence intensity of Y2MgTiO6 doped with Mn4+ and Nd3+ at 1 085 nm was 5 times stronger than that of Y2MgTiO6 doped with Nd3+. Furthermore, the energy transfer from Mn4+ to Nd3+ is mainly achieved by the electric dipole-dipole mechanism of resonance energy transfer. The near-infrared emitting down-conversion material Y2MgTiO6: Mn4+/Nd3+ is very useful for the luminescence conversion layer of crystalline silicon solar cells.
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    • References (32)
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