Founded in 1987, Bimonthly
Supervisor:Jiangxi University Of Science And Technology
Sponsored by:Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN:1674-9669
CN:36-1311/TF
CODEN YJKYA9
LI Jinqiong, WEN Herui, KONG Liyun, PENG Guanghuai, LIAO Jinsheng. Preparation and Characterization of LaF3:Eu3+ red phosphors as white LED[J]. Nonferrous Metals Science and Engineering, 2018, 9(5): 97-102. DOI: 10.13264/j.cnki.ysjskx.2018.05.016
Citation: LI Jinqiong, WEN Herui, KONG Liyun, PENG Guanghuai, LIAO Jinsheng. Preparation and Characterization of LaF3:Eu3+ red phosphors as white LED[J]. Nonferrous Metals Science and Engineering, 2018, 9(5): 97-102. DOI: 10.13264/j.cnki.ysjskx.2018.05.016

Preparation and Characterization of LaF3:Eu3+ red phosphors as white LED

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  • Received Date: March 27, 2018
  • Published Date: October 30, 2018
  • Nanophosphors LaF3:Eu3+ with hexagonal structure have been prepared by hydrothermal method.The properties of the resulting phosphors are characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), photoluminescence (PL) spectra and decay curve.The excitation spectra of LaF3:Eu3+ phosphors are mainly consists of the band at about 250 nm that corresponding to O2-→Eu3+ charge-transfer (CT) and some sharp lines of Eu3+ f-f transitions in the near ultraviolet region with one intense peak at about 396 nm.The emission spectra were used to probe the local environments of Eu3+ ion in LaF3 crystal.Based on the emission and excitation spectra at 298K, it is identified that the lattice site of Eu3+ in tetragonal LaF3 nanocrystals descending from D4h to approximate C2v as a result of the lattice distortion.Under the 396 nm excitation, strong red emission peaked at 591 nm attributed to 5D07F1 transition of Eu3+ are observed for 10 % LaF3:Eu3+ phosphors as the optimal doping concentration.The luminescence properties show that LaF3:Eu3+ phosphor may be considered to be a potential red phosphor candidate for near-UV light emitting diodes (LEDs).
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