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Supervisor：Jiangxi University Of Science And Technology
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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 11 Issue 3
Jun.  2020
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ZHAO Chaonan, ZHANG Wenqi, YANG Jiancheng, SHANG Zhitong, LIANG Tongxiang, LI Xiaocheng. Preparation and lithium-storage performance of attapulgite-derived Si@C composite[J]. Nonferrous Metals Science and Engineering, 2020, 11(3): 52-58. DOI: 10.13264/j.cnki.ysjskx.2020.03.007
Citation: ZHAO Chaonan, ZHANG Wenqi, YANG Jiancheng, SHANG Zhitong, LIANG Tongxiang, LI Xiaocheng. Preparation and lithium-storage performance of attapulgite-derived Si@C composite[J]. Nonferrous Metals Science and Engineering, 2020, 11(3): 52-58. DOI: 10.13264/j.cnki.ysjskx.2020.03.007
shu

Preparation and lithium-storage performance of attapulgite-derived Si@C composite

  • a.

    Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

  • b.

    Jiangxi Key Laboratory of Power and Materials, Jiangxi University of Science and Technology, Ganzhou 341000, China

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  • Received Date: March 15, 2020
  • Published Date: June 29, 2020
    Graphical Abstract
    • Abstract
  • Silicon is considered as one of the most promising anode materials of next generation lithium-ion battery (LIBs) due to its extremely high theoretic capacity. However, its applications in LIBs are hindered by the high-cost and harsh synthesis conditions of silicon nanomaterials. In this paper, the natural attapulgite was selected as the precursor for the synthesis of silicon nanoparticles (MRR Si) via hydrothermal purification process followed by magnesium reduction process. By adopting chemical vapor deposition, MRR Si@C composite was prepared and its electrochemical performance was evaluated. Results indicate that the synthesized MRR Si can deliver a high discharge capacity of 2 362 mAh/g under a current density of 0.2 A/g with a coulombic efficiency (CE) of 71.87%. After 100 cycles at 0.5 A/g, the MRR Si-based electrode can deliver a capacity of 909 mAh/g. After the deposition of carbon film, the resulted MRR Si@C composite can deliver a high capacity of 2 494 mAh/g with an enhanced CE of 78.92% and a high capacity of 1 324 mAh/g after 100 cycles at 0.5 A/g. More importantly, the MRR Si@C composite can still remain a high capacity of 844 mAh/g at a high current density of 5 A/g, implying a good rate capability and promising applications of MRR Si in LIBs.
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    • References (33)
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