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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
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CODEN YJKYA9
Volume 10 Issue 4
Aug.  2019
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HAN Xiuxiu, ZHANG Tingan, LYU Guozhi, PAN Xijuan. A comparative study of alumina prepared from aluminum chloride solution by electrotransformation method and by sodium hydroxide titration method[J]. Nonferrous Metals Science and Engineering, 2019, 10(4): 16-21. DOI: 10.13264/j.cnki.ysjskx.2019.04.003
Citation: HAN Xiuxiu, ZHANG Tingan, LYU Guozhi, PAN Xijuan. A comparative study of alumina prepared from aluminum chloride solution by electrotransformation method and by sodium hydroxide titration method[J]. Nonferrous Metals Science and Engineering, 2019, 10(4): 16-21. DOI: 10.13264/j.cnki.ysjskx.2019.04.003
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A comparative study of alumina prepared from aluminum chloride solution by electrotransformation method and by sodium hydroxide titration method

  • Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education), Northeastern University, Shenyang 110819, China

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  • Received Date: March 26, 2019
  • Published Date: August 30, 2019
    Graphical Abstract
    • Abstract
  • At present, there are many methods for preparing alumina from aluminum chloride solution in our country. However, these methods have some shortcomings, such as producing waste acid and salt, requiring demanding preparation conditions, producing toxic and harmful substances in the reaction, and so on. In this case, inspired by the chlorine-alkali industry, Northeastern University has proposed a new method for the preparation of alumina by electrochemical conversion of AlCl3 aqueous solution. And the method has been verified experimentally. This paper investigates the differences in infrared spectrum and particle size distribution of alumina precursor prepared by electrochemical transformation and the one prepared by sodium hydroxide titration. At the same time, this paper also studies the differences in phase, morphology and particle size between the two kinds of alumina precursors. The results show that the alumina precursors prepared by the two methods contained Al element and Al-OH bond, and the precursors' roasted products are all alumina. In addition, compared with alumina prepared by sodium hydroxide titration, the morphology of alumina prepared by electrochemical transformation is more regular and flake-like, while the shape of alumina prepared by sodium hydroxide titration is irregular. Meanwhile, alumina and its precursor prepared by electrochemical transformation have smaller particle size and more regular particle size distribution than those prepared by sodium hydroxide titration.
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  • [1]
    樊青枝.我国氧化铝工业的生产现状及发展战略[J].山西财经大学学报, 2000, 22(4):38-39. doi: 10.3969/j.issn.1007-9556.2000.04.013
    [2]
    商连弟, 武换荣, 张艳红.中国化学品氧化铝生产现状及发展趋势[J].无机盐工业, 2009, 41(12):11-13. doi: 10.3969/j.issn.1006-4990.2009.12.004
    [3]
    陆钦芳.我国氧化铝工业的现状及发展对策[C]//沈阳: 沈阳铝镁设计院, 中国有色金属学会学术会议. 1997. http://cpfd.cnki.com.cn/Article/CPFDTOTAL-ZGYY199710001033.htm
    [4]
    王彧.我国氧化铝市场现状及发展方向[J].中国高新技术企业, 2012(14):10-11. http://d.old.wanfangdata.com.cn/Periodical/zggxjsqy201214003
    [5]
    祖树正.铝土矿资源合理开发利用的探讨[J].江西有色金属, 1999, 13(2):12-14. doi: 10.3969/j.issn.1674-9669.1999.02.004
    [6]
    陶英君, 杨玉华.我国氧化铝工业现状与发展建议——第三次全国工业普查资料分析[J].轻金属, 1998(7):3-9. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800460283
    [7]
    朱妍, 霍云波. 2015年氧化铝市场回顾及展望[J].中国有色金属, 2016(7):50-51. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjsgy201607016
    [8]
    车玲.我国氧化铝工业技术现状与发展趋势[J].世界有色金属, 2005(5):14-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sjysjs200505004
    [9]
    WU X, MENG X, DING J, et al. Preparation of core-shell structured amorphous aluminum hydroxide ultra-fine powders via a microwave-hydrothermal route[J]. Materials Letters, 2011, 65(14): 2133-2135. doi: 10.1016/j.matlet.2011.04.072
    [10]
    江琦, 雷蕾.醇盐水解-水热法制备高结晶度纳米氢氧化铝[J].材料导报:纳米与新材料专辑, 2008(3): 23-25. http://d.old.wanfangdata.com.cn/Periodical/cldb2008z3008
    [11]
    LEE J S, KIM H S, PARK N K, et al. Low temperature synthesis of α -alumina from aluminum hydroxide hydrothermally synthesized using [Al(C2O4)x(OH)y] complexes[J]. Chemical Engineering Journal, 2013, 230: 351-360. doi: 10.1016/j.cej.2013.06.099
    [12]
    PANASYUK G P, AZAROVA L A, VOROSHILOV I L, et al. Preparation of nanocrystalline aluminum hydroxide and alumina by thermal and vapor heat treatments of reaction products of terephthalic acid and aluminum hydroxide[J]. Inorganic Materials, 2011, 47(3): 273-278. doi: 10.1134/S0020168511020129
    [13]
    KINOSHITA K, MINAMI H, TARUTANI Y, et al. Preparation of aluminum hydroxide and alumina particles in an ionic liquid[J]. Chemistry Letters, 2010, 39(7): 741-743. doi: 10.1246/cl.2010.741
    [14]
    KINOSHITA K, MINAMI H, TARUTANI Y, et al. Preparations of polystyrene/aluminum hydroxide and polystyrene/alumina composite particles in an ionic liquid[J]. Langmuir, 2011, 27(8): 4474-4480. doi: 10.1021/la200172j
    [15]
    JANG C R, HAN K B, VOICU V, et al. Impregnation of catalytic active components in an ammonia solution during granulation of aluminium hydroxide gel by sol-gel method in hydrocarbon-ammonia moulding column[J]. Revista De Chimie, 2012, 63(12): 1301-1305. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=c4a4dcafd981b22d6785dce5f332e62e
    [16]
    FARAG H K, Al ZOUBI M, ENDRES F. Sol-gel synthesis of alumina, titania and mixed alumina/titania in the ionic liquid1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulphonyl) amide[J]. Journal of Materials Science, 2009, 44 (1):122-128. doi: 10.1007/s10853-008-3107-y
    [17]
    王莉, 张丽云.水热法制备氢氧化铝晶须研究[J].科学技术与工程, 2011, 11(24): 5906-5909. doi: 10.3969/j.issn.1671-1815.2011.24.038
    [18]
    王凌云, 童东绅, 祝军兵, 等.氢氧化铝的制备方法及应用[J].浙江化工, 2014(12):24-29. doi: 10.3969/j.issn.1006-4184.2014.12.007
    [19]
    CASTRUITA G, ERERA-MERCADO Y A, SAUCEDO-SALAZAR E M, et al. Sol-gel aluminum hydroxides and their thermal transformation studies for the production of alpha-alumina[J]. Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23(5): 1145-1152. doi: 10.1007/s10904-013-9905-y
    [20]
    SUZUKI T, TAMAGAWA S. Aluminum hydroxide gel particle and production method thereof: US, 13/759 447[P]. 2013-02-05.
    [21]
    ZHANG Y, ZHANG T A, DREISINGER D, et al. Chelating extraction of vanadium(Ⅴ) from low pH sulfuric acid solution by Mextral 973H[J]. Separation and Purification Technology, 2018, 190:123-135. doi: 10.1016/j.seppur.2017.07.016
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