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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 14 Issue 1
Feb.  2023
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LI Kaibin, LIU Fupeng, MA Shuaibing, CHEN Feixiong. Selective roasting transformation to extract lithium from LiNi0.815Co0.15Al0.035O2 anode material of waste Tesla battery[J]. Nonferrous Metals Science and Engineering, 2023, 14(1): 40-50. DOI: 10.13264/j.cnki.ysjskx.2023.01.006
Citation: LI Kaibin, LIU Fupeng, MA Shuaibing, CHEN Feixiong. Selective roasting transformation to extract lithium from LiNi0.815Co0.15Al0.035O2 anode material of waste Tesla battery[J]. Nonferrous Metals Science and Engineering, 2023, 14(1): 40-50. DOI: 10.13264/j.cnki.ysjskx.2023.01.006
shu

Selective roasting transformation to extract lithium from LiNi0.815Co0.15Al0.035O2 anode material of waste Tesla battery

  • Faculty of Materials and Metallurgy Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

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  • Received Date: June 22, 2022
  • Revised Date: August 26, 2022
  • Available Online: March 13, 2023
    Graphical Abstract
    • Abstract
  • To achieve the goals for "carbon peaking and carbon neutrality", the new energy industry has been strongly supported by national policies. With the rapid development of China's lithium new energy industry, the production and scrap volume of lithium-ion batteries, the core components of new energy vehicles, have been increasing. The comprehensive recycling of ternary lithium batteries, containing a large amount of valuable metals and hazardous wastes, are of both economic and environmental benefits. The traditional pyrometallurgy has the disadvantages of high energy consumption, high lithium loss rate and heavy pollution, and the routine hydrometallurgy also has the problems of long process, complex purification process, low comprehensive lithium recovery rate and a large amount of wastewater. At present, LiNi0.5Co0.2Mn0.3O2 (NCM) ternary anode materials are taken as the main research objects, while the recovery of new aluminum-containing Tesla battery materials is rarely reported. Therefore, with the typical Tesla ternary anode material LiNi0.815Co0.15Al0.035O2 (NCA) as raw material, carbon and hydrogen reducing agents, the lithium in waste lithium batteries was selectively extracted and recovered by reduction and roasting transformation—selective lithium extraction processes. Comparisons were conducted from the perspectives of reduction roasting and leaching methods, economic cost and environmental aspects. The results show that, by carbon reduction and roasting-selective lithium extraction process, the extraction rates of Li, Ni, Co and Al are 97.84%, 0.45%, 0.36% and 0.75%, respectively, at a carbon content of 15.0%, temperature of 700 ℃ and roasting time of 90 mins. The transition temperature is rather low when NCA materials are treated by hydrogen reduction roasting selective lithium extraction process. The extraction rate of Li is 95.97% and that of Al 8.65%, but the extraction rates of Ni and Co are both less than 0.5% at a roasting temperature of 500℃, hydrogen flow rate of 300 mL/min in the same roasting time. Meanwhile, no pollution gas such as CO and CO2 is generated in the products. Therefore, hydrogen reduction roasting has a large potential for industrial applications.
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    • References (28)
  • [1]
    SWAIN B. Recovery and recycling of lithium: a review[J]. Separation & Purification Technology, 2017, 172: 388-403.
    [2]
    SONOC A, JESWIET J. A Review of Lithium supply and demand and a preliminary investigation of a room temperature method to recycle lithium-ion batteries to recover lithium and other materials[J]. Procedia CIRP, 2014, 15: 289-293. doi: 10.1016/j.procir.2014.06.006
    [3]
    ALEXANDRU, SONOC, JACK, et al. Opportunities to improve recycling of automotive lithium ion batteries[J]. Procedia Cirp, 2015, 29: 752-757. doi: 10.1016/j.procir.2015.02.039
    [4]
    GRUBER P W, MEDINA P A, KEOLEIAN G A, et al. Global lithium availability[J]. Journal of Industrial Ecology, 2011, 15(5): 760-775. doi: 10.1111/j.1530-9290.2011.00359.x
    [5]
    林若虚. 锂离子电池正极材料简介及标准布局浅析[J]. 中国金属通报, 2021(8): 107-109. https://www.cnki.com.cn/Article/CJFDTOTAL-JSTB202108053.htm
    [6]
    李方昊, 杨建元. 废旧锂电池正极材料回收研究进展[J]. 现代化工, 2021, 41(1): 90-94. https://www.cnki.com.cn/Article/CJFDTOTAL-XDHG2021S1019.htm
    [7]
    MESHRAM P, PANDEY B D, MANKHAND T R. Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: A comprehensive review[J]. Hydrometallurgy, 2014, 150: 192-208. doi: 10.1016/j.hydromet.2014.10.012
    [8]
    A T T, A D S, C H O, et al. Distributions of lithium-ion and nickel-metal hydride battery elements in copper converting[J]. Journal of Cleaner Production, 2017, 168: 399-409. doi: 10.1016/j.jclepro.2017.09.051
    [9]
    ZHENG Y, SONG W, Mo W T, et al. Lithium fluoride recovery from cathode material of spent lithium-ion battery[J]. RSC Advances, 2018, 8(16): 8990-8998. doi: 10.1039/C8RA00061A
    [10]
    ZENG X, LI J, SINGH N. Recycling of spent lithium-ion battery: a critical review[J]. Critical Reviews in Environmental Science & Technology, 2013, 10(44): 1129-1165.
    [11]
    ZHANG X, XIE Y, LIN X, et al. An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries[J]. Mater. Cycles Waste Manage, 2013, 15(4): 420-430. doi: 10.1007/s10163-013-0140-y
    [12]
    HEYDARIAN A, MOUSAVISM, VAKILCHAP F, et al. Application of a mixed culture of adapted acidophilic bacteria in two-step bioleaching of spent lithium-ion laptop batteries[J]. Journal of Power Sources, 2018, 378: 19-30. doi: 10.1016/j.jpowsour.2017.12.009
    [13]
    TIRRONEN T, SUKHOMLINOV D, OBRIEN H T, et al. Distributions of lithium-ion and nickel-metal hydride battery elements in copper converting[J]. Clean. Prod, 2017, 168: 399-409. doi: 10.1016/j.jclepro.2017.09.051
    [14]
    周弋惟, 陈卓, 徐建鸿. 湿法冶金回收废旧锂电池正极材料的研究进展[J]. 化工学报, 2022, 73(1): 85-96. https://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ202201007.htm
    [15]
    XIN Y, GUO X, CHEN S, et al. Bioleaching of valuable metals Li, Co, Ni and Mn from spent electric vehicle Li-ion batteries for the purpose of recovery[J]. Journal of Cleaner Production, 2016, 116: 249-258. doi: 10.1016/j.jclepro.2016.01.001
    [16]
    DUTTA D, KUMARI A, PANDA R, et al. Close loop separation process for the recovery of Co, Cu, Mn, Fe and Li from spent lithium ion batteries[J]. Separation and Purification Technology, 2018, 200: 327-334. doi: 10.1016/j.seppur.2018.02.022
    [17]
    ORDONEZ J, GAGO E J, GIRARD A. Processes and technologies for the recycling and recovery of spent lithium-ion batteries[J]. Renewable and Sustainable Energy Reviews, 2016, 60: 195-205. doi: 10.1016/j.rser.2015.12.363
    [18]
    陈艳, 胡显智. 电子废料中贵金属的回收利用方法[J]. 中国矿业, 2006(12): 102-104. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKA200612030.htm
    [19]
    TORKAMAN R, ASADOLLAHZADEH M, TORAB MOSTAEDI M, et al. Recovery of cobalt from spent lithium-ion batteries by using acidic and basic extract ants in solvent extraction process[J]. Separation and Purification Technology, 2017, 186: 318-325. doi: 10.1016/j.seppur.2017.06.023
    [20]
    CHEN M, WANG R, QI Y, et al. Cobalt and lithium leaching from waste lithium-ion batteries by glycine[J]. Journal of Power Sources, 2021, 482: 228942. doi: 10.1016/j.jpowsour.2020.228942
    [21]
    MUSARIRI B, AKDOGAN G, DORFLING C, et al. Evaluating organic acids as alternative leaching reagents for metal recovery from lithium-ion batteries[J]. Minerals Engineering, 2019, 137: 108-117. doi: 10.1016/j.mineng.2019.03.027
    [22]
    崔鹏媛, 俞小花, 冯天意, 等. 废旧三元锂电池正极材料的回收再生研究[J]. 有色金属工程, 2022, 12(6): 151-159. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS202206019.htm
    [23]
    QUIJADA-MALDONADO E, OLEA F, R SEPúLVEDA, et al. Possibilities and Challenges for ionic liquids in hydrometallurgy[J]. Separation and Purification Technology, 2020, 251: 117289.
    [24]
    YADAV D, BANERJEE R. A comparative life cycle energy and carbon emission analysis of the solar carbon thermal and hydrometallurgy routes for zinc production[J]. Applied Energy, 2018, 229, 577-602.
    [25]
    PENG C, LIU F, WANG Z, et al. Selective extraction of lithium (Li) and preparation of battery grade lithium carbonate (Li2CO3) from spent Li-ion batteries in nitrate system[J]. Journal of Power Sources, 2019, 415(3): 179-188.
    [26]
    NAN J, HAN D, ZUO X. Recovery of metal values from spent lithium-ion batteries with chemical deposition and solvent extraction[J]. Journal of Power Sources, 2005, 152(12): 278-284.
    [27]
    HU J T, ZHANG J l, LI H X, et al. A promising approach for the recovery of high value-added metals from spent lithium-ion batteries[J]. Journal of Power Sources, 2017, 351(3): 192-199.
    [28]
    LIU F P, PENG C, MA Q X, et al. Selective lithium recovery and integrated preparation of high-purity lithium hydroxide products from spent lithium-ion batteries-ScienceDirect[J]. Separation and Purification Technology, 2021, 259: 118181.
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