Founded in 1987, Bimonthly
Supervisor:Jiangxi University Of Science And Technology
Sponsored by:Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN:1674-9669
CN:36-1311/TF
CODEN YJKYA9
YAO Shiwen, HUANG Wenjin, SHU Bo, XIA Shubiao. Graphene-supported Ni-based polyoxometalate anode material and its electrochemical performance[J]. Nonferrous Metals Science and Engineering, 2020, 11(5): 134-141. DOI: 10.13264/j.cnki.ysjskx.2020.05.019
Citation: YAO Shiwen, HUANG Wenjin, SHU Bo, XIA Shubiao. Graphene-supported Ni-based polyoxometalate anode material and its electrochemical performance[J]. Nonferrous Metals Science and Engineering, 2020, 11(5): 134-141. DOI: 10.13264/j.cnki.ysjskx.2020.05.019

Graphene-supported Ni-based polyoxometalate anode material and its electrochemical performance

More Information
  • Received Date: July 25, 2020
  • Published Date: October 30, 2020
  • The energy crisis is currently an important issue of global concern. Lithium-ion battery (LIB) has become the most popular new energy technology due to its high energy density, good cycle life, and environmental friendliness. Although the commercial carbon anode can effectively reduce the formation of lithium dendrites, it still fails to meet the increasing demand for energy storage density. Therefore, designing and synthesizing new electrode materials for LIB is one of the key issues to break the bottleneck of high-energy LIB. In this work, a graphene-supported polyoxometalate-organic framework material (Ni-POMs) was successfully synthesized and used for the anode of LIB. Scanning electron microscopy (SEM) analysis showed that Ni-POMs material has a regular hexagonal prism shape, and X-ray diffraction (XRD) test results showed that the diffraction peak of the experimental samples were consistent with computer simulated one. After the graphene was loaded, the morphology of its sample was partially damaged, but the hexagonal prism shape could still be observed. At a current density of 100 mA/g, the specific discharge capacity of Ni-POMs could reach 717 mAh/g after 50 cycles. At a current density of 800 mA/g, a capacity retention rate of 82.2% could be maintained after 500 cycles. After graphene loaded, the cycle performance and rate performance of Ni-POMs@GO materials further improved. The material cycle stability of Ni-POMs@GO electrode mainly attributes to its unique porous characteristics and high chemical stability. Loaded graphene provides an electron transport channel for the materials, which further improves its electrochemical performance.
  • [1]
    段建峰, 钟盛文, 曾敏. 20Ah富锂锰动力电池的性能研究[J].有色金属科学与工程, 2013, 4(2): 37-40. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201302008
    [2]
    GOODENOUGH J B. Electrochemical energy storage in a sustainable modern society[J]. Energy & Environmental Science, 2014, 7: 14-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d9cfa1da5d1a86b3e32e9ea9d16faef3
    [3]
    ARMAND M, TAEASCON J M. Building better batteries[J]. Nature, 2008, 451: 652-657. doi: 10.1038/451652a
    [4]
    李俊莉, 黄文进, 杨润芳, 等. Mn掺杂Co0.9Mn0.1P/RGO复合电极材料的合成及其电化学性能[J].江西冶金, 2020, 40(1): 22-26. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jxyj202001005
    [5]
    BOLES M A, ENGEL M, TALAPIN D V. Self-assembly of colloidal nanocrystals: from intricate structures to functional materials[J]. Chemical Reviews, 2016, 116: 11220-11289. doi: 10.1021/acs.chemrev.6b00196
    [6]
    KONG L, ZHONG M, SHUANG W, et al. Electrochemically active sites inside crystalline porous materials for energy storage and conversion[J]. Chemical Society Reviews, 2020, 49:2378. doi: 10.1039/C9CS00880B
    [7]
    LI C, LIU L, KANG J, et al. Pristine MOF and COF materials for advanced batteries[J]. Energy Storage Materials, 2020, 31: 115-134. doi: 10.1016/j.ensm.2020.06.005
    [8]
    JI Y, MA Y, LIU R, et al. Modular development of metal oxide/carbon composites for electrochemical energy conversion and storage[J]. Journal of Materials Chemistry A, 2019, 87: 13096. http://pubs.rsc.org/en/content/articlepdf/2019/ta/c9ta03498f
    [9]
    YUE Y, LI Y, BI Z, et al. A POM-organic framework anode for Li-ion battery[J]. Journal of Materials Chemistry A, 2015(3): 22989-22995. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=51798a83f7ed47666e808b40dfa75e41
    [10]
    WANG H, HAMANAKA S, NISHIMOTO Y, et al. In Operando X-ray absorption fine structure studies of polyoxometalate molecular cluster batteries: polyoxometalates as electron sponges[J]. Journal of the American Chemical Society, 2012, 134: 4918-4924. doi: 10.1021/ja2117206
    [11]
    XIE J, ZHANG Y, HAN Y, et al. High-capacity molecular scale conversion anode enabled by hybridizing cluster-type framework of high loading with amino-functionalized graphene[J]. ACS Nano, 2016, 10: 5304-5313. doi: 10.1021/acsnano.6b01321
    [12]
    XIA G, LIU D, ZHENG F, et al. Preparation of porous MoO2@C nano-octahedrons from a polyoxometalate-based metal-organic framework for highly reversible lithium storage[J]. Journal of Materials Chemistry A, 2016(4): 12434-12441. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7485c12183aee767f195b5587a3e94d7
    [13]
    JI Y, HU J, HUANG L, et al. Covalent attachment of anderson-type polyoxometalates to single-walled carbon nanotubes gives enhanced performance electrodes for lithium ion batteries[J]. Chemistry: A European Journal, 2015, 21: 6469-6474. doi: 10.1002/chem.201500218
    [14]
    WANG Y, ZHAGN M LI S, et al. Diamondoid-structured polymolybdate-based metal-organic frameworks as high-capacity anodes for lithium-ion batteries[J]. Chemical Communications, 2017, 53: 5204-5207. doi: 10.1039/C6CC10208E
    [15]
    HARTUNG S, BUCHER N, CHEN H, et al. Vanadium-based polyoxometalate as new material for sodium-ion battery anodes[J]. Journal of Power Sources, 2015, 288: 270-277. doi: 10.1016/j.jpowsour.2015.04.009
    [16]
    CHEN W, HUANG L, HU J, et al. Connecting carbon nanotubes to polyoxometalate clusters for engineering high-performance anode materials[J]. Physical Chemistry Chemical Physics, 2014, 16: 19668-19673. doi: 10.1039/C4CP03202K
    [17]
    HU J, JIA F, SONG Y. Engineering high-performance polyoxometalate/PANI/MWNTs nanocomposite anode materials for lithium ion batteries[J]. Chemical Engineering Journal, 2017, 326: 273-280. doi: 10.1016/j.cej.2017.05.153
    [18]
    CHENJ, SYMES M D, FAN S, et al. High-performance polyoxometalate-based cathode materials for rechargeable lithium-ion batteries[J]. Advanced Materials, 2015, 27: 4649-4654. doi: 10.1002/adma.201501088
    [19]
    ZHANG M, ZHANG A M, WANG X X, et al. Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage[J]. Journal of Materials Chemistry A, 2018(6): 8735-8741. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d49cd73fc28ca0abb190fd61858362b1
    [20]
    HUANG B, YANG D H, HAN B H. Application of polyoxometalate derivatives in rechargeable batteries[J]. Journal of Materials Chemistry A, 2020(8): 4593.
    [21]
    ZHU P, YANG X, LI X, et al. Insights into the lithium diffusion process in a defect-containing porous crystalline POM@MOF anode material[J]. Daltion Transsctions, 2020, 49:79. doi: 10.1039/C9DT04163J
    [22]
    SAMANIYAN M, MIRZAEI M, KHAJAVIAN R, et al. Heterogeneous catalysis by polyoxometalates in metal-organic frameworks[J]. ACS Catalysis, 2019(9):10174-10191.
    [23]
    LIU Y Z, YAO W, GAN H M, et al. Polyoxometalates-based metal-organic frameworks made by electrodeposition and carbonization methods as cathodes and anodes for asymmetric supercapacitors[J]. Chemistry: A European Journal, 2019, 25: 16617-16624. doi: 10.1002/chem.201903664
  • Cited by

    Periodical cited type(0)

    Other cited types(1)

Catalog

    Article Metrics

    Article views (101) PDF downloads (4) Cited by(1)
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return