Founded in 1987, Bimonthly
Supervisor:Jiangxi University Of Science And Technology
Sponsored by:Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN:1674-9669
CN:36-1311/TF
CODEN YJKYA9
LI Wei, ZHANG Xiaolin, NING Rui. Experimental study on thallium removal from ammonium perrhenate[J]. Nonferrous Metals Science and Engineering, 2019, 10(3): 21-25. DOI: 10.13264/j.cnki.ysjskx.2019.03.004
Citation: LI Wei, ZHANG Xiaolin, NING Rui. Experimental study on thallium removal from ammonium perrhenate[J]. Nonferrous Metals Science and Engineering, 2019, 10(3): 21-25. DOI: 10.13264/j.cnki.ysjskx.2019.03.004

Experimental study on thallium removal from ammonium perrhenate

More Information
  • Received Date: March 19, 2019
  • Published Date: June 29, 2019
  • Ammonium perrhenate extracted from copper smelting acid contains a certain amount of Tl element which affects the quality of ammonium perrhenate and limits the end application of rhenium products. In this paper, a traditional adsorption method was used to remove Tl: activated carbon, TiO2, KI and XH30 resin were used to carry out static absorption tests. On this basis, the effects of rhenium solution concentration, adsorption linear velocity and rhenium solution pH on the dynamic adsorption of Tl by using XH30 resin were investigated. The results showed that the adsorption effect on Tl by using activated carbon and KI was not ideal, and the adsorption rates of Tl by using TiO2 and XH30 resin for long-term dynamic adsorption were 96.9 % and 97.95 %, respectively. Tl was adsorbed with XH30 resin column. When [Re] was 10 g/L, [Tl], roughly 5 mg/L, pH, 8.5, and linear velocity of adsorption, controlled at 8 cm/min, the Tl removal rate could stand stable at 93.4 % and the grade of recrystallized ammonium perrhenate remained above 99.99 %.
  • [1]
    ASHRAM A. The hydrometallurgical extraction of rhenium from copper industrial wastes[J]. JOM., 2008, 60(8) :52-54. doi: 10.1007/s11837-008-0108-x
    [2]
    ABISHEVA Z S, ZAGORODNYAYA A N, BEKTURGANOV N S. Review of technologies for rhenium recovery from mineral raw materials in kazakhstan[J]. Hydrometallurgy, 2011, 109(1/2):1-8. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=2afffd9262932b73de8bde5c1a8f5513
    [3]
    郑欣, 白润, 王东辉, 等.航天航空用难熔金属材料的研究进展[J].稀有金属材料与工程, 2011, 40(10): 1871-1875. http://d.old.wanfangdata.com.cn/Periodical/xyjsclygc201110040
    [4]
    黄翀, 陈其慎, 李颖, 等.2030年全球及中国铼资源需求刍议[J].中国矿业, 2014, 2(9):9-11. doi: 10.3969/j.issn.1004-4051.2014.09.003
    [5]
    杨登峰, 崔涛, 把发栋, 等.冶炼烟气制酸废水零排放并回收铼酸铵[J].硫酸工业, 2015(1):64-66. doi: 10.3969/j.issn.1002-1507.2015.01.020
    [6]
    张小林, 李伟, 吕重安, 等.用D990从污酸中吸附回收铼实验研究[J].中国有色冶金, 2017(1): 65-68. doi: 10.3969/j.issn.1672-6103.2017.01.016
    [7]
    肖祈春, 肖国光, 余侃萍, 等.含铊废水污染及其治理技术[J].矿冶工程, 2015, 35:33-35. http://d.old.wanfangdata.com.cn/Periodical/kygc2015z1009
    [8]
    王成彦, 陈永强.中国铅锌冶金技术状况及发展趋势:节能潜力[J].有色金属科学与工程, 2017, 8(3): 1-5. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201610015
    [9]
    刘烨.饮用水中铊污染的净化技术研究[D].广州: 广东工业大学, 2013. http://cdmd.cnki.com.cn/Article/CDMD-11845-1013214092.htm
    [10]
    王松, 陈家昌, 戴振宇, 等.铊污染地下水的微生物修复研究[J].地球与环境, 2018(3):282-287. http://d.old.wanfangdata.com.cn/Periodical/dzdqhx201803010
    [11]
    BAI M, LIU Z H, ZHOU L J, et al. Preparation of ultrafine rhenium powders by CVD hydrogen reduction of volatile rhenium oxides[J]. Trans.Nonferrous Met.So., 2013, 23: 538-542. doi: 10.1016/S1003-6326(13)62496-6
    [12]
    张小林, 宁瑞, 李伟.用离子交换与萃取法直接从污酸中回收铼实验[C]//中国有色金属冶金第1届学术会仪, 2016, 222-225.
    [13]
    郭株辉, 沈裕军, 冯洁.从某铜矿伴生铼所产低等品中提取高纯铼酸铵的技术研究[J].中国钼业, 2015, 39(4):31-35. http://d.old.wanfangdata.com.cn/Periodical/zgmy201504007
    [14]
    陆少鸣, 赵田甜, 孟建宾.去除饮用水中金属铊的研究[J].净水技术, 2009, 27(4):25-27. doi: 10.3969/j.issn.1009-0177.2009.04.008
    [15]
    邵立南, 杨晓松, 胡建龙, 等.复合纳米吸附深度除铊技术研究[J].环境保护科学, 2016, 42(2):75-78. http://d.old.wanfangdata.com.cn/Periodical/hjbhkx201602016
    [16]
    巢猛, 胡小芳, 余素华.粉末活性炭去除原水中铊的试验研究[J].供水技术, 2015, 9(3):1-3. doi: 10.3969/j.issn.1673-9353.2015.03.001
    [17]
    ZITKO V, CARSON W V. Thallium occurrence in the environment and toxicity to fish[J].Bulletin of Environmental Contam inaction and Toxicity, 1975, 13: 23-30. doi: 10.1007/BF01684859
    [18]
    SAGER M.Thallium in agricultural practice.In:NRIAGU J O. Thallium in the Environment[M].New York:John Wiley Sons Inc, 1998, 59-87.
    [19]
    程海军.铊(Ⅰ)在水体中化学氧化特性研究[D].哈尔滨: 哈尔滨工业大学, 2014.
    [20]
    淡维杰, 肖连生, 张贵清, 等.萃取法提取铬(Ⅲ)分离铁(Ⅱ)的研究[J].有色金属科学与工程, 2017, 8(3): 35-41. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=2017030006
  • Related Articles

    [1]REN Kepiao, WANG Jingsong, LI Yan, SHE Xuefeng, XUE Qingguo, ZUO Haibin, WANG Guang. Transport and enrichment of thallium in metallurgical processes[J]. Nonferrous Metals Science and Engineering, 2024, 15(3): 311-321. DOI: 10.13264/j.cnki.ysjskx.2024.03.001
    [2]CAO Caifang, LI Xiaowen, NIE Huaping, LI Laichao, ZHANG Xing, QIU Tingsheng. Study on thermodynamics of anions′ dynamic exchange of tungsten metallurgy system by ion chromatography[J]. Nonferrous Metals Science and Engineering, 2019, 10(4): 1-6. DOI: 10.13264/j.cnki.ysjskx.2019.04.001
    [3]ZONG Yi, XIONG Daoling, WANG Luqi, CAO Xuewen, LIU Jiancong, OUYANG Shaobo, XIONG Shijie. Study on the process of aluminum removal and recovery from waste lithium ion batteries[J]. Nonferrous Metals Science and Engineering, 2018, 9(5): 26-32. DOI: 10.13264/j.cnki.ysjskx.2018.05.005
    [4]CAO Caifang, ZHANG Xing, LI Xiaowen, QIU Xiaochen, LI Yupeng, ZHONG Zhenyu, WANG Yizhao, WANG Jiansong. Thermodynamic study on the adsorption of tungstate by chlorine-type quaternary ammonium resin[J]. Nonferrous Metals Science and Engineering, 2018, 9(3): 1-4, 52. DOI: 10.13264/j.cnki.ysjskx.2018.03.001
    [5]CHEN Zhifeng, LI Jinhui, SHEN Bangpo, LIAO Chunfa. Research progress on technology of removing aluminum from ion adsorption type rare earth ore[J]. Nonferrous Metals Science and Engineering, 2017, 8(2): 112-118. DOI: 10.13264/j.cnki.ysjskx.2017.02.019
    [6]LUO Xian-ping, ZHANG Yan, DENG Yang-wu. Several common ion exchange materials and their application in treatment of ammonia-nitrogen wastewater[J]. Nonferrous Metals Science and Engineering, 2012, 3(6): 51-54,74. DOI: 10.13264/j.cnki.ysjskx.2012.06.021
    [7]YAN Qun, YU Yang, ZHOU Na-na. Research development of arsenic removal from drinking water[J]. Nonferrous Metals Science and Engineering, 2012, 3(3): 74-79. DOI: 10.13264/j.cnki.ysjskx.2012.03.003
    [8]XIA Li-bin, CAI Wei-song. Impurity Removal from Waste Ni-MH Battery Lixivium[J]. Nonferrous Metals Science and Engineering, 2011, 2(1): 32-34.
    [9]TONG Chang-ren, ZHOU Xiao-xue. Mathematical Model and Computer Simulation of Ion Exchange[J]. Nonferrous Metals Science and Engineering, 2006, 20(4): 32-34.
    [10]WANG Rui-xiang, ZENG Oing-yun, LIU Jian-hua. An Experimental Investigation of the Treatment of Complexed Copper-containing Wastewater by Ion-exchange[J]. Nonferrous Metals Science and Engineering, 2003, 17(1): 35-36, 40.
  • Cited by

    Periodical cited type(1)

    1. 丁璨,王成豪,张露露,孙华斌,田浩博,刘骐诺. Mg-Ti共掺杂LiFePO_4电子结构及弹性性质的第一性原理计算. 稀有金属. 2025(03): 389-400 .

    Other cited types(0)

Catalog

    Article Metrics

    Article views (76) PDF downloads (12) Cited by(1)
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return