Citation: | ZHANG Bo, LIU Yi, XIA Shubiao. Effects of heat treatment on the microstructure and mechanical performance of Co-Cr alloy by selective laser melting[J]. Nonferrous Metals Science and Engineering, 2024, 15(2): 265-273. DOI: 10.13264/j.cnki.ysjskx.2024.02.013 |
Heat treatment of laser additive manufactured materials cannot only eliminate thermal stress during the printing process, but also regulate their microstructure and mechanical properties. This article studies the changes in the microstructure of selective laser melted Co-Cr alloy under different heat treatment conditions and its corresponding mechanical properties. It was found that the alloy structure in the as-printed state was γ-austenite, with a large amount of dislocation, sub-grain boundaries, and a small amount of tetragonal σ-CoCr precipitation phase in the matrix. A γ-ε transformation occurred at 1 150 ℃ with a holding time of 1 h, and the volume fraction of ε-martensite was 10.4%. At the same time, the precipitation phase transformed from a tetragonal σ-phase to a hexagonal Co3W(Mo)2Si phase. After further treatment at 800 ℃ for 2 h, the martensite content increased to 15.5%, and the quantity and size of the precipitation phase increased. The influence of the precipitation phase on the mechanical properties after heat treatment was significant. The material's hardness increased from 31 HRC to 38 HRC, and the yield strength increased from 848 MPa to 1 119 MPa. This study can provide a reference for the microstructure and property regulation of Co-based alloys by selective laser melting.
[1] |
王华明. 高性能大型金属构件激光增材制造:若干材料基础问题[J]. 航空学报, 2014, 35 (10): 2690-2698.
|
[2] |
黄卫东,林鑫. 激光立体成形高性能金属零件研究进展[J]. 中国材料进展, 2010, 29(6): 12-27,49.
|
[3] |
巩水利, 锁红波, 李怀学. 金属增材制造技术在航空领域的发展与应用[J]. 航空制造技术, 2013, 56(13): 66-71.
|
[4] |
赵志国, 柏林, 李黎, 等. 激光选区熔化成形技术的发展现状及研究进展[J]. 航空制造技术, 2014, 57(19): 46-49.
|
[5] |
张义文. 3D打印技术在航空发动机上的应用[J]. 粉末冶金工业, 2015, 25(6): 61.
|
[6] |
KRAKHMALEV P, YADROITSAVA I, FREDRIKSSON G, et al. In situ heat treatment in selective laser melted martensitic AISI 420 stainless steels[J]. Materials & Design, 2015, 87: 380-385.
|
[7] |
汪洋, 王远, 张述泉, 等. 激光熔化沉积AerMet100超高强度钢凝固组织及高温稳定性[J]. 金属热处理, 2011, 36(3): 60-63.
|
[8] |
顾冬冬, 戴冬华, 夏木建, 等. 金属构件选区激光熔化增材制造控形与控性的跨尺度物理学机制[J]. 南京航空航天大学学报, 2017, 49(5): 645-652.
|
[9] |
WANG Y M, VOISIN T, MCKEOWN J T, et al. Additively manufactured hierarchical stainless steels with high strength and ductility[J]. Nature Materials, 2018, 17(1): 63-71.
|
[10] |
罗丽娟, 余森, 于振涛, 等. 3D打印钛及钛合金医疗器械的优势及临床应用现状[J]. 生物骨科材料与临床研究, 2015,12(6): 72-75.
|
[11] |
UEKI K, KASAMATSU M, UEDA K, et al. Precipitation during γ-ε phase transformation in biomedical Co-Cr-Mo alloys fabricated by electron beam melting [J]. Metals, 2020, 10(1): 71.
|
[12] |
HARUN W S W, KAMARIAH M S I N, MUHAMAD N, et al. A review of powder additive manufacturing processes for metallic biomaterials [J]. Powder Technology, 2018, 327: 128-151.
|
[13] |
BOSE S, KE D X, SAHASRABUDHE H, et al. Additive manufacturing of biomaterials[J]. Progress in Materials Science, 2018, 93: 45-111.
|
[14] |
SINGH S, RAMAKRISHNA S, SINGH R. Material issues in additive manufacturing: a review[J]. Journal of Manufacturing Processes, 2017, 25: 185-200.
|
[15] |
MENGUCCI P, BARUCCA G, GATTO A, et al. Effects of thermal treatments on microstructure and mechanical properties of a Co-Cr-Mo-W biomedical alloy produced by laser sintering[J]. Journal of the Mechanical Behavior of Biomedical Materials, 2016, 60: 106-117.
|
[16] |
刘爽, 马国武. 3D打印钴铬合金和铸造钴铬合金的理化性能和生物相容性的比较[J]. 口腔医学, 2022, 42(3): 210-214.
|
[17] |
李小宇, 郑美华, 王洁琪, 等. 3D打印和铸造钴铬合金耐蚀性及力学稳定性比较[J]. 中华口腔医学研究杂志(电子版), 2016,10(5): 327-332.
|
[18] |
孙德勤, 陈慧君, 文青草, 等. 耐热铝合金的发展与应用[J]. 有色金属科学与工程, 2018, 9(3): 65-69.
|
[19] |
王井井, 黄元春, 刘宇, 等. 时效工艺对Al-Zn-Mg-Cu-Zr-Er铝合金组织与耐腐蚀性影响[J].有色金属科学与工程, 2018, 9(2): 47-55.
|
[20] |
GAO C, LIU Z, XIAO Z, et al. Effect of heat treatment on SLM-fabricated TiN/AlSi10Mg composites: microstructural evolution and mechanical properties [J]. Journal of Alloys and Compounds, 2021, 853: 156722.
|
[21] |
SHIN W S, SON B, SONG W S, et al. Heat treatment effect on the microstructure, mechanical properties, and wear behaviors of stainless steel 316L prepared via selective laser melting[J]. Materials Science and Engineering: A, 2021, 806: 140805.
|
[22] |
LU Y J, YANG C G, LIU Y J, et al. Characterization of lattice defects and tensile deformation of biomedical Co29Cr9W3Cu alloy produced by selective laser melting [J]. Additive Manufacturing, 2019, 30: 100908.
|
[23] |
KAJIMA Y, TAKAICHI A, KITTIKUNDECHA N, et al. Effect of heat-treatment temperature on microstructures and mechanical properties of Co-Cr-Mo alloys fabricated by selective laser melting [J]. Materials Science and Engineering: A, 2018, 726: 21-31.
|
[24] |
ZHOU Y N, DONG X, LI N, et al. Effects of post-treatment on metal-ceramic bond properties of selective laser melted Co-Cr dental alloy. Part 1: Annealing temperature [J]. The Journal of Prosthetic Dentistry, 2023, 129(4): 657.
|
[25] |
KAJIMA Y, TAKAICHI A, LINN HTATA H, et al. Recrystallization behavior of selective laser melted Co-Cr-Mo alloys with several heat treatment times[J]. Materials Science and Engineering: A, 2022, 856: 143998.
|
[26] |
BOZZOLO N, BERNACKI M. Viewpoint on the formation and evolution of annealing twins during thermomechanical processing of FCC metals and alloys [J]. Metallurgical and Materials Transactions A, 2020, 51: 2665-2684.
|
[27] |
DONG X, ZHOU Y N, QU Y T, et al. Recrystallization behavior and grain boundary character evolution in Co-Cr alloy from selective laser melting to heat treatment[J]. Materials Characterization, 2022, 185: 111716.
|
[28] |
KIM H G, KIM W R, PARK H W, et al. Microstructural study of the nano-scale martensitic lamellar α-Co and ε-Co phases of a Co-Cr alloy fabricated by selective laser melting[J]. Journal of Materials Research and Technology, 2021, 12: 437-443.
|
[29] |
NARUSHIMA T, MINETA S, KURIHARA Y, et al. Precipitates in biomedical Co-Cr alloys[J]. The Journal of The Minerals, Metals & Materials Society, 2013, 65: 489-504.
|
[30] |
HOOPER P A. Melt pool temperature and cooling rates in laser powder bed fusion[J]. Additive Manufacturing, 2018, 22: 548-559.
|
[31] |
SAGE M, GUILLAUD C. Méthode d'analyse quantitative des variétés allotropiques du cobalt par les rayons X [J]. Revue De Métallurgie, 1950, 47(2): 139-145.
|
[32] |
KURZ W, FISHER D J. Dendrite growth at the limit of stability: tip radius and spacing[J]. Acta Metallurgica, 1981, 29(1): 11-20.
|
[33] |
NARUSHIMA T, MINETA S, KURIHARA Y, et al. Precipitates in biomedical Co-Cr alloys[J]. JOM, 2013, 65(4): 489-504.
|
[34] |
WANG Z, TANG S Y, SCUDINO S ,et al. Additive manufacturing of a martensitic Co-Cr-Mo alloy: Towards circumventing the strength-ductility trade-off[J]. Additive Manufacturing, 2021, 37: 101725.
|
[35] |
ACHMAD T L, FU W X, CHEN H, et. al. Computational thermodynamic and first-principles calculation of stacking fault energy on ternary Co-based alloys[J]. Computational Materials Science, 2018, 143: 112-117.
|
[36] |
TIAN L Y, LIZÁRRAGA R, LARSSON H, et al. A first principles study of the stacking fault energies for fcc Co-based binary alloys[J]. Acta Materialia, 2017, 136: 215-223.
|
[37] |
MORI M, YAMANAKA K, CHIBA A. Cold-rolling behavior of biomedical Ni-free Co-Cr-Mo alloys: role of strain-induced ε martensite and its intersecting phenomena[J]. Journal of the Mechanical Behavior of Biomedical Materials, 2016, 55: 201-214.
|
[38] |
KAITA W, HAGIHARA K, ROCHA L A, et al. Plastic deformation mechanisms of biomedical Co-Cr-Mo alloy single crystals with hexagonal close-packed structure[J]. Scripta Materialia, 2018, 142: 111-115.
|