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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
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Jiangxi Nonferrous Metals Society
ISSN：1674-9669
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CODEN YJKYA9
Volume 13 Issue 2
Apr.  2022
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LU Jingling, XU Cunying, LI Jianru, XIANG Qinqin, CHEN Xiao, HUA Yixin, ZHANG Qibo, LI Yan. Electrochemical behavior of Ni(Ⅱ) in different ionic liquids[J]. Nonferrous Metals Science and Engineering, 2022, 13(2): 1-9. DOI: 10.13264/j.cnki.ysjskx.2022.02.001
Citation: LU Jingling, XU Cunying, LI Jianru, XIANG Qinqin, CHEN Xiao, HUA Yixin, ZHANG Qibo, LI Yan. Electrochemical behavior of Ni(Ⅱ) in different ionic liquids[J]. Nonferrous Metals Science and Engineering, 2022, 13(2): 1-9. DOI: 10.13264/j.cnki.ysjskx.2022.02.001
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Electrochemical behavior of Ni(Ⅱ) in different ionic liquids

  • Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China

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  • Received Date: July 08, 2021
  • Revised Date: September 10, 2021
  • Available Online: May 09, 2022
    Graphical Abstract
    • Abstract
  • Abstract: The electrochemical behaviors of Ni(Ⅱ) with the addition of NiCl2 to a 1-butyl-3-methylimidazolium chloride-glycerine (BMIC-GL) ionic liquid and a 1-butyl-3-methylimidazolium dicyanamide ([BMIM]DCA) ionic liquid were studied. Voltammetry analysis showed that the reduction potential of Ni(Ⅱ) in [BMIM]DCA-NiCl2 ionic liquids was more positive than that in the BMIC-GL-NiCl2 ionic liquid, indicating that the reduction of Ni(Ⅱ) in [BMIM]DCA-NiCl2 was easier. In addition, the reduction reaction of Ni(Ⅱ) in both ionic liquids was a quasi-reversible process controlled by diffusion, but the diffusion coefficient in BMIC-GL-NiCl2 was 8.92×10-7 cm2/s, which was significantly greater than that in [BMIM]DCA-NiCl2 (2.94×10-7 cm2/s). Current-time transient analysis showed that the electrodeposition of nickel on a glassy carbon electrode in BMIC-GL-NiCl2 ionic liquid followed the three-dimensional instantaneous nucleation mechanism, while that in [BMIM]DCA-NiCl2 conformed to the three-dimensional progressive nucleation mechanism.
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    • References (29)
  • [1]
    ZHANG F, YAO Z, MOLIAR O, et al. Nanocrystalline Ni coating prepared by a novel electrodeposition[J]. Journal of Alloys and Compounds, 2020, 830: 153785. doi: 10.1016/j.jallcom.2020.153785
    [2]
    OMAR I M A, AlFAKIH A M, AZIZ M, et al. Part Ⅱ: Impact of ionic liquids as anticorrosives and additives on Ni-Co alloy electrodeposition: Experimental and DFT study[J]. Arabian Journal of Chemistry, 2021, 14(1): 102909. doi: 10.1016/j.arabjc.2020.11.015
    [3]
    WANG S, ZOU X, LU Y, et al. Electrodeposition of nano-nickel in deep eutectic solvents for hydrogen evolution reaction in alkaline solution[J]. International Journal of Hydrogen Energy, 2018, 43(33): 15673-15686. doi: 10.1016/j.ijhydene.2018.06.188
    [4]
    郭崇武, 陈康. 用亚铁离子和钙离子协同沉淀柠檬酸盐镀镍废水中的配位剂[J]. 电镀与涂饰, 2021, 40(3): 225-228. https://www.cnki.com.cn/Article/CJFDTOTAL-DDTL202103012.htm
    [5]
    LI T, XIAO K, YANG B, et al. Recovery of Ni(Ⅱ) from real electroplating wastewater using fixed-bed resin adsorption and subsequent electrodeposition[J]. Frontiers of Environmental Science & Engineering, 2019, 13(6): 1-12.
    [6]
    王海兰. 电镀行业典型污染场地调查及重金属镍污染修复技术研究[J]. 资源节约与环保, 2017(8): 132-133. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYJH201708077.htm
    [7]
    SHI T, ZOU X, WANG S, et al. Electrodeposition of Sn-Co-Ni and Sn-Co-Zn alloy coatings on copper substrate in a deep eutectic solvent and their characterization[J]. Int. J. Electrochemical Science, 2020, 15: 7493-7507.
    [8]
    REN X, LV Q, LIU B, et al. Preparation of gold catalyst by electrodeposition in[BMIm][TfO] ionic liquid electrolyte: an insightful study of theoretical calculations and experiments[J]. Ionics, 2019, 25(3): 1407-1412. doi: 10.1007/s11581-018-2806-x
    [9]
    AMARASEKARA A S. Acidic ionic liquids[J]. Chemical Reviews, 2016, 116(10): 6133-6183. doi: 10.1021/acs.chemrev.5b00763
    [10]
    卜路霞, 刘恒悦, 金会义, 等. 氯化胆碱-丙二酸离子液体电沉积锌-镍合金[J]. 电镀与涂饰, 2021, 40(9): 665-668. https://www.cnki.com.cn/Article/CJFDTOTAL-DDTL202109001.htm
    [11]
    ZHU Y L, KOZUMA Y, KATAYAMA Y, et al. Electrochemical behavior of Ni(Ⅱ)/Ni in a hydrophobic amide-type room-temperature ionic liquid[J]. Electrochimica Acta, 2009, 54(28): 7502-7506. doi: 10.1016/j.electacta.2009.07.088
    [12]
    BERNASCONI R, MAGAGNIN L. Electrodeposition of nickel from DES on aluminium for corrosion protection[J]. Surface Engineering, 2017, 33(2): 131-135. doi: 10.1080/02670844.2016.1175786
    [13]
    LUKACZYNSKA M, CEGLIA A, VAN D B K, et al. Influence of water content and applied potential on the electrodeposition of Ni coatings from deep eutectic solvents[J]. ElectrochimicaActa, 2019, 319: 690-704. doi: 10.1016/j.electacta.2019.06.161
    [14]
    HE X, ZHANG C, ZHU Q, et al. Electrodeposition of nanocrystalline Ni-Fe alloy coatings based on 1-Butyl-3-methylimidazolium-hydrogen sulfate ionic liquid[J]. Journal of Nanoscienceand Nanotechnology, 2017, 17(2): 1108-1115. doi: 10.1166/jnn.2017.12719
    [15]
    JESMANI S M, AMINI R, ABDOLLAH-POUR H, et al. Effect of current density on Ni-Mo electrodeposition using EMIM[Br][J]. Surface Engineering, 2019, 35(12): 1088-1096. doi: 10.1080/02670844.2019.1644914
    [16]
    ZHENG Y, ZHOU X, LUO Y, et al. Electrodeposition of nickel in air-and water-stable 1-butyl-3-methylimidazolium dibutylphosphate ionic liquid[J]. RSC Advances, 2020, 10(28): 16576-16583. doi: 10.1039/D0RA00351D
    [17]
    XU C, ZHAO J, HUA Y, et al. Electrodeposition of Ni-Mg alloys from 1-butyl-3-methylimidazolium chloride/glycerin eutectic-based ionic liquid[J]. Journal of Solid State Electrochemistry, 2016, 20(3): 793-800. doi: 10.1007/s10008-015-3112-4
    [18]
    ZHU Y L, KATAYAMA Y, MIURA T. Effects of coumarin and saccharin on electrodeposition of Ni from a hydrophobic ionic liquid[J]. Electrochimica Acta, 2014, 123: 303-308. doi: 10.1016/j.electacta.2013.12.181
    [19]
    ABBOTT A P, BALLANTYNE A, HARRIS R C, et al. Bright metal coatings from sustainable electrolytes: the effect of molecular additives on electrodeposition of nickel from a deep eutectic solvent[J]. Physical Chemistry Chemical Physics, 2017, 19(4): 3219-3231. doi: 10.1039/C6CP08720E
    [20]
    ZHANG Q B, YANG C, HUA Y X, et al. Electrochemical preparation of nanostructured lanthanum using lanthanum chloride as a precursor in 1-butyl-3-methylimidazolium dicyanamide ionic liquid[J]. Physical Chemistry Chemical Physics, 2015, 17(6): 4701-4707. doi: 10.1039/C4CP05266H
    [21]
    龚凯, 华一新, 徐存英, 等. Betaine·HCl-6EG-nNiSO4·6H2O低共熔离子液体电沉积镍镀层[J]. 昆明理工大学学报(自然科学版), 2017, 42(5): 1-8. https://www.cnki.com.cn/Article/CJFDTOTAL-KMLG201705001.htm
    [22]
    雷震, 徐存英, 华一新, 等. ChCl-urea-ZnO低共熔溶剂体系的电化学行为[J]. 化工学报, 2017, 68(8): 3301-3309. https://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ201708042.htm
    [23]
    耿笑, 汝娟坚, 华一新, 等. 低共熔溶剂电化学回收废铅膏可控制备铅粉的研究[J]. 有色金属科学与工程, 2021, 12(2): 8-13. doi: 10.13264/j.cnki.ysjskx.2021.02.002
    [24]
    黄晶明, 张晓虎, 田亚斌, 等. Nd(Ⅲ)在NaF-KF熔盐钨电极上电化学行为[J]. 有色金属科学与工程, 2020, 11(5): 127-133. doi: 10.13264/j.cnki.ysjskx.2020.05.018
    [25]
    YE M, DING T, HAO Z, et al. Nucleation and growth mechanism of electrodeposited Ni-W alloy[J]. Transactions of Nonferrous Metals Society of China, 2021, 31(6): 1842-1852. doi: 10.1016/S1003-6326(21)65621-2
    [26]
    田亚斌, 董泉, 叶昌美, 等. NaCl-KCl-MgCl2熔盐Mg2+在钨电极上的电化学还原机理[J]. 有色金属科学与工程, 2019, 10(2): 13-18. doi: 10.13264/j.cnki.ysjskx.2019.02.003
    [27]
    SCHARIFKER B, HILLS G. Theoretical and experimental studies of multiple nucleation[J]. Electrochimica Acta, 1983, 28(7): 879-889. doi: 10.1016/0013-4686(83)85163-9
    [28]
    赵焕, 乔永莲, 董宇, 等. 氯化物三价铬电镀的电化学形核机理[J]. 材料保护, 2019, 52(3): 1-5. https://www.cnki.com.cn/Article/CJFDTOTAL-CLBH201903001.htm
    [29]
    FENG Z, WANG L, LI D, et al. Electrodeposition of Ni-Se in a chloride electrolyte: An insight of diffusion and nucleation mechanisms[J]. Journal of Electroanalytical Chemistry, 2019, 847: 113195.
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