逄启寿, 忻治霖, 林小程, 龚姚腾, 王郅阳. 稀土电解槽电化学三维时变流场数值模拟[J]. 有色金属科学与工程, 2022, 13(3): 152-158. DOI: 10.13264/j.cnki.ysjskx.2022.03.019
引用本文: 逄启寿, 忻治霖, 林小程, 龚姚腾, 王郅阳. 稀土电解槽电化学三维时变流场数值模拟[J]. 有色金属科学与工程, 2022, 13(3): 152-158. DOI: 10.13264/j.cnki.ysjskx.2022.03.019
PANG Qishou, XIN Zhilin, LIN Xiaocheng, GONG Yaoteng, WANG Zhiyang. Numerical simulation of the electrochemical 3D time-varying flow field in a rare earth electrolytic cell[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 152-158. DOI: 10.13264/j.cnki.ysjskx.2022.03.019
Citation: PANG Qishou, XIN Zhilin, LIN Xiaocheng, GONG Yaoteng, WANG Zhiyang. Numerical simulation of the electrochemical 3D time-varying flow field in a rare earth electrolytic cell[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 152-158. DOI: 10.13264/j.cnki.ysjskx.2022.03.019

稀土电解槽电化学三维时变流场数值模拟

Numerical simulation of the electrochemical 3D time-varying flow field in a rare earth electrolytic cell

  • 摘要: 目前对电解槽流场分析建立在气体或金属溶体定量单一流动的假设上,为更真实地表现电解槽在电解过程的流场变化,利用ANSYS Fluent软件对稀土电解槽进行电化学三维时变流场数值模拟研究。以加料镨钕氧化物时刻为初始时间的12 min槽内电化学瞬态三维模拟分析。仿真结果与生产实际相符。得出流场主要流动方式为阳极内侧区域生成气体向上流动,流速常居于最大值;阴极区域生成金属溶体向下流动,流速次之;阳极与阴极之间区域以此形成纵向涡流,流速小于前两者;阳极外侧区域为流动死区,流速最小,坩埚收集区域整体趋于稳定,流速远小于阳极内侧及阴极区域;电解至10 min镨钕氧化物被消耗殆尽,流场速度逐渐减小。

     

    Abstract: The current analysis of the flow field of an electrolytic tank is based on the assumption of a quantitative single flow of gas or metal solvent. To show the flow field changes of the electrolytic tank in the electrolysis process, numerical simulation of the electrochemical 3D time-varying current field for the rare earth analysis tank was studied by ANSYS Fluent software. 3D simulation analysis of electrochemical transients was conducted in a tank for 12 min with the time of adding neodymium praseodymium oxide as the initial time. The simulation result was consistent with the actual production. It is concluded that the main flow mode of the flow field is the upward flow of gas generated in the inner area of the anode, and the flow rate is always at the maximum. The metal solution generated in the cathode area flows downward, whose flow velocity takes second place. The area between the anode and the cathode forms a longitudinal vortex, and the flow velocity is less than the first two. The lateral area of the anode is a flow dead zone with a minimum flow velocity. The crucible collection area tends to be stable overall, and the flow velocity is far smaller than the inner anode and the cathode area. The praseodymium neodymium oxide is consumed up after electrolysis for 10 minutes, and the flow field velocity gradually decreases.

     

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