蒋正帅, 夏飞龙, 张姗姗, 张强, 张敏. 低品位铝土矿的高效脱硫脱硅工艺研究[J]. 有色金属科学与工程, 2022, 13(3): 26-34. DOI: 10.13264/j.cnki.ysjskx.2022.03.004
引用本文: 蒋正帅, 夏飞龙, 张姗姗, 张强, 张敏. 低品位铝土矿的高效脱硫脱硅工艺研究[J]. 有色金属科学与工程, 2022, 13(3): 26-34. DOI: 10.13264/j.cnki.ysjskx.2022.03.004
JIANG Zhengshuai, XIA Feilong, ZHANG Shanshan, ZHANG Qiang, ZHANG Min. Study on efficient desulfurization and desilication process of low-grade bauxite[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 26-34. DOI: 10.13264/j.cnki.ysjskx.2022.03.004
Citation: JIANG Zhengshuai, XIA Feilong, ZHANG Shanshan, ZHANG Qiang, ZHANG Min. Study on efficient desulfurization and desilication process of low-grade bauxite[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 26-34. DOI: 10.13264/j.cnki.ysjskx.2022.03.004

低品位铝土矿的高效脱硫脱硅工艺研究

Study on efficient desulfurization and desilication process of low-grade bauxite

  • 摘要: 通过采用悬浮焙烧-碱浸脱硅的方式对铝土矿进行处理,并研究了焙烧温度、苛碱浓度、碱浸温度对焙烧矿碱浸脱硅的影响。结果表明,悬浮焙烧较优温度为930 ℃,在碱浸脱硅条件下液固比为8∶1,脱硅时间为30 min,苛碱浓度为110 g/L,脱硅温度为95 ℃时,可获得较高脱硅率,可达49.24%。Al2O3损失率为2.03%,精矿铝硅质量比可提至8.21,悬浮焙烧的脱硅精矿实际溶出率最高可达94.79%。采用石灰为脱硅剂,对碱浸脱硅后的碱液进行脱硅后,可对焙烧矿进行循环脱硅利用,脱硅后的精矿铝硅比均可达到7以上,从而使碱液实现了循环利用。

     

    Abstract: Bauxite was treated by suspension roasting alkali leaching desilication, and the effects of roasting temperature, caustic concentration and alkali leaching temperature on baked ore alkali leaching silicon were studied. The results show that with a better temperature of suspension roasting of 930 ℃, when the liquid-solid ratio is 8:1, desilicate time is 30 min, caustic alkali concentration is 110 g/L and desilicate temperature is 95 ℃, a higher esilicate rate can be obtained, up to 49.24%. With the loss rate of Al2O3 down to 2.03%, the concentrate Al/Si can be raised to 8.21, and the actual dissolution rate of suspended baked silica concentrate can reach 94.79%. With lime as the desilication agent, after the desilication of alkali-immersed lyate, the roasting ore can be recycled for cycle desilication. After desilication, the Al/Si ratio of the concentrate can reach more than 7 so that the alkali liquor after desilication can be recycled.

     

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