钕铁硼表面脉冲电沉积Ni镀层工艺及性能研究

Process and properties of Ni coating on NdFeB magnet by surface pulsed electrodeposition

  • 摘要: 基于当前钕铁硼产业的发展需求以及其表面防护技术所面临的问题,引入脉冲电沉积技术,采用脉冲电沉积改善钕铁硼磁体表面耐蚀性,通过优化占空比、频率和电流密度等工艺,获得低缺陷率、高表面综合质量的Ni镀层。镀层腐蚀电位由-894.36 mV提升至-680.0 mV,腐蚀电流密度达3.5×10-6 A/cm2,有效降低了镀层腐蚀倾向和腐蚀速率。结合镀层表面形貌分析发现,占空比和频率调控可降低浓差极化,而电流密度调控则有利于镀层表面质量的提升。

     

    Abstract: Based on the current development needs of NdFeB industry and the problems faced by surface protection technology, pulse electrodeposition technology was introduced in this paper to improve the surface corrosion resistance of NdFeB magnets. Ni coatings with low defect rates and high surface comprehensive quality were obtained by optimizing processes such as duty cycle, frequency and current density. The corrosion potential of the coating increases from -894.36 mV to -680.0 mV, and the corrosion current density reaches 3.5×10-6 A/cm2, which effectively reduces the corrosion tendency and corrosion rate of the coating. Combined with the analysis of the surface microstructure of the coating, it is found that the concentration polarization can be reduced by the regulation of duty ratio and frequency, while the regulation of current density can improve the surface quality of the coating.

     

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