强碱性体系提钒微乳液的制备研究

Preparation of Micro-emulsion Used for Extraction of Vanadium from Strong Base System

  • 摘要: 为了制备能够用于强碱性体系中萃取的微乳液体系,研究了以N263作为表面活性剂,醇类为助表面活性剂,煤油为油相形成的微乳液体系的相行为,考察了表面活性剂浓度、助表面活性剂种类及浓度、内水相盐度及pH、温度等因素对微乳液最大增溶水量的影响,并通过微乳液电导率的测定来考察微乳液的稳定性.结果表明:当N263浓度为10 %、异戊醇浓度为25 %,内水相浓度为(0.4 mol/L NaCl+0.2 mol/L NaOH),温度为T=35 ℃,煤油为油相时所制备的微乳液稳定且增溶水量能到达15 %左右.

     

    Abstract: This paper studies the phase behavior of microemulsion by using N263 as surfactant alcohols as cosurfactant and kerosene as oil phase. We focus the study on the effects of surfactant concentration, co-surfactant kinds and concentration, inner water phase salinity and pH value, on water content of the microemulsion the stability of micro-emulsion is also investigated by measuring the its conductivity. The results shows the microemulsion stays stable and the water content can reach to about 15% under the following conditions: N263 concentration is 10%; isoamyl alcohol concentration is 25%; inner water phase concentration is 0.4mol/L NaCl+0.2mol/ L NaOH; temperature is 35℃; kerosene used as oil phase.

     

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