Al-Ga元素掺杂调控烧结Nd-Fe-B磁性能及微观结构

Modulating microstructure and magnetic properties of sintered Nd-Fe-B magnets through Al-Ga element doping

  • 摘要: 微量低熔点元素掺杂是改善Nd-Fe-B磁体磁性能和微观结构的有效方法。本文通过系统设计和实验分析,深入研究了不同Al-Ga比例掺杂对烧结Nd-Fe-B磁体磁性能和显微结构的影响。结果表明,随着Al-Ga比例的变化,磁体的磁性能呈非线性变化;磁体的微观结构随Ga元素比重的增加得到显著改善,表现为包裹主相晶粒边界的富Nd相增多,主相晶粒外形更加圆润,尖锐棱角及突出部分减少。当添加合金质量比为m(Al)∶m(Ga)=0∶100时,磁体的剩磁、矫顽力和最大磁能积分别为1.387 T、1 358 kA/m和367.7 kJ/m3。研究表明,对Al-Ga比例掺杂的调控能显著影响Nd-Fe-B磁体的磁性能,为高性能磁体的设计提供了新的思路和依据。

     

    Abstract: Doping with trace amounts of low-melting-point elements is an effective method to enhance the magnetic properties and optimize the microstructure of Nd-Fe-B magnets. In this study, the influence of different Al-Ga doping ratios on the magnetic properties and microstructure of sintered magnets was investigated through systematic design and experimental analysis. It was found that the magnetic properties of the magnets show non-linear changes with variations in the Al-Ga ratio. The microstructure of the magnets was significantly improved with an increased proportion of the Ga element, as evidenced by an increase in Nd-rich phases surrounding the boundaries of the main-phase grains and a more rounded appearance of the main-phase grains, as well as a reduction in sharp corners and protruding parts. When the mass ratio of the added alloy is m(Al)∶m(Ga)=0∶100, the remanent magnetization, coercivity and maximum magnetic energy product of the magnets are 1.387 T, 1 358 kA/m and 367.7 kJ/m³, respectively. This study shows that modulating the Al-Ga doping ratio can significantly influence the magnetic properties of Nd-Fe-B magnets, providing new insights and fundamentals for the preparation of high-performance magnets.

     

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