极间距对稀土熔盐电解气泡流场影响的仿真研究及分析

Simulation study and analysis of the influence of electrode spacing on the bubble flow field in rare earth molten salt electrolysis

  • 摘要: 稀土电解过程中电解质的流动情况对电解效率存在一定影响,电解槽通电后阳极处产生的气泡会带动熔融电解质的流动,因此阳极壁表面气泡逸出的速率大小对电解反应的效率存在一定影响,而不同的极间距对应的气泡逸出速率也不同。因此本研究以某有色企业8 kA稀土电解槽为研究对象,探究气泡流场与电解效率之间的关系,传统8 kA稀土电解槽的常用极间距为80~90 mm,为了使研究更严谨,本次仿真实验选取了极间距为75、80、85、90、95 mm的5种电解槽进行流场的仿真模拟分析。结论如下:熔体氧化还原反应在进行到约第25 s时,流场中的涡流达到相对稳定的状态,极间距的变化对熔体流场稳定状态时的最大流速、阴阳电极间涡流面积有较明显的影响。当极间距约为85 mm时,电解质流场的最大稳定流速达到峰值;当极间距达到95 mm时,两极间的涡流面积最大,但此时槽底小涡流被两电极间的涡流分割,不利于稀土单质的收集。仿真结果表明,镨钕体系的8 kA稀土电解槽极间距取值约为85 mm时,下半部分熔体的流动情况能使稀土单质的沉淀收集效率达到最高。

     

    Abstract: In the rare-earth electrolysis process, the flow state of the electrolyte significantly affects the electrolysis efficiency. Once the electrolysis cell is energized, bubbles generated at the anode induce the molten electrolyte in motion. As a result, the bubble escape rate from the anode wall surface, which varies with different electrode spacing, plays a crucial role in the electrolytic efficiency. Therefore, this study focused on an 8 kA rare-earth electrolysis cell from a non-ferrous enterprise as the research object to explore the relationship between the bubble flow field and the electrolytic efficiency. Considering that the conventional electrode spacing for an 8 kA cell typically ranges between 80 and 90 mm, five specific cases with electrode spacings (75, 80, 85, 90, and 95 mm) were selected for flow field simulation and analysis to ensure scientific rigor.The experimental results showed that the eddy current in the flow field reached a relatively stable state at about 25 s of the melt redox reaction, and changes in electrode spacing had a significant impact on the maximum flow velocity and the area of eddy current between the anode and cathode electrodes. Specifically, the stable maximum flow velocity of the electrolyte peaked when the electrode spacing was approximately 85 mm. Although the area of the eddy current between the electrodes reached its maximum at an electrode spacing of 95 mm, the small eddy current at the bottom of the cell was segmented by the inter-electrode vortices, which hindered the collection of rare earth metals. The simulation results showed that for an 8 kA Pr-Nd system electrolysis cell, an electrode spacing of approximately 85 mm optimized the flow in the lower part of the melt, thereby maximizing the precipitation and collection efficiency of metallic rare earth.

     

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