钨尾矿基发泡陶瓷的制备

Preparation of tungsten tailings-based foamed ceramic

  • 摘要: 钨尾矿的大量堆存造成了严重的资源浪费和水土污染问题。本文以钨尾矿为主要原料,高岭土和钾长石为辅助原料,碳化硅(SiC)为发泡剂,通过高温烧结法制备发泡陶瓷,系统地研究了辅助原料含量、SiC掺量、烧结温度和保温时间对发泡陶瓷的影响。实验结果表明,随着4种变量的增加,发泡陶瓷逐渐膨胀,其体积密度和抗压强度均呈下降的趋势。由85%钨尾矿、12%高岭土、3%钾长石和0.3%SiC组成的配方在1 160 ℃下烧结40 min后,发泡陶瓷具有良好性能,其体积密度为0.60 g/cm3,抗压强度为1.28 MPa,研究结果为钨尾矿制备发泡陶瓷提供可靠依据。此外,实验结果还表明,通过调整原料含量和烧结制度,可以有效地调控发泡陶瓷的性能,以期满足其在不同场景的应用需求。

     

    Abstract: The accumulation of substantial quantities of tungsten tailings has led to considerable resource wastage and the contamination of soil and water resources. In this paper, the foamed ceramic was prepared using a high-temperature sintering method with tungsten tailings as the primary raw material, kaolin and potassium feldspar as supplementary materials, and silicon carbide (SiC) as the foaming agent. The study meticulously examined the effects of varying contents of supplementary materials, SiC concentration, sintering temperature, and holding time on the properties of the resulting foamed ceramic. Experimental results indicate that increasing these four variables results in a progressive expansion of the foamed ceramic and a decrease in bulk density and compressive strength. A formulation comprising 85% tungsten tailings, 12% kaolin, 3% potassium feldspar and 0.3% SiC is subjected to sintering at 1160 ℃ for 40 minutes. The resulting foamed ceramic exhibits favorable performance, with a bulk density of 0.60 g/cm3 and a compressive strength of 1.28 MPa. The properties provide a robust foundation for developing foamed ceramic derived from tungsten tailings. Furthermore, the results demonstrate that the performance of foamed ceramic can be effectively tailored by adjusting the raw material composition and sintering parameters, thereby enhancing its suitability for various applications.

     

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