CoP元素添加对Cu-15Ni-8Sn合金耐腐蚀性和高温抗氧化性能的影响

Influence of the corrosion resistance and high temperature oxidation resistance of Cu-15Ni-8Sn alloy with Co or P additions

  • 摘要: 采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)和电化学测试等方法研究了微量Co或P元素添加对Cu-15Ni-8Sn合金的耐腐蚀性能以及高温抗氧化性能的影响。结果表明:微量Co元素的添加可以提高Cu-15Ni-8Sn合金在3.5%NaCl溶液中的耐腐蚀性,而P元素会恶化合金的耐腐蚀性能,这与晶界处第二相的形成紧密相关,在腐蚀过程中,晶界处的第二相充当电偶腐蚀的阴极,参与合金基体阳极的腐蚀溶解,从而导致局部腐蚀的产生,局部腐蚀加重的同时又会导致第二相脱落,促使腐蚀的进一步加重。此外,在500 ℃高温长时间氧化过程中,3组合金的氧化增重基本符合抛物线规律,微量Co元素的添加不会影响Cu-15Ni-8Sn的抗氧化性能,但是微量P元素的添加会恶化合金的抗氧化性能,这是因为在Cu-15Ni-8Sn-0.2P合金中形成的氧化产物与合金表面结合力低,易形成空腔,导致表面鼓包和裂纹的产生,进而加速合金的氧化行为。

     

    Abstract: The influence of trace additions of Co or P elements on the corrosion resistance and high-temperature oxidation resistance of Cu-15Ni-8Sn alloy was investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), and electrochemical testing methods. The results indicate that adding of trace amounts of Co enhances the corrosion resistance of the Cu-15Ni-8Sn alloy in 3.5% NaCl solution. In contrast, adding P deteriorates the alloy's corrosion resistance. This phenomenon is closely related to the formation of second phases at grain boundaries. During the corrosion process, these second phases act as cathodes for galvanic corrosion, participating in the anodic dissolution of the alloy matrix, leading to localized corrosion. The exacerbation of localized corrosion also results in the detachment of second phases, further exacerbating corrosion. Additionally, during prolonged oxidation at 500 ℃, the weight gain of the three alloy compositions follows a parabolic trend. The addition of trace Co does not affect the oxidation resistance of Cu-15Ni-8Sn, whereas the addition of trace P deteriorates the oxidation resistance of the alloy. This is attributed to the low adhesion strength of the oxide products formed in Cu-15Ni-8Sn-0.2P alloy, leading to the formation of voids, surface blistering, and cracking, thereby accelerating the oxidation behavior of the alloy.

     

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