钢铁工业含铬固废在线处置技术开发与评价

Development and evaluation of in-line disposal technology for chromium-containing solid wastes in the iron and steel industry

  • 摘要: 含铬渣尘泥是钢铁工业固废中的典型代表,因其复杂的特性、高重金属含量及庞大的存量,处理难度极大,亟须建立有针对性的含铬固废分类体系,并给出相应的处置路线。本研究建立了含铬固废处置分类体系,并以不锈钢渣、不锈钢粉尘及酸洗污泥等为原料开发了高炉渣浴、AOD渣浴和铁水浴熔融处置技术的零固废再生在线处置工艺。结果表明:在热量平衡方面,AOD渣浴所需总热量最小,为117.2 kJ/kg,铁浴所需的总热量最大,为2 056 kJ/kg。在物质平衡方面,高炉渣浴工艺的主要产物是粒化玻璃碴,当玻璃化率为99%,残渣替代量为50%时,制备胶凝材料后Cr的浸出量为0.017 mg/L。当AOD渣浴工艺的主要产物为Fe-Cr-C合金及低Cr残渣,残渣替代量为30%时,制备胶凝材料后Cr的浸出量基本未检出,胶凝材料的抗压强度为37.5 MPa。铁浴工艺的主要产物为Fe-Cr合金及低Cr残渣,残渣替代量为70%时,制备铸石后Cr的浸出量为0.013 mg/L,抗折强度为135.5 MPa。最后,新定义了综合经济指数CBI,铁浴的CBI最大,表现出了极具竞争力的优势。3种嵌入式在线处置工艺均可实现危固废的低碳、节能、安全、零固废处置,合金产品可用于炼钢流程,残渣可安全用于建材替代原料。

     

    Abstract: Chromium-containing metallurgical dust, slag and sludge represent solid waste in the iron and steel industry. Due to the complex characteristics, high heavy metal content, and large stock, they are tricky to be disposed of. This situation leads to an urgent need to establish a targeted categorization system for chromium-containing solid waste and to provide a corresponding disposal route. This study established a classification system for the disposal of chromium-containing solid waste and developed an online disposal process route for zero solid waste regeneration. This process used stainless steel slag, stainless steel dust, and pickling sludge as raw materials for blast furnace slag bath, AOD slag bath, and iron bath melt disposal technologies. The results show that in terms of heat balance, the AOD slag bath required the slightest total heat of 117.2 kJ/kg, while the iron bath needed the most significant total heat of 2 056 kJ/kg. In terms of material balance, the main product from the blast furnace using slag bath process was granular glass slag, achieving a vitrification rate of 99%. The residue substitution was 50%, and the amount of Cr leached after the preparation of cementitious materials was 0.017 mg/L. The AOD slag bath process mainly produced Fe-Cr-C alloy and low-Cr residue. When the residue substitution was 30%, the amount of Cr leached after the preparation of cementitious materials was virtually undetectable, and its compressive strength was 37.5 MPa. The main products of the iron bath process were Fe-Cr alloy and low Cr residue. When the residue substitution was 70%, the amount of Cr leached after the preparation of cast stone was 0.013 mg/L, and the flexural strength was 135.5 MPa. Finally, a new comprehensive economic index, CBI, was defined. The iron bath had the most considerable CBI value, indicating a competitive advantage. All three embedded online disposal processes can achieve low-carbon, energy-saving, safe, and zero-solid disposal of hazardous solid waste. The alloy products can be used in the steelmaking process, and the residue can be safely used as an alternative raw material for building materials.

     

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