不锈钢的氢脆研究进展

Research progress on hydrogen embrittlement of stainless steel

  • 摘要: 随着氢能产业化进程的加快,制氢、储氢、用氢过程中金属材料氢脆问题逐渐被关注。尽管不锈钢因良好的耐腐蚀性能在石油、化工和能源等领域被广泛使用,但是在临氢环境下,不锈钢的氢脆问题难以避免。关于微观组织、晶界特征分布、第二相粒子等对不锈钢氢脆行为的影响有诸多报道,奥氏体、马氏体和铁素体等不同基体对不锈钢的氢脆影响机制有明显差异。在特定服役环境下,不锈钢成分、组织、工艺和氢脆之间的内在关联尚需深入探讨。文中总结和分析了不同类型不锈钢的氢脆研究现状,探讨了不同基体组织与结构,以及外界环境对不锈钢氢脆的影响,从成分设计和工艺优化两方面提出了调控不锈钢氢陷阱的策略,为进一步开发抗氢脆不锈钢提供理论参考。

     

    Abstract: With the acceleration of the industrialization process of hydrogen energy, the hydrogen embrittlement problem faced by metal materials in hydrogen production, hydrogen storage and hydrogen use has gradually attracted attention. Although stainless steel is widely used in petroleum, chemical and energy fields due to its good corrosion resistance, it is still difficult to avoid the hydrogen embrittlement of stainless steel in the presence of hydrogen. There are many reports on the effects of microstructure, grain boundary characteristic distribution and second-phase particles on the hydrogen embrittlement behavior of stainless steel. There are apparent differences in the hydrogen embrittlement mechanism of different matrix stainless steels such as austenite, martensite and ferrite. The internal relationship between the composition, organization, process and hydrogen embrittlement of stainless steel needs to be further discussed in the specific service environment. In this paper, the research status of hydrogen embrittlement of different types of stainless steel was summarized and analyzed, and the influence of different matrix structures and external environments on hydrogen embrittlement of stainless steel was discussed. The strategy of the regulating hydrogen trap of stainless steel was put forward from two aspects of composition design and process optimization, providing a theoretical reference for further development of hydrogen embrittlement-resistant stainless steel.

     

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