10 kA稀土电解槽通电方式对熔盐电解影响数值仿真

Numerical simulation of the influence of 10 kA rare earth electrolyzer electrification mode on molten salt electrolysis

  • 摘要: 10 kA稀土电解槽是目前企业中使用最为广泛的槽型,以某研究院中的10 kA稀土电解槽为原型,通过商业软件COMSOL的电热耦合仿真模块对该电解槽进行研究,发现原结构电解槽在电解过程中存在电流分布不均的问题,为解决该问题,研究提出一种新型导电板结构方案,同时由于该槽型不是中心对称分布,且最终流入电解质中的电流应控制在10 kA,因此根据通入电流的大小还确定了如下4种结构,即原始结构型、电流均分型、电流2332分布型以及电流1441分布型。根据仿真结果得知电流2332分布时槽内电流密度最高、槽盖板与电解质之间电势差最小,而原结构电流密度最低,槽盖板与电解质之间电势差最高。

     

    Abstract: The 10 kA rare earth electrolyzer is the most widely used type in the enterprise at present. Based on a 10 kA rare earth electrolyzer in a certain research institute, the electrolyzer was studied through the electrothermal coupling simulation module of the commercial software COMSOL. It was found that the original structure had the problem of uneven current distribution in the electrolysis process. In order to solve the problem of low electrolysis efficiency caused by uneven current distribution under the original conductive plate structure, a new conductive plate structure scheme was proposed. Meanwhile, since the 10 kA groove is not centrosymmetrically distributed, and the final current flowing into the electrolyte should be controlled at about 10 kA, according to the size of the incoming current, the following four structures were determined, namely, original structure type, current splitting type, current 2332 distribution type and current 1441 distribution type. According to the simulation results, the current density in the tank is the highest and the potential difference between the tank cover plate and the electrolyte is the smallest when the current 2332 is distributed. The current density of the original structure is the lowest, and the potential difference between the cover plate and the electrolyte is the highest.

     

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