含钛高炉渣资源化利用研究进展及展望

Research progress and prospect of resource utilization of titanium-bearing blast furnace slag

  • 摘要: 含钛高炉渣是典型的大宗工业废弃物,其资源化利用难度高。文中总结了国内外含钛高炉渣的资源利用途径,阐述了硫酸法、稀盐酸法、碱熔盐法、高温选择性结晶分离法、高温碳化-低温氯化法、钛合金合成法、硅-钛溶剂精炼法、NH4HF2-HF浸出水解法、氢氧化钠常压分解法制备二氧化钛和高炉熔融渣直接生产人造石材等工艺过程,并分析了几种工艺的优缺点。通过对目前国内含钛高炉渣现状分析,结合高炉熔融渣直接生产人造石材工艺在基建成本、处理量、产品质量、环保水平、经济和社会效益等方面的优势,提出该工艺为未来实现含钛高炉渣资源化利用的一种前景工艺。

     

    Abstract: Titanium-containing blast furnace slag is a typical bulk industrial waste, and resource utilization is difficult. This paper summarized the resource utilization methods of titanium-containing blast furnace slag at home and abroad. It expounded the sulfuric acid method, dilute hydrochloric acid method, alkali molten salt method, high-temperature selective crystallization separation method, high-temperature carbide-low temperature chloride method, titanium alloy synthesis method, silicon- titanium solvent refining method, NH4HF2-HF leaching and hydrolysis method, sodium hydroxide atmospheric decomposition to prepare titanium dioxide and blast furnace molten slag to produce artificial stone directly. The advantages and disadvantages of several processes were analyzed. Through the analysis of the current situation of domestic titanium-containing blast furnace slag, combined with the advantages of the direct production of artificial stone from blast furnace molten slag in terms of capital construction cost, processing capacity, product quality, environmental protection level, economic and social benefit analysis, a prospective process was proposed for the resource utilization of blast furnace slag in the future.

     

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