离子型稀土矿浸出过程的数值模拟

Numerical simulation on leaching characteristics of ion-absorbed rare earth ore

  • 摘要: 稀土元素具有优异的物理化学性质,包括在光学、电学、磁学性能等方面表现出色,在军工、光纤通信、航天航空等高新技术核心科技领域具有难以替代的作用。当前稀土矿的浸出效率不高,提升其浸出效率并深入了解其内部反应机制具有重要意义。对于深入理解浸出过程的内部反应机制在实验研究中面临直接观察和测量的困难,本工作基于计算流体力学方法融合收缩未反应芯模型构建了二维机理仿真模型,采用经验证的该模型研究浸出过程中的组分变化及孔隙率、浸取剂初速度对浸取过程的影响。结果表明:稀土矿层体积分数在反应600 min后从初始的65%减少至58.4%;稀土矿孔隙率变大时稀土浸出率反而越小;浸取剂入口流速越大稀土浸出率越大,但增幅放缓,在追求较大的稀土浸出率的同时,为了有效控制生产成本,建议入口流速控制在0.004 ~0.006 m/s之间。

     

    Abstract: Rare earth elements exhibit outstanding physical and chemical properties, presenting distinguished performance in optics, electronics, and magnetism, and play an irreplaceable role in cutting-edge technology fields such as defense, optical fiber communication and aerospace. To date, the leaching efficiency of rare earth ore is far away from optimal level. Therefore, it is necessary to exert the utmost effort to improve leaching efficiency and examine internal reaction mechanisms. In fact, it is difficult to investigate internal reaction mechanisms and comprehensively measure the leaching process in experiments. In this work, a two-dimensional mechanistic simulation model based on computational fluid mechanics incorporating the shrinking unreacted core model for ion-type rare earth ore leaching was developed and validated with experimental data. It investigated the evolution of chemical components over time and examined the effects of porosity and the initial velocity of the leaching agent on the leaching process. The results showed that the volume fraction of the rare earth ore decreased from an initial 65% to 58.4% after 600 min of leaching. Contrary to the expectation, the leaching rate decreased with increasing porosity of the rare earth ore. Additionally, it was found that a higher leaching rate could be achieved with a higher inlet flow velocity of the leaching agent, but the extent of the increase slowed down. In the pursuit of a greater rare earth leaching rate, while effectively controlling production costs, it is recommended that the inlet velocity be maintained between 0.004 m/s and 0.006 m/s.

     

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