固体氧化物燃料电池连接体用尖晶石涂层研究进展

Research progress of spinel coatings for solid oxide fuel cell interconnects

  • 摘要: 铁素体不锈钢具有耐高温腐蚀性、易加工成形、成本低廉、热膨胀系数与电池材料匹配等特点,被广泛用作固体氧化物燃料电池(SOFC)连接体。但是,铁素体不锈钢连接体在工作时存在“阴极Cr中毒”、抗氧化性弱等问题,这些问题严重限制了它的广泛应用与长远发展。本文首先概述了铁素体不锈钢连接体的实际应用困境,归纳了解决其应用问题的两大优化策略;其次,针对连接体保护涂层的研究,重点综述了尖晶石涂层的应用,特别是Mn-Cu尖晶石、Mn-Co尖晶石与Cu-Fe尖晶石;最后,对不锈钢连接体尖晶石防护涂层尚存在的缺陷进行了总结,对未来的发展趋势进行了展望,这将加深对尖晶石材料在SOFC连接体涂层应用的认识,并为提高SOFC综合性能和推进SOFC的商业化提供启示。

     

    Abstract: Ferritic stainless steels (FSSs) are widely used as solid oxide fuel cell (SOFC) interconnects because of their high-temperature corrosion resistance, easy machining and forming, low cost and coefficient of thermal expansion (CTE) matching with battery materials, etc. However, there are some problems such as “cathode Cr poisoning” and weak oxidation resistance for FSSs during long-term operation, which seriously limit their wide application and long-term development. This paper introduced the practical application difficulties of FSS interconnects and summarized two optimization strategies to solve these problems. Research of protective coatings for interconnectors focused on the application of spinel coatings, especially Mn-Cu spinel, Mn-Co spinel and Cu-Fe spinel. Finally, the existing defects and the future development trend of the protective spinel coatings of FSSs interconnects were proposed, which would deepen the understanding of the application of spinel coating materials in SOFC interconnects, and would provide some enlightenment for improving the comprehensive performance of SOFC and promoting their commercialization.

     

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