直写成型用碳化硅浆料及其流变性能研究

Rheological properties of SiC suspension for direct ink writing

  • 摘要: 碳化硅(SiC)凭借高强度、轻质性以及耐高温性能等优势已成为时下应用最广泛的陶瓷材料之一。传统的制备方法生产周期长、成本高且难以制造相对复杂结构的陶瓷。本文利用直写成型方法制备三维复杂结构的SiC陶瓷,研究分散剂含量、pH值、固相体积分数和增稠剂等因素对SiC浆料流变性能的影响,制备可打印的SiC浆料并直写成型,获得SiC的三维点阵结构。结果表明:调节分散剂含量能使浆料黏度获得最低值;pH值影响分散剂的解离度进而改变浆料的黏度;固相体积分数越高,打印结构完整性越好;添加甲基纤维素(MC)可增加浆料的黏度和剪切弹性模量,使其可打印。优化的SiC浆料配方为:分散剂聚丙烯酸(PAA)质量分数为0.01%,固相体积分数为63%和MC质量分数为0.04%,pH>10。

     

    Abstract: Silicon carbide is one of the most widely used ceramic materials today due to its excellent properties such as high strength, light weight and high temperature resistance. However, the traditional preparation method has long production cycle, high cost and is difficult to manufacture relatively complex structures. In this paper, the SiC slurry used in direct ink writing was studied to fabricate SiC ceramics with 3D complex structure. The effects of dispersant content, pH, solid loading and thickener on the rheological properties of SiC suspension were investigated. Printable SiC suspension was prepared and direct-written into three-dimensional lattice structures of silicon carbide. The results show that the optimum content of dispersant results in the lowest paste viscosity; pH affects the dissociation of the dispersant to change the viscosity of the paste; the higher the solid loading, the stronger the printable structural integrity; and the addition of methyl cellulose (MC) increases the viscosity and shear elastic modulus of the slurry, making it printable. The optimized silicon carbide slurry formulations are: 0.01% polyacrylic acid (PAA)in mass fraction, 63% solid loading and 0.04% MC in mass fraction, pH > 10, respectively.

     

/

返回文章
返回