镓的分离提取及高纯化制备方法

Extraction and purification process of gallium

  • 摘要: 镓是一种重要的稀散金属,在众多新兴高精尖领域有着重要的应用。文中介绍了镓分离提取及高纯化制备的常规工艺。镓在地壳中的丰度较低,通常和铝、锌等金属伴生,主要作为冶炼过程的副产品回收。常先采用酸或碱浸出矿石或二次资源中的镓,后采用离子交换法、分级沉淀法、溶剂萃取法富集浸出液中的镓,最终通过电积制备99.99%粗镓。镓的高纯化制备通常以工业生产的粗镓为原料,借助镓低熔点、高沸点的特点,以及主金属和杂质元素在不同相分配比不同的性质,通过电解精炼法、部分结晶法、单晶生长法、区域熔炼法、真空蒸馏法和真空热解法等技术进一步提纯制备99.999%~99.999 999%高纯镓。

     

    Abstract: Gallium, as a rare metal, occupies an important position in many emerging high-precision fields. This paper introduced several conventional processes of gallium extraction and purification. Gallium has a low abundance in the earth’s crust and is usually associated with aluminum and zinc, which is usually recovered as a byproduct. Acid or alkali leaching is first used to extract gallium from ores or secondary resources. And then ion exchange, fractional precipitation, and solvent extraction are generally applied to enrich gallium from lixivium, and finally crude gallium (99.99%) can be obtained by electrowinning, which is the raw material for further purification. Gallium has a low melting point and a high boiling point, and the distribution ratios of gallium and impurity elements in different phases are different, which is the theoretical basis for the purification. Therefore, the high-purity gallium (99.999%~99.999 999%) can be prepared by electrorefining, partial crystallization, single crystal growth, zone smelting, vacuum distillation and vacuum pyrolysis processes.

     

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