铝离子电池电解质研究进展

Research progress of electrolytes for aluminum-ion batteries

  • 摘要: 铝离子电池因其原材料成本低,金属铝负极理论容量高,以及整个电池体系的高安全性而被认为是“后锂时代”储能系统的有力候选者。目前,铝离子电池的研究更多集中在正极材料方面,然而电解质作为电池的重要组成部分,无论在液态还是固态铝离子电池中,对电池的电化学性能及安全性都具有关键性作用。近年来,有关铝离子电池电解质的研究报道迅速增加。基于此,文中综述了铝离子电池电解质的研究进展,主要包括水系电解质和非水系离子液体、无机熔盐、凝胶聚合物电解质,并探讨了不同电解质体系在电化学窗口、稳定性、工作温度条件、离子电导率和成本等方面的优势与局限性,对未来的发展方向作出了展望。

     

    Abstract: Aluminum-ion batteries are considered as an attractive candidate for "post-lithium" energy storage system due to their low cost of raw materials, high theoretical capacity of aluminum metal anode, and high safety of the whole battery system. At present, more researches for aluminum-ion batteries are focused on the cathode materials. However, as an important component, the electrolyte plays a crucial role in electrochemical performance and safety of aluminum-ion batteries, no matter in liquid or solid-state systems. In recent years, there is a rapid increase of research reports on electrolytes for aluminum-ion batteries. Herein, this paper reviewed the research progress of electrolytes for aluminum-ion batteries, including aqueous electrolytes and non-aqueous ionic liquid, inorganic molten salt, and gel polymer electrolytes. Furthermore, the advantages and disadvantages of different electrolyte systems in the aspect of electrochemical window, stability, operating temperature conditions, ionic conductivity and cost were discussed. Finally, some prospects of the future development direction were put forward in this paper.

     

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