铷的应用及提取工艺研究进展

Research progress in the application and extraction process of Rubidium

  • 摘要: 近年来,由于铷优良的物理化学性能,铷不仅在电子器件、特种玻璃、医药等传统领域有着重要用途,而且在磁流体发电、离子推进发动机等新型能源科技领域也显现出无限的活力。铷主要存在于矿石和盐湖卤水资源中,从含铷矿石中提铷比较成熟的工艺主要有硫酸分解法和焙烧分解法,传统的矿石提铷工艺存在流程复杂、污染大、能耗高等问题,对实现“双碳”目标构成严峻考验。分析表明,溶剂萃取法和离子交换法在解决盐湖卤水等液态资源提铷方面更具有发展前景。盐湖卤水提铷工艺简单,能耗低,无矿石分解过程,避免了大量固体废渣的产生,环境友好。文中在分析各类含铷矿石以及盐湖卤水资源特点的基础上,简述了铷资源在各领域的用途,综合介绍了硫酸分解法、碳酸盐焙烧法、氯化焙烧法、溶剂萃取法以及离子交换法等关键提铷技术的工艺研究现状及优缺点,展望了清洁环保、高效提铷的发展方向。

     

    Abstract: In recent years, due to its excellent physical and chemical properties, rubidium has not only played important roles in traditional fields such as electronic devices, special glass, and medicine, but also shown infinite vitality in new energy technology fields such as magnetic fluid power generation and ion propulsion engines. Rubidium is mainly found in ore and salt lake brine resources. The relatively mature processes of extracting rubidium from rubidium-containing ore mainly include sulfuric acid decomposition method and roasting decomposition method. The traditional rubidium extraction process from ores has problems such as complex processes, high pollution, and high energy consumption, which poses a severe test to achieve the goal of "carbon peak and neutrality". The analysis shows that solvent extraction method and ion exchange method are more promising in solving the problem of extracting rubidium from liquid resources such as salt lake brine. The process of extracting rubidium from salt lake brine, simple with low energy consumption, has no ore decomposition process, avoiding the generation of a large amount of solid waste residue, and thus is friendly to environment. Based on the analysis of the characteristics of various types of rubidium ores and salt lake brine resources, the uses of rubidium resources in various fields were briefly introduce in this paper. In addition, the research status as well as advantages and disadvantages of key rubidium extracting technologies, such as sulfuric acid decomposition method, carbonate roasting method, chlorinate roasting method, solvent extraction method and ion exchange method, are comprehensively introduced. Finally, the development direction of clean environmental protection and efficient rubidium extraction is looked forward to.

     

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