正极浆料黏度对汽车动力电池的影响

Effect of viscosity of vathode slurry on automotive power battery

  • 摘要: 为了研究LiNi0.5Co0.3Mn0.2O2正极材料浆料的黏度对锂离子汽车动力电池的影响.首先通过研究不同NMP含量对浆料黏度的影响,由此产生的对电池一致性和电化学性能的影响,再选取最优NMP含量的配方研究不同搅拌时间对正极浆料黏度的影响.利用黏度计、内阻测试仪、加速绝热量热仪、电池测试系统表征浆料的黏度、电池内阻、电池热稳定性和电化学性能,实验结果表明, NMP含量为880 g及搅拌6 h的浆料,平均黏度为6.348 pa·s,做出的电池容量差和内阻差比较小,电池在25 ℃, 2.75~4.2 V, 0.5 C倍率下首次放电比容量为163.5 mAh/g,循环100次后容量保持率为98.6 %,电池在绝热环境下充放电过程中温度最高为47.3 ℃,电池表现出良好的一致性、较好的电化学性能和热稳定性能.

     

    Abstract: This paper studies the effect of the viscosity of LiNi0.5Co0.3Mn0.2O2 cathode material on lithium ion vehicle power battery. The effect of different NMP content on the viscosity of the slurry leads to its effect on the uniformity of battery and electrochemical performance. The optimum formulation of NMP content was utilized to study the effect of different stirring time on the viscosity of the cathode. Viscometer, internal resistance tester, accelerated adiabatic calorimeter, battery test system are applied to characterize slurry viscosity, battery internal resistance, battery thermal stability and electrochemical performance. The experimental results show that NMP content of 880 g and stir for 6 hours, the average viscosity of 6.348 pa﹒s, with slight internal resistance difference and capacity difference. When cycled at 25 ℃with 0.5 C in the voltage range of 2.75-4.2 V, the first discharge capacity of 163.5 mAh/g with capacity retention rate of 98.6 % after 100 cycles. under the adiabatic conditions, the highest temperature of 47.3 ℃when battery charging and discharging process. Therefore, it shows good battery consistency, electrochemical performance and thermal stability.

     

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