离子型稀土矿土壤对铜的吸附解吸特性

Adsorption and desorption of copper in the soil of ionic rare earth mining areas

  • 摘要: 以原矿土、尾矿土作为供试土壤,采用振荡平衡法,研究Cu在离子型稀土矿区土壤中的吸附、解吸特性.结果表明:Cu在原矿、尾矿土中的吸附量均随平衡浓度的增加而增大,Cu在尾矿土的吸附量大于原矿土;用Langmuir、Frundlich、Temkin模型对吸附过程进行拟合,相关系数R2均大于0.93,其中Langmuir模型拟合效果最好. Elovich方程是描述Cu在原矿、尾矿土中吸附动力学行为的最优模型,其次是准二级动力学模型,最差的是准一级动力学模型. Cu在原矿、尾矿土上的解吸量随解吸平衡浓度的增加而持续增大,Cu的解吸量与吸附量之间的关系符合二次幂方程.

     

    Abstract: The adsorption and desorption characteristics of Cu in the soil (ore soil and tailings soil) of ionic rare earth mining areas were studied by the oscillation equilibrium method.The results show that the adsorption capacity of Cu in ore and tailings soil increases with the increasing adsorption of the ions, and the adsorption capacity of Cu in the tailings soil is larger than that in the ore soil. The Langmuir, the Freundlich and the Temkin models were used to fit the adsorption process. The correlation constant R2 is more than 0.93, and the Langmuir model is the best.The Elovich equation is the optimal model for describing the adsorption kinetic behavior of Cu in the ore and tailings soil, followed by the quasi-second order kinetic model and the worst is the quasi-first order kinetic model.The desorption amount of Cu in the ore and tailings soil continues to grow as the desorption equilibrium concentration increases, and the relationship between the amount of the adsorption and the desorption of Cu in soils could be simulated by quadratic function.

     

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