001×8 树脂从离子型稀土浸出液中吸附稀土及杂质离子的性能研究

Property of 001×8 resin for adsorption RE3+ and impurity ions from ionic-type rare earth lixivium

  • 摘要: 通过静态吸附和动态吸附实验,研究温度、pH值、稀释倍数和流速对001×8树脂从离子型稀土浸出液中吸附稀土与杂质离子的吸附量及分离系数的影响. 结果表明:浸出液中稀土与杂质离子的吸附量及分离系数随着pH值的增大呈现出先增大而后减小的趋势,在pH值为3.5时达到最大值;随着温度的升高而增大,吸附量在313 K后逐渐趋于平衡. 树脂对各离子吸附能力大小为: RE3+>Al3+>Mg2+>SiO32-. RE3+、SiO32-和Al3+的吸附量随着稀释倍数的加大而增大,随着流速的加快而减小,而Mg2+的吸附量随着稀释倍数的加大或流速的加快而减小. 因此,增大稀释倍数和降低流速有利于001×8树脂吸附稀土和除去杂质.

     

    Abstract: To reveal the regulations of adsorption capacity and separation coefficient during the adsorption of RE3+ and impurity ions from ionic-type rare earth lixivium, the effect of temperature, pH value, dilution ration and flow velocity were investigated through static and dynamic adsorption experiments. The results show that the adsorption capacity and separation coefficient tends to increase first then decrease with the increasing of pH, and reaches maximum at pH 3.5. Adsorption capacity increases with the rising of temperature and tends to be balanced after 313 K. The adsorption capability order of 001×8 resin to all related ions is: RE3+>Al3+>Mg2+>SiO32-. The adsorption capacity to RE3+, SiO32- and Al3+ is proportional to desaturation multiple, and inverse ratio to flow velocity. Mg2+ adsorption reduces with the increase of desaturation multiple or flow velocity. Thus increase of desaturation multiple and decrease of flow velocity are beneficial to the rare earth adsorption capacity and impurities removing capacity of 001×8 resin.

     

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