攀钢含钛高炉渣湿法提钛工艺

Hydrometallurgical process for recovering titanium from titanium-bearing blast furnace slag in Panzhihua Steel Plant

  • 摘要: 酸浸法提钛工艺可以获得较高TiO2含量的产物,但是该工艺所产生的酸浸液存在难回收的问题.采用碱浸法可以避免酸浸液回收的问题,但是该工艺流程比较复杂,钠盐的回收成本较高.酸碱法在理论上可以将含钛高炉渣转化为富钛料,然而该工艺流程相对复杂,工业应用还需要不断深入研究与完善.针对采用湿法工艺从攀钢含钛高炉渣中提钛的各项技术,从技术、经济、环保等方面进行对比分析,指出需要将湿法工艺与火法工艺联合,同时将一些外场冶金技术引入到含钛高炉渣的提钛分离过程中,从而有望高效、综合利用攀钢含钛高炉渣.

     

    Abstract: High purity TiO2-containing product is prepared by acid leaching method. However, the pickle liquor recycling remains a difficult problem, which can be avoided by using the alkaline leaching method, but this process is complex and the recovering cost of sodium salt is a bit high. The acid-alkali method can change the Ti-bearing blast-furnace slag into rich-titanium material theoretically, while this process is complex too, which needs further study and perfection. A variety of pyrometallurgy technologies to recover titanium from titanium bearing blast furnace slag are comprehensively reviewed and a comparative analysis is made from aspect of technological, economic and environmental protection. It is pointed out that efficient and comprehensive utilization of titanium bearing blast furnace slag requires combining pyrometallurgy with hydro metallurgical process, as well as some external field metallurgy technology.

     

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