磁场对镍基 Ni-Mn-Ga 铁磁合金相变温度影响的热力学分析

Thermodynamic analysis of phase transformation temperature affected by magnetic field on nickel-base Ni-Mn-Ga ferromagnetic alloy

  • 摘要: 通过测量磁化曲线、电阻-温度关系和热分析等手段,研究了磁场对镍基铁磁合金试样 Ni- Mn-Ga 相变的影响.结果表明:在磁场作用下相变温度升高了约 1.5 K,具有明显的磁场影响特征.利用马氏体相变热力学理论,研究了磁场对镍基铁磁合金化学自由能和非化学自由能与温度的变化关系,建立了其作用的数理模型,并与实验结果比较后基本吻合.

     

    Abstract: Nickel -base ferromagnetic alloy Ni -Mn -Ga was investigated for phase transformation temperature affected by magnetic field by measuring magnetization curve, temperature dependence of the resistance, and thermal analysis. The results show that magnetic field application can increase phase transformation temperature 1.5 K with distinctive behavioral affected by field. Meanwhile, thermodynamic theory of martensitic phase transformation is applied to study temperature dependence of the chemical free energy and non-chemical free energy on nickel-base ferromagnetic alloy; a mathematical model is built and agrees well with experimental result.

     

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