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Volume 2 Issue 1
Feb.  2011
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TANG Yun－zhi, LIAO Su-lan, HUANG shuai, DENG Yun-pan, WEN He-rui. The Hydrolysis of Fipronil with Zn2+ Ion Catalysis and Its Crystal Structure[J]. Nonferrous Metals Science and Engineering, 2011, 2(1): 19-22.
Citation: TANG Yun－zhi, LIAO Su-lan, HUANG shuai, DENG Yun-pan, WEN He-rui. The Hydrolysis of Fipronil with Zn2+ Ion Catalysis and Its Crystal Structure[J]. Nonferrous Metals Science and Engineering, 2011, 2(1): 19-22.
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The Hydrolysis of Fipronil with Zn2+ Ion Catalysis and Its Crystal Structure

  • Faculty of Material and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

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  • Received Date: October 20, 2010
  • Published Date: February 27, 2011
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    • Abstract
  • A new compound 1, 5-amino-1-[2, 6-dichloro-4-(trifluoromethyl) phenyl]-4-[(trifluoromethyl) sulfinyl] -1H -pyrazole -3-carboxylic acid has been produced by hydrothermal reaction of fipronil (5 -amino -1 -[2, 6-dichloro-4-(trifluoromethyl) phenyl]-4-[(trifluoromethyl) sulfinyl]-1H-pyrazole-3-nitrile) and lewis acid ZnCl2. The compound was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21/c with a = 12.7457(8)Å, b = 8.8244(6)Å, c = 15.7322 (11)Å, α= 90°, β = 100.2310(10)°, γ=90°, Z= 4, V = 1741.3(2)Å3, F(000) = 856. The intermolecular hydrogen bonds are speculated to hold together the molecules of the compound. UV spectrum of 1 in solid state shows two maximum absorption peaks at 220 and 281 nm respectively.
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    • References (13)
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