Current Issue Cover
Advanced Search
Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 15 Issue 1
Feb.  2024
Turn off MathJax
Article Contents
Abstract
References
HOU Hongying, JIA Yanpeng, LI Junkai, LAN Jian, CHEN Fangshu. Extraction and electrochemical lithium storage performances of double-spheroid manganous carbonate from graphene production waste effluent[J]. Nonferrous Metals Science and Engineering, 2024, 15(1): 8-14. DOI: 10.13264/j.cnki.ysjskx.2024.01.002
Citation: HOU Hongying, JIA Yanpeng, LI Junkai, LAN Jian, CHEN Fangshu. Extraction and electrochemical lithium storage performances of double-spheroid manganous carbonate from graphene production waste effluent[J]. Nonferrous Metals Science and Engineering, 2024, 15(1): 8-14. DOI: 10.13264/j.cnki.ysjskx.2024.01.002
shu

Extraction and electrochemical lithium storage performances of double-spheroid manganous carbonate from graphene production waste effluent

  • 1.

    Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming650093, China

  • 2.

    Law School, Kunming University of Science and Technology, Kunming650093, China

More Information
  • Received Date: August 28, 2022
  • Revised Date: November 17, 2022
    Graphical Abstract
    • Abstract
  • According to the “double carbon” targets and circular economy, various wastes must be recycled as much as possible. Therefore, manganous ions in the waste effluent from graphene production were extracted with Na2CO3 as the precipitation agent by one-step chemical reaction, forming light yellow MnCO3 powder. Meanwile, its electrochemical lithium storage properties were studied. The results show that the removal rate of manganous ions is 99.9% and the recovery rate of MnCO3 is 92.6%. The extracted MnCO3 powders consist of many double spheroids with a particle size of 0.5-1.5 μm, which belong to the hexagonal crystalline. After cycling for 300 cycles at 0.5 A/g and 1.0 A/g, the corresponding reversible capacity is maintained at about 570 mAh/g and 418 mAh/g, respectively. This article provides a new idea for the recovery of graphene industrial wastewater, helping to reduce environmental emissions.
    • FullText(HTML)
    • References (26)
  • [1]
    魏文栋, 陈竹君, 耿涌, 等. 循环经济助推碳中和的路径和对策建议[J]. 中国科学院院刊, 2021, 36(9): 1030-1038.
    [2]
    LI Q S. The view of technological innovation in coal industry under the vision of carbon neutralization[J]. International Journal of Coal Science and Technology2021, 8(6):1197-1207.
    [3]
    刘彩利, 王京芳, 周军. 材料科学的绿色之路[J]. 材料导报,2006, 20(3): 92-96.
    [4]
    蔡云婷,俞小花,史春阳. 镍基电池的回收及锌镍电池负极回收技术[J]. 有色金属科学与工程, 2019,10(6):8-12.
    [5]
    侯宏英, 孟瑞晋. 石墨烯的晶格缺陷[J]. 人工晶体学报,2014, 43(11): 2935-2942.
    [6]
    代志鹏,侯宏英,刘显茜,等. 过期藻酸双酯钠药片的电化学储钠/锂性能[J]. 硅酸盐学报, 2019,47(6)：730-734.
    [7]
    DUAN J X, HOU H Y, LIU X X, et al. High performance PPO/Ti3+/TiO2NT membrane/electrode for lithium ion battery[J]. Ceramics International2016, 42:16611-16618.
    [8]
    HOU H, LIU X, YAO Y, et al. Recovery of waste Li foils from spent experimental Li-anode coin cells for LiFePO4/C cathode[J]. Sustainable Materials and Technologies, 2018,17:e00064.
    [9]
    聂薇,田丰,袁志强,等. 稻壳基多孔硬碳的制备及其储钠性能[J]. 有色金属科学与工程, 2019,10(5):85-90.
    [10]
    李德山, 张祥, 杨桂英, 等. 花状碳酸锰的制备及其电化学性能表征[J].广州化工,2020, 48(7):34-35,41.
    [11]
    KESAVAN T,SURESH S,ARULRAJ I,et al．Facile synthesis of hollow sphere MnCO3:A cheap and environmentally benign anode material for Li-ion batteries[J]. Materials Letters ,2014,136: 411-415.
    [12]
    WANG L, SUN Y W, ZENG S Y, et al. Study on the morphology-controlled synthesis of MnCO3 materials and their enhanced electrochemical performance for lithium ion batteries[J]. Cryst Eng Comm, 2016, 18(41):8072-8079.
    [13]
    王明辉, 晏波, 麦戈, 等. 分步沉淀法处理酸性矿山废水[J]. 化工环保, 2016, 36(1):47-52.
    [14]
    SHEN W, REN Y S, MA H J, et al. Investigation of solid-liquid equilibria on the system Na+, K+//CI-, SO42--H2O and Na+, K+//SO42--H2O at 313.15 K[J]. Journal of Chemical and Engineering Data2016, 61(6):2027-2039.
    [15]
    HAN X, CUI Y P, LIU H W. Ce-doped Mn3O4 as high-performance anode material for lithium ion batteries[J]. Journal of Alloys and Compounds, 2020, 814:152348.
    [16]
    BIESINGER M C, PAYNE B P, GROSVENOR A P, et al. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni[J]. Applied Surface Science, 2011, 257(7):2717-2730.
    [17]
    QI M, LIN L W, WANG L Q, BAI Z, et al. Spindle MnCO3 tightly encapsulated by MXene nanoflakes with strengthened interface effect for lithium-ion battery[J]. Surface and Coatings Technology, 2021, 417: 127192.
    [18]
    XIAO L, WANG S Y, WANG Y F, et al. High-capacity and self-stabilized manganese carbonate microspheres as anode material for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2016, 8(38):25369-25378.
    [19]
    HOU H Y, DAI Z P, LIU X X, et al. Reutilization of the expired tetracycline for lithium ion battery anode[J]. Science of the Total Environment, 2018, 630:495-501.
    [20]
    SU D Y, WANG J, YANG Z, et al. Stability electrochemical performance of self-assembled hierarchical MnCO3/MWCNT nanocomposite as anode material for lithium-ion batteries[J]. Journal of Solid State Electrochemistry , 2018, 22(11):3485-3491.
    [21]
    LIU B, HU X L, XU H H, et al. Encapsulation of MnO nanocrystals in electrospun carbon nanofibers as high-performance anode materials for lithium-ion batteries[J]. Scientific Reports , 2014, 4(1):1-6.
    [22]
    安贵凤, 高鹏宇, 庄子辰, 等. 多孔MnCO3立方体的制备及其储锂性能[J]. 化工时刊, 2020, 34(7):5-7,40.
    [23]
    钟采妮,陈哲钦,卢彦华,等. 锂离子电池用 CuFe2O4立方颗粒负极材料的合成及其电化学性能[J]. 有色金属科学与工程,2020,11(3):59-64.
    [24]
    HAO R R, WANG J, YAO S W, et al. The 3D Networked MnCO3-C composite as anode materials for lithium ion batteries[J]. Journal of Electroanalytical Chemistry,2020, 877:114655.
    [25]
    LIU M J, WANG Q, LIU Z Y, et al. In-situ N-doped MnCO3 anode material via one-step solvothermal synthesis: Doping mechanisms and enhanced Electrochemical performances[J]. Chemical Engineering Journal, 2020, 383:123161.
    [26]
    WEI Y Y, ZI Z F, CHEN B Z, et al. Facile synthesis of hollow MnO microcubes as superior anode materials for lithium-ion batteries[J]. Journal of Alloys and Compounds,2018, 756: 93-102.
    • Related Articles

Catalog

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (93) PDF downloads (17) Cited by()
    Related

    Copyright © 2010 Editorial Department of Nonferrous Metals Science and Engineering All rights reserved

    Address：11th floor, bishop building, University of science and technology, No. 86, Hongqi Avenue, Ganzhou City, Jiangxi Province  Tel：0797-8312555

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return