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Founded in 1987， Bimonthly
Supervisor：Jiangxi University Of Science And Technology
Sponsored by：Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN：1674-9669
CN：36-1311/TF
CODEN YJKYA9
Volume 14 Issue 2
Apr.  2023
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TONG Zhifang, XU Congcong, WANG Jiaxing, JIA Zhiheng, ZHANG Chuanbo. Effect of FeO content on migration and distribution of chromium in glass ceramics derived from stainless steel slag and chromium fixation[J]. Nonferrous Metals Science and Engineering, 2023, 14(2): 171-181. DOI: 10.13264/j.cnki.ysjskx.2023.02.003
Citation: TONG Zhifang, XU Congcong, WANG Jiaxing, JIA Zhiheng, ZHANG Chuanbo. Effect of FeO content on migration and distribution of chromium in glass ceramics derived from stainless steel slag and chromium fixation[J]. Nonferrous Metals Science and Engineering, 2023, 14(2): 171-181. DOI: 10.13264/j.cnki.ysjskx.2023.02.003
shu

Effect of FeO content on migration and distribution of chromium in glass ceramics derived from stainless steel slag and chromium fixation

  • 1.

    Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

  • 2.

    Changchun Gold Design Institute Co., Ltd., Changchun 130000, China

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  • Received Date: April 06, 2022
  • Available Online: May 05, 2023
    Graphical Abstract
    • Abstract
  • In this paper, glass-ceramics were prepared from stainless steel slag, and the effects of FeO content on the occurrence and distribution of Cr in glass-ceramics, migration behavior and chromium fixation were systematically studied. The results showed that the amount of crystal nucleus of Cr-spinel increased, and then Cr in the glass phase gradually migrated to Cr-spinel with the increase of FeO content in the nucleation stage. In the crystallization stage, Cr-spinel nanocrystals generated diopside crystal phase. TEM and XPS analysis showed that part of Cr occurred in the crystal lattice of diopside, and the other part of Cr still existed in the Cr-spinel encapsulated by diopside. The Cr in the glass phase also diffused and migrated into the crystal lattice of diopside with the formation of diopside crystals. When the content of FeO was 4.80%(w/w), 95.23% (w/w) Cr occurred in the crystal phase of diopside. The leaching concentration of Cr3+ was only 0.007 mg/L, and the compressive and Vickers hardness strength of glass-ceramics were 235 MPa and 949.3, respectively. The research results provide theoretical and technical support for strengthening chromium fixation, realizing harmless and high-value utilization of stainless steel slag.
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