XIA Dingfeng, ZHOU Miaomiao, GUO Qiankun, HU Shun, ZOU Jin, ZHONG Shengwen. Effect of graphene composite conductor on kinetic and electrochemical properties of LiNi0.5Co0.2Mn0.3O2[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 35-42. DOI: 10.13264/j.cnki.ysjskx.2022.03.005
Citation: XIA Dingfeng, ZHOU Miaomiao, GUO Qiankun, HU Shun, ZOU Jin, ZHONG Shengwen. Effect of graphene composite conductor on kinetic and electrochemical properties of LiNi0.5Co0.2Mn0.3O2[J]. Nonferrous Metals Science and Engineering, 2022, 13(3): 35-42. DOI: 10.13264/j.cnki.ysjskx.2022.03.005

Effect of graphene composite conductor on kinetic and electrochemical properties of LiNi0.5Co0.2Mn0.3O2

  • The lithium-ion deembedding kinetics study of two different groups of conductive agents adding conductive carbon black and conductive carbon black composite graphene as well as the battery assembled by LiNi0.5Co0.2Mn0.3O2 is conducted by cyclic voltammetry and AC impedance method. The lithium ion diffusion coefficient was calculated to explore the effect of different conductive agents on the LiNi0.5Co0.2Mn0.3O2 lithium ion deintercalation kinetics ring. The electrochemical performance tests show that the first discharge specific capacities of adding a single conductive carbon black conductive agent, as well as a composite conductive agent of graphene and conductive carbon black, are 166 and 184 mAh/g, respectively. The discharge specific capacity of graphene and conductive carbon black composite conductive agents is significantly improved.
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