Founded in 1987, Bimonthly
Supervisor:Jiangxi University Of Science And Technology
Sponsored by:Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN:1674-9669
CN:36-1311/TF
CODEN YJKYA9
ZENG Qingyun, LI Qing, XIAO Ting, WANG Zongjun, XIAO Peinan. Preparation of (Y1-x-y, Lay)2O3:xEu3+ red phosphors by microwave-assisted homogeneous precipitation method[J]. Nonferrous Metals Science and Engineering, 2017, 8(2): 107-111. DOI: 10.13264/j.cnki.ysjskx.2017.02.018
Citation: ZENG Qingyun, LI Qing, XIAO Ting, WANG Zongjun, XIAO Peinan. Preparation of (Y1-x-y, Lay)2O3:xEu3+ red phosphors by microwave-assisted homogeneous precipitation method[J]. Nonferrous Metals Science and Engineering, 2017, 8(2): 107-111. DOI: 10.13264/j.cnki.ysjskx.2017.02.018

Preparation of (Y1-x-y, Lay)2O3:xEu3+ red phosphors by microwave-assisted homogeneous precipitation method

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  • Received Date: September 11, 2016
  • Published Date: April 29, 2017
  • A series of (Y1-x-y, Lay)2O3:xEu3+(x=0.01~0.05, y=0.05~0.25) red phosphors were synthesized by microwave-assisted homogeneous precipitation method. The effects of doping density of Eu3+ and La3+, the calcining temperature on the characteristics of lumen-escence were investigated. The TG and FTIR curves of precursor, crystal structure, surfacemorphology, particle size and spectral characteristics of the samples were also investigated by differential thermal analysis, infrared spectroscopy, X-ray diffraction, SEM and fluoresc-ence spectrophotometer. The results indicate that the composition of precursor is (Y, La, Eu) OHCO3·nH2O and the as-prepared samples are cubic system. The SEM show that the samples are uniformly dispersed spherical phosphors particles with particle size of being about 200 nm. The optimum calcining temperature is 900 ℃. The optimum emission intensity of 614 nm is obtained when the x=0.03, y=0.1, 614 nm is corresponding to 5D07F2 transitionof Eu3+ ions in emission spectrum. The color coordinates of the sample is (0.654, 0.346).(Y1-x-y, Lay)2O3:xEu3+ phosphors have good color purity and luminous intensity.
  • [1]
    洪广言.稀土发光材料的研究进展[J].人工晶体学报, 2015, 44(10):2641-2651. http://cdmd.cnki.com.cn/Article/CDMD-10200-2008108365.htm
    [2]
    赵娟刚, 曾青云, 肖婷, 等.微波辅助液相法制备CaMoO4:Eu3+荧光粉[J].有色金属科学与工程, 2016, 7(1): 15-19. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=201601004
    [3]
    吴迪, 叶信宇, 黄昕, 等. (Sc, Y)(VO4, BO3):Eu3+红色荧光粉的制备与发光性能研究[J].稀有金属, 2016, 40(5):440-445.
    [4]
    洪广言.稀土发光材料[M].北京:科学出版社, 2011.
    [5]
    PIMPUTKAR S, SPECK J S, DENBAARS S P, et al. Prospects for LED lighting[J]. Nature Photonics, 2009, 3(4): 180-182. doi: 10.1038/nphoton.2009.32
    [6]
    SHEU J K, CHANG S J, KUO C H, et al. White-light emission from near UV InGaN-GaN LED chip precoated with blue /green /red phosphors[J]. IEEE Photonics Technology Letters, 2003, 15(1): 18-20. doi: 10.1109/LPT.2002.805852
    [7]
    YE X Y, LONG Z, YANG Y M, et al. Photoluminescence enhancement of YAG: Ce3+ phosphor prepared by co-precipitation rheological phase Method[J]. Journal of Rare Earths, 2012, 30(1): 21. doi: 10.1016/S1002-0721(10)60631-X
    [8]
    CAO F B, TIAN Y W, CHEN Y J, et al. Improved luminous properties of red emitting phosphors for LED application by charge compensation[J]. Acta Physico-Chimica Sinica, 2009, 25(2): 299-303. http://www.whxb.pku.edu.cn/EN/abstract/abstract21237.shtml
    [9]
    ZHAI Y Q, YOU Z J, LIU Y H, et al. Properties of red-emitting phosphors Sr2MgSi2O7:Eu3+ prepared by gel-combustionmethod assisted by microwave[J]. Journal of Rare Earths, 2012, 30(2): 114-117. doi: 10.1016/S1002-0721(12)60005-2
    [10]
    杨泰, 李霞.红色Sr1-2xNaxWO4:xEu3+荧光体的制备与发光性能[J].稀土, 2012, 33(1): 37-41. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201201011.htm
    [11]
    杨志平, 王天洋, 冉争瑞, 等.红色荧光粉Ba3La6(SiO4)6:Eu3+的制备与发光性能[J].硅酸盐学报, 2015, 43(4): 465-470.
    [12]
    廖金生, 柳少华, 周单, 等.红色荧光粉La2O3:Eu3+的合成及发光性质[J].有色金属科学与工程, 2013, 4(6): 19-23. http://ysjskx.paperopen.com/oa/DArticle.aspx?type=view&id=2013060004
    [13]
    WANG J, ZHANG Z J, GUO X X, et al. High quality thin film phosphors of Y2O3:Eu3+ deposited via chemical bath deposition[J]. Journal of Rare Earths, 2010, 28(5): 684-687. doi: 10.1016/S1002-0721(09)60179-4
    [14]
    司伟, 姜妲, 高宏, 等. Ca2+、La3+掺杂纳米Y2O3:Eu3+的超声波制备及光致发光性能[J].稀土, 2008, 29(5): 24-29. http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ200805008.htm
    [15]
    MORALES R A, GARCIA M A, CARRILLO R F, et al. Properties of Gd2O3:Eu3+, Tb3+ nanopowders obtained by solgel process[J]. Materials Research Bulletin, 2010, 45(1): 40-45. doi: 10.1016/j.materresbull.2009.09.005
    [16]
    LIU W D, WANG H C, ZHAN S P, et al. Splitting and broadening of the emission bands of Y2O3:Eu3+, Nd3+ and its dependence on Nd3+ concentration and annealing temperature[J]. Journal of Materials Science, 2011, 46(23): 7620-7625. doi: 10.1007/s10853-011-5739-6
    [17]
    王烨文, 陈毅彬, 曾人杰.微波水热法制备铋铕共掺杂氧化钇磷光粉[J].发光学报, 2009, 30(2): 174-178. http://www.cnki.com.cn/Article/CJFDTOTAL-FGXB200902011.htm
    [18]
    蒲勇, 朱达川, 马明星, 等.化学共沉淀法制备的 (Y1-x-y, Gdy)2O3:xEu3+红色荧光粉及其发光性能[J].发光学报, 2012, 33(3): 247-252.
    [19]
    翟永清, 李瑞方, 胡志春, 等.微波辐射法快速合成Dy3+激活的SrMoO4黄色荧光粉[J].功能材料, 2014, 17(45): 17136-17139. http://www.cnki.com.cn/Article/CJFDTOTAL-GNCL201417029.htm
    [20]
    杨玉玲, 黎学明, 冯文林, 等. (Ca1-x-yLuy) MoO4:xEu3+红色荧光粉的化学共沉淀合成与光致发光[J].无机化学学报, 2011, 27(2): 276-280. http://www.cnki.com.cn/Article/CJFDTOTAL-WJHX201102013.htm
    [21]
    冯宗玉, 黄小卫, 王猛, 等.共沉淀-热处理工艺合成 (La, Ce, Tb) PO4荧光粉的研究[J].稀有金属材料与工程, 2013, 42(2): 375-378. http://www.cnki.com.cn/Article/CJFDTOTAL-COSE2013S2088.htm
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