Founded in 1987, Bimonthly
Supervisor:Jiangxi University Of Science And Technology
Sponsored by:Jiangxi University Of Science And Technology
Jiangxi Nonferrous Metals Society
ISSN:1674-9669
CN:36-1311/TF
CODEN YJKYA9
YANG Shao-hua, LAI Xiao-hui, WANG Jun, WANG Hao-ran, XIE Bao-ru. The extraction and separation of rubidium from high potassium and sodium contained brine using t-BAMBP[J]. Nonferrous Metals Science and Engineering, 2015, 6(5): 17-21. DOI: 10.13264/j.cnki.ysjskx.2015.05.004
Citation: YANG Shao-hua, LAI Xiao-hui, WANG Jun, WANG Hao-ran, XIE Bao-ru. The extraction and separation of rubidium from high potassium and sodium contained brine using t-BAMBP[J]. Nonferrous Metals Science and Engineering, 2015, 6(5): 17-21. DOI: 10.13264/j.cnki.ysjskx.2015.05.004

The extraction and separation of rubidium from high potassium and sodium contained brine using t-BAMBP

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  • Received Date: April 21, 2015
  • Published Date: October 30, 2015
  • T-BAMBP extraction system with xylene as diluent was taken to separate rubidium from brine contained high potassium and sodium. The influences of organic phase composition, feed liquid alkalinity,organic-aqueous phase ratio, extraction time and temperature on extraction and separation efficiency were researched. The results showed that extraction rate of rubidium after five stage countercurrent extraction can reach 95.5% using 30% volume fraction t-BAMBP contained organic extractant with 0.4mol/L feed liquid alkalinity,0.0117mol/L initial concentration of Rb+,1:1 phase ratio, 4 minutes extraction time and 21℃ extraction temperature. Highly purified rubidium salt can be obtained through multistage extraction.
  • [1]
    . 张霜华.浅谈拓宽我国铷铯的应用领域[J].新疆有色金属,1998(2):43-47. http://www.cnki.com.cn/Article/CJFDTOTAL-XJYS199802010.htm
    [2]
    . 王威,曹耀华,高照国,等.铷、铯分离提取技术研究进展[J].矿产保护与利 用,2013(4):54-58. http://www.cnki.com.cn/Article/CJFDTOTAL-KCBH201304018.htm
    [3]
    . 张正斌.海洋化学原理和应用—中国近海的海洋化学[M].北京:海洋出版社,1999:24-26.
    [4]
    . 曹冬梅,张雨山,高春娟,等.提铷技术研究进展[J].盐业与化工,2011,40(5):44-47. http://www.cnki.com.cn/Article/CJFDTOTAL-HHYH201105016.htm
    [5]
    . 牛慧贤.铷及其化合物的制备技术研究与应用展望[J].稀有金属,2006,30(4):523-527. http://www.cnki.com.cn/Article/CJFDTOTAL-ZXJS200604020.htm
    [6]
    . Kumar A,Mohapatra P K,Manchanda V K. Extraction of cesium-137 from nitric acid medium in the presence of macrocyclic polyethers[J]. J Radioanal Nuel Chem,1998, 229(1):169-172. http://cn.bing.com/academic/profile?id=2113577794&encoded=0&v=paper_preview&mkt=zh-cn
    [7]
    . Tanihara K. Composite ion exchangers of redox type for cesium separation Sorption-desorption—regeneration cycle with cupric ferroeyanide impregrmted.macroporous anion-exchange resins of strongly basic type[J]. J Radioanal Nud Chem,1995, 201(6): 509—519.
    [8]
    . 刘雪颖,杨锦瑜,陈晓伟,等.t-BAMBP分离铷钾萃取机理及热力学函数研究[J].核化学与放射化学,2007,29(3):151-155. http://www.cnki.com.cn/Article/CJFDTOTAL-HXFS200703005.htm
    [9]
    . 杨锦瑜,古映莹,钟世安,等.以t-BAMBP萃取分离铷钾的研究[J].有色金属,2008,60(2):55-58. http://www.cnki.com.cn/Article/CJFDTOTAL-YOUS200802013.htm
    [10]
    . Fujii T,Nishizawa K. Isotope sepaiations of potassium and rubidium in chemicad exchange system with dicyclohexano-18-crown-6 [J].J.Radioanal.Nucl.Chem,2001,249(3):569.
    [11]
    . Banerjee S,Mukhopadhyay K, Mukhopadhyay B,Lahiri S. Extraction separation of 86Rb from 85Sr in trace level with 18-crown-6 in nitrobenzene [J].J.Radioanal.Nucl.Chem,2002,252(1):157.
    [12]
    . 杨玲,王林生,赖华生,等.不同稀释剂中t-BAMBP萃取铷铯的研究[J].稀有金属,2011, 35 (4):627-632. http://www.cnki.com.cn/Article/CJFDTOTAL-ZXJS201104027.htm
    [13]
    . 孟素青,李瑞琴,丁建跃,等.萃取法(t-BAMBP)提取卤水中铷、铯及其影响因素分析[J].中国井矿盐,2013,(6):12-14. http://www.cnki.com.cn/Article/CJFDTOTAL-ZJKY201306005.htm
    [14]
    . 卢智,安莲英,宋晋.t-BAMBP萃取法分离提取高钾卤水中铷[J].广东微量元素科学,2010,17 (1):52-56. http://www.cnki.com.cn/Article/CJFDTOTAL-GWYS201001013.htm
    [15]
    . Liu SM, Liu H H, Huang Y J, et al. Solvent extraction of rubidium and cesium from salt lake brine witht-BAMBP-kerosene solution[J]. Transactions of Nonferrous Metals Society of China,2015(1):329-334.
    [16]
    . 陈正炎,陈富珍.t-BAMBP萃取铷、铯的相关因素研究[J].稀有金属,1995,19(4):245-247. http://www.cnki.com.cn/Article/CJFDTOTAL-ZXJS504.002.htm
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